The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>

Autores
Baran, Enrique José; Lavat, A. E.; Saez Puche, R.; Salinas Sanchez, A.
Año de publicación
1992
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Compounds of general composition Ln2BaCuO5 (Ln=lanthanide) adopt different structural types. Two series of structures have been reported for LnzBaCuO5 compounds. For lanthanide ions smaller than Nd(III) (Y and Sm-Lu) the so-called "green phases" (orthorhombic, space group Pbnm) are stabilized. They are one of the main impurities generated during the synthesis of the LnBa2Cu3OT_x-type high-T¢ superconducting oxides. A different structural type (tetragonal, space group P4/mbm) becomes stabilized for Ln = La or Nd, although in the case of the lanthanum-containing material the totally stoichiometric composition does not seem to be attainable.
Facultad de Ciencias Exactas
Materia
Química
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/139138

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network_name_str SEDICI (UNLP)
spelling The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>Baran, Enrique JoséLavat, A. E.Saez Puche, R.Salinas Sanchez, A.QuímicaCompounds of general composition Ln2BaCuO5 (Ln=lanthanide) adopt different structural types. Two series of structures have been reported for LnzBaCuO5 compounds. For lanthanide ions smaller than Nd(III) (Y and Sm-Lu) the so-called "green phases" (orthorhombic, space group Pbnm) are stabilized. They are one of the main impurities generated during the synthesis of the LnBa2Cu3OT_x-type high-T¢ superconducting oxides. A different structural type (tetragonal, space group P4/mbm) becomes stabilized for Ln = La or Nd, although in the case of the lanthanum-containing material the totally stoichiometric composition does not seem to be attainable.Facultad de Ciencias Exactas1992info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1087-1088http://sedici.unlp.edu.ar/handle/10915/139138enginfo:eu-repo/semantics/altIdentifier/issn/0261-8028info:eu-repo/semantics/altIdentifier/issn/1573-4811info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00730839info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T11:04:39Zoai:sedici.unlp.edu.ar:10915/139138Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 11:04:39.271SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
spellingShingle The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
Baran, Enrique José
Química
title_short The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_full The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_fullStr The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_full_unstemmed The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_sort The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
dc.creator.none.fl_str_mv Baran, Enrique José
Lavat, A. E.
Saez Puche, R.
Salinas Sanchez, A.
author Baran, Enrique José
author_facet Baran, Enrique José
Lavat, A. E.
Saez Puche, R.
Salinas Sanchez, A.
author_role author
author2 Lavat, A. E.
Saez Puche, R.
Salinas Sanchez, A.
author2_role author
author
author
dc.subject.none.fl_str_mv Química
topic Química
dc.description.none.fl_txt_mv Compounds of general composition Ln2BaCuO5 (Ln=lanthanide) adopt different structural types. Two series of structures have been reported for LnzBaCuO5 compounds. For lanthanide ions smaller than Nd(III) (Y and Sm-Lu) the so-called "green phases" (orthorhombic, space group Pbnm) are stabilized. They are one of the main impurities generated during the synthesis of the LnBa2Cu3OT_x-type high-T¢ superconducting oxides. A different structural type (tetragonal, space group P4/mbm) becomes stabilized for Ln = La or Nd, although in the case of the lanthanum-containing material the totally stoichiometric composition does not seem to be attainable.
Facultad de Ciencias Exactas
description Compounds of general composition Ln2BaCuO5 (Ln=lanthanide) adopt different structural types. Two series of structures have been reported for LnzBaCuO5 compounds. For lanthanide ions smaller than Nd(III) (Y and Sm-Lu) the so-called "green phases" (orthorhombic, space group Pbnm) are stabilized. They are one of the main impurities generated during the synthesis of the LnBa2Cu3OT_x-type high-T¢ superconducting oxides. A different structural type (tetragonal, space group P4/mbm) becomes stabilized for Ln = La or Nd, although in the case of the lanthanum-containing material the totally stoichiometric composition does not seem to be attainable.
publishDate 1992
dc.date.none.fl_str_mv 1992
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
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info:ar-repo/semantics/articulo
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status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/139138
url http://sedici.unlp.edu.ar/handle/10915/139138
dc.language.none.fl_str_mv eng
language eng
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info:eu-repo/semantics/altIdentifier/issn/1573-4811
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00730839
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
1087-1088
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instname:Universidad Nacional de La Plata
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reponame_str SEDICI (UNLP)
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repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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