Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process
- Autores
- Cotes, Sonia Marcela; Fernández Guillermet, Armando; Sade, Marcos
- Año de publicación
- 2004
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This article, which continues the series started by Cotes et al. (Metall. Mater. Trans. A , 1995, vol. 26A, p. 1957-69), presents a study of the energetics of the heterogeneous nucleation of hcp martensite in the fcc matrix of the Fe-Mn system. A major goal of the work is the exploration of the various qualitative and quantitative consequences of applying the Olson and Cohen approach (OCA) to the most reliable information on the Fe-Mn system. To this end, an extensive assessment of the quantities involved in the OCA is performed. The selected Gibbs energy and the lattice parameter descriptions for fcc and hcp are based on recent experimental studies. Explicit calculations are presented of the key quantities in the OCA, including those quantities that have not yet been measured. In particular, a probable range of values is established for the surface energy parameter σ, which plays a crucial role in the treatment of the nucleation size. On these bases, values are derived for the probable number of atomic planes ( n C) of the embryo, which, according to the OCA, is at the condition of spontaneous growth. Predictions of the Mn content upon n C are also reported. The present attempt to calculate in detail the energetics of the fcc -hcp martensitic transformation also revealed the lack of thermophysical data for Fe-Mn alloys. The need for experimental studies of various relevant quantities is emphasized.
Facultad de Ciencias Exactas - Materia
-
Química
heterogeneous nucleation of hcp martensite
Fe-Mn system
Fe-Mn alloys - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/133106
Ver los metadatos del registro completo
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Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation processCotes, Sonia MarcelaFernández Guillermet, ArmandoSade, MarcosQuímicaheterogeneous nucleation of hcp martensiteFe-Mn systemFe-Mn alloysThis article, which continues the series started by Cotes <i>et al.</i> (<i>Metall. Mater. Trans. A</i> , 1995, vol. 26A, p. 1957-69), presents a study of the energetics of the heterogeneous nucleation of hcp martensite in the fcc matrix of the Fe-Mn system. A major goal of the work is the exploration of the various qualitative and quantitative consequences of applying the Olson and Cohen approach (OCA) to the most reliable information on the Fe-Mn system. To this end, an extensive assessment of the quantities involved in the OCA is performed. The selected Gibbs energy and the lattice parameter descriptions for fcc and hcp are based on recent experimental studies. Explicit calculations are presented of the key quantities in the OCA, including those quantities that have not yet been measured. In particular, a probable range of values is established for the surface energy parameter σ, which plays a crucial role in the treatment of the nucleation size. On these bases, values are derived for the probable number of atomic planes ( n <sub>C</sub>) of the embryo, which, according to the OCA, is at the condition of spontaneous growth. Predictions of the Mn content upon n <sub>C</sub> are also reported. The present attempt to calculate in detail the energetics of the fcc <sup>-</sup>hcp martensitic transformation also revealed the lack of thermophysical data for Fe-Mn alloys. The need for experimental studies of various relevant quantities is emphasized.Facultad de Ciencias Exactas2004info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf83-91http://sedici.unlp.edu.ar/handle/10915/133106enginfo:eu-repo/semantics/altIdentifier/issn/1073-5623info:eu-repo/semantics/altIdentifier/issn/1543-1940info:eu-repo/semantics/altIdentifier/doi/10.1007/s11661-004-0111-yinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:31:43Zoai:sedici.unlp.edu.ar:10915/133106Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:31:43.46SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
title |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
spellingShingle |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process Cotes, Sonia Marcela Química heterogeneous nucleation of hcp martensite Fe-Mn system Fe-Mn alloys |
title_short |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
title_full |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
title_fullStr |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
title_full_unstemmed |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
title_sort |
Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process |
dc.creator.none.fl_str_mv |
Cotes, Sonia Marcela Fernández Guillermet, Armando Sade, Marcos |
author |
Cotes, Sonia Marcela |
author_facet |
Cotes, Sonia Marcela Fernández Guillermet, Armando Sade, Marcos |
author_role |
author |
author2 |
Fernández Guillermet, Armando Sade, Marcos |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Química heterogeneous nucleation of hcp martensite Fe-Mn system Fe-Mn alloys |
topic |
Química heterogeneous nucleation of hcp martensite Fe-Mn system Fe-Mn alloys |
dc.description.none.fl_txt_mv |
This article, which continues the series started by Cotes <i>et al.</i> (<i>Metall. Mater. Trans. A</i> , 1995, vol. 26A, p. 1957-69), presents a study of the energetics of the heterogeneous nucleation of hcp martensite in the fcc matrix of the Fe-Mn system. A major goal of the work is the exploration of the various qualitative and quantitative consequences of applying the Olson and Cohen approach (OCA) to the most reliable information on the Fe-Mn system. To this end, an extensive assessment of the quantities involved in the OCA is performed. The selected Gibbs energy and the lattice parameter descriptions for fcc and hcp are based on recent experimental studies. Explicit calculations are presented of the key quantities in the OCA, including those quantities that have not yet been measured. In particular, a probable range of values is established for the surface energy parameter σ, which plays a crucial role in the treatment of the nucleation size. On these bases, values are derived for the probable number of atomic planes ( n <sub>C</sub>) of the embryo, which, according to the OCA, is at the condition of spontaneous growth. Predictions of the Mn content upon n <sub>C</sub> are also reported. The present attempt to calculate in detail the energetics of the fcc <sup>-</sup>hcp martensitic transformation also revealed the lack of thermophysical data for Fe-Mn alloys. The need for experimental studies of various relevant quantities is emphasized. Facultad de Ciencias Exactas |
description |
This article, which continues the series started by Cotes <i>et al.</i> (<i>Metall. Mater. Trans. A</i> , 1995, vol. 26A, p. 1957-69), presents a study of the energetics of the heterogeneous nucleation of hcp martensite in the fcc matrix of the Fe-Mn system. A major goal of the work is the exploration of the various qualitative and quantitative consequences of applying the Olson and Cohen approach (OCA) to the most reliable information on the Fe-Mn system. To this end, an extensive assessment of the quantities involved in the OCA is performed. The selected Gibbs energy and the lattice parameter descriptions for fcc and hcp are based on recent experimental studies. Explicit calculations are presented of the key quantities in the OCA, including those quantities that have not yet been measured. In particular, a probable range of values is established for the surface energy parameter σ, which plays a crucial role in the treatment of the nucleation size. On these bases, values are derived for the probable number of atomic planes ( n <sub>C</sub>) of the embryo, which, according to the OCA, is at the condition of spontaneous growth. Predictions of the Mn content upon n <sub>C</sub> are also reported. The present attempt to calculate in detail the energetics of the fcc <sup>-</sup>hcp martensitic transformation also revealed the lack of thermophysical data for Fe-Mn alloys. The need for experimental studies of various relevant quantities is emphasized. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004 |
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http://sedici.unlp.edu.ar/handle/10915/133106 |
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eng |
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