Electrochemical Deposition onto Self-Assembled Monolayers

Autores
Schilardi, Patricia Laura; Dip, Patricio; Dos Santos Claro, Paula Cecilia; Benitez, Guillermo Alfredo; Fonticelli, Mariano Hernán; Azzaroni, Omar; Salvarezza, Roberto Carlos
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Pattern transfer with high resolution is a frontier topic in the emerging field of nanotechnologies. Electrochemical molding is a possible route for nanopatterning metal, alloys and oxide surfaces with high resolution in a simple and inexpensive way. This method involves electrodeposition onto a conducting master covered by a self-assembled alkanethiolate monolayer (SAMs). This molecular film enables direct surface–relief pattern transfer from the conducting master to the inner face of the electrodeposit, and also allows an easy release of the electrodeposited film due their excellent anti-adherent properties. Replicas of the original conductive master can be also obtained by a simple two-step procedure. SAM quality and stability under electrodeposition conditions combined with the formation of smooth electrodeposits are crucial to obtain high-quality pattern transfer with sub-50 nm resolution.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
alloys
electrochemistry
metal
nanotechnology
oxides
self-assembled monolayers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/159811

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network_name_str SEDICI (UNLP)
spelling Electrochemical Deposition onto Self-Assembled MonolayersSchilardi, Patricia LauraDip, PatricioDos Santos Claro, Paula CeciliaBenitez, Guillermo AlfredoFonticelli, Mariano HernánAzzaroni, OmarSalvarezza, Roberto CarlosCiencias ExactasQuímicaalloyselectrochemistrymetalnanotechnologyoxidesself-assembled monolayersPattern transfer with high resolution is a frontier topic in the emerging field of nanotechnologies. Electrochemical molding is a possible route for nanopatterning metal, alloys and oxide surfaces with high resolution in a simple and inexpensive way. This method involves electrodeposition onto a conducting master covered by a self-assembled alkanethiolate monolayer (SAMs). This molecular film enables direct surface–relief pattern transfer from the conducting master to the inner face of the electrodeposit, and also allows an easy release of the electrodeposited film due their excellent anti-adherent properties. Replicas of the original conductive master can be also obtained by a simple two-step procedure. SAM quality and stability under electrodeposition conditions combined with the formation of smooth electrodeposits are crucial to obtain high-quality pattern transfer with sub-50 nm resolution.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2005-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf38-49http://sedici.unlp.edu.ar/handle/10915/159811enginfo:eu-repo/semantics/altIdentifier/issn/0947-6539info:eu-repo/semantics/altIdentifier/issn/1521-3765info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.200500203info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T11:13:48Zoai:sedici.unlp.edu.ar:10915/159811Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 11:13:48.703SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Electrochemical Deposition onto Self-Assembled Monolayers
title Electrochemical Deposition onto Self-Assembled Monolayers
spellingShingle Electrochemical Deposition onto Self-Assembled Monolayers
Schilardi, Patricia Laura
Ciencias Exactas
Química
alloys
electrochemistry
metal
nanotechnology
oxides
self-assembled monolayers
title_short Electrochemical Deposition onto Self-Assembled Monolayers
title_full Electrochemical Deposition onto Self-Assembled Monolayers
title_fullStr Electrochemical Deposition onto Self-Assembled Monolayers
title_full_unstemmed Electrochemical Deposition onto Self-Assembled Monolayers
title_sort Electrochemical Deposition onto Self-Assembled Monolayers
dc.creator.none.fl_str_mv Schilardi, Patricia Laura
Dip, Patricio
Dos Santos Claro, Paula Cecilia
Benitez, Guillermo Alfredo
Fonticelli, Mariano Hernán
Azzaroni, Omar
Salvarezza, Roberto Carlos
author Schilardi, Patricia Laura
author_facet Schilardi, Patricia Laura
Dip, Patricio
Dos Santos Claro, Paula Cecilia
Benitez, Guillermo Alfredo
Fonticelli, Mariano Hernán
Azzaroni, Omar
Salvarezza, Roberto Carlos
author_role author
author2 Dip, Patricio
Dos Santos Claro, Paula Cecilia
Benitez, Guillermo Alfredo
Fonticelli, Mariano Hernán
Azzaroni, Omar
Salvarezza, Roberto Carlos
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
alloys
electrochemistry
metal
nanotechnology
oxides
self-assembled monolayers
topic Ciencias Exactas
Química
alloys
electrochemistry
metal
nanotechnology
oxides
self-assembled monolayers
dc.description.none.fl_txt_mv Pattern transfer with high resolution is a frontier topic in the emerging field of nanotechnologies. Electrochemical molding is a possible route for nanopatterning metal, alloys and oxide surfaces with high resolution in a simple and inexpensive way. This method involves electrodeposition onto a conducting master covered by a self-assembled alkanethiolate monolayer (SAMs). This molecular film enables direct surface–relief pattern transfer from the conducting master to the inner face of the electrodeposit, and also allows an easy release of the electrodeposited film due their excellent anti-adherent properties. Replicas of the original conductive master can be also obtained by a simple two-step procedure. SAM quality and stability under electrodeposition conditions combined with the formation of smooth electrodeposits are crucial to obtain high-quality pattern transfer with sub-50 nm resolution.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description Pattern transfer with high resolution is a frontier topic in the emerging field of nanotechnologies. Electrochemical molding is a possible route for nanopatterning metal, alloys and oxide surfaces with high resolution in a simple and inexpensive way. This method involves electrodeposition onto a conducting master covered by a self-assembled alkanethiolate monolayer (SAMs). This molecular film enables direct surface–relief pattern transfer from the conducting master to the inner face of the electrodeposit, and also allows an easy release of the electrodeposited film due their excellent anti-adherent properties. Replicas of the original conductive master can be also obtained by a simple two-step procedure. SAM quality and stability under electrodeposition conditions combined with the formation of smooth electrodeposits are crucial to obtain high-quality pattern transfer with sub-50 nm resolution.
publishDate 2005
dc.date.none.fl_str_mv 2005-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/159811
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dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0947-6539
info:eu-repo/semantics/altIdentifier/issn/1521-3765
info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.200500203
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
38-49
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
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institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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