Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode...

Autores
Marchiano, Susana Lucy; Rebollo Neira, L.; Arvia, Alejandro Jorge
Año de publicación
1990
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The concentration profiles of reacting species at the electrode—solution interface under a periodic square wave perturbing potential are calculated by solving the diffusion equation for the case of a fast reversible metal—metal ion reaction. This situation is particularly interesting in the electrochemical facetting of metals. The model explains the dependence of current density and charge density on the frequency and number of cycles of the perturbing potential.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Electrochemical facetting of metals
Pulsating diffusional boundary layers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/122107
Acceder
id SEDICI_9d0c90c5a3c556a3cc5f1ade187e6338
oai_identifier_str oai:sedici.unlp.edu.ar:10915/122107
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrodeMarchiano, Susana LucyRebollo Neira, L.Arvia, Alejandro JorgeCiencias ExactasQuímicaElectrochemical facetting of metalsPulsating diffusional boundary layersThe concentration profiles of reacting species at the electrode—solution interface under a periodic square wave perturbing potential are calculated by solving the diffusion equation for the case of a fast reversible metal—metal ion reaction. This situation is particularly interesting in the electrochemical facetting of metals. The model explains the dependence of current density and charge density on the frequency and number of cycles of the perturbing potential.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1990-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf483-487http://sedici.unlp.edu.ar/handle/10915/122107enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/001346869087033Xinfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(90)87033-Xinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:29:03Zoai:sedici.unlp.edu.ar:10915/122107Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:29:04.216SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
spellingShingle Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
Marchiano, Susana Lucy
Ciencias Exactas
Química
Electrochemical facetting of metals
Pulsating diffusional boundary layers
title_short Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_full Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_fullStr Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_full_unstemmed Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_sort Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
dc.creator.none.fl_str_mv Marchiano, Susana Lucy
Rebollo Neira, L.
Arvia, Alejandro Jorge
author Marchiano, Susana Lucy
author_facet Marchiano, Susana Lucy
Rebollo Neira, L.
Arvia, Alejandro Jorge
author_role author
author2 Rebollo Neira, L.
Arvia, Alejandro Jorge
author2_role author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Electrochemical facetting of metals
Pulsating diffusional boundary layers
topic Ciencias Exactas
Química
Electrochemical facetting of metals
Pulsating diffusional boundary layers
dc.description.none.fl_txt_mv The concentration profiles of reacting species at the electrode—solution interface under a periodic square wave perturbing potential are calculated by solving the diffusion equation for the case of a fast reversible metal—metal ion reaction. This situation is particularly interesting in the electrochemical facetting of metals. The model explains the dependence of current density and charge density on the frequency and number of cycles of the perturbing potential.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The concentration profiles of reacting species at the electrode—solution interface under a periodic square wave perturbing potential are calculated by solving the diffusion equation for the case of a fast reversible metal—metal ion reaction. This situation is particularly interesting in the electrochemical facetting of metals. The model explains the dependence of current density and charge density on the frequency and number of cycles of the perturbing potential.
publishDate 1990
dc.date.none.fl_str_mv 1990-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/122107
url http://sedici.unlp.edu.ar/handle/10915/122107
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/001346869087033X
info:eu-repo/semantics/altIdentifier/issn/0013-4686
info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(90)87033-X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
483-487
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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