Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
- Autores
- Vassallo, Marta Beatriz; Botto, Irma Lía
- Año de publicación
- 1992
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The thermal behaviour of the MH₂(IO₃)₃ (M=K, Rb and NH₄) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I₃O₈]− polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations.
Facultad de Ciencias Exactas - Materia
-
Química
Isomorphous compounds
Solid protonic conductors
TG
DTA
XRD
IR - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/142626
Ver los metadatos del registro completo
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Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)Vassallo, Marta BeatrizBotto, Irma LíaQuímicaIsomorphous compoundsSolid protonic conductorsTGDTAXRDIRThe thermal behaviour of the MH₂(IO₃)₃ (M=K, Rb and NH₄) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I₃O₈]− polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations.Facultad de Ciencias Exactas1992info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf2593-2602http://sedici.unlp.edu.ar/handle/10915/142626enginfo:eu-repo/semantics/altIdentifier/issn/0368-4466info:eu-repo/semantics/altIdentifier/issn/1572-8943info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01979735info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:24:29Zoai:sedici.unlp.edu.ar:10915/142626Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:24:30.026SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| title |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| spellingShingle |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) Vassallo, Marta Beatriz Química Isomorphous compounds Solid protonic conductors TG DTA XRD IR |
| title_short |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| title_full |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| title_fullStr |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| title_full_unstemmed |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| title_sort |
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄) |
| dc.creator.none.fl_str_mv |
Vassallo, Marta Beatriz Botto, Irma Lía |
| author |
Vassallo, Marta Beatriz |
| author_facet |
Vassallo, Marta Beatriz Botto, Irma Lía |
| author_role |
author |
| author2 |
Botto, Irma Lía |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Química Isomorphous compounds Solid protonic conductors TG DTA XRD IR |
| topic |
Química Isomorphous compounds Solid protonic conductors TG DTA XRD IR |
| dc.description.none.fl_txt_mv |
The thermal behaviour of the MH₂(IO₃)₃ (M=K, Rb and NH₄) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I₃O₈]− polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations. Facultad de Ciencias Exactas |
| description |
The thermal behaviour of the MH₂(IO₃)₃ (M=K, Rb and NH₄) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I₃O₈]− polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations. |
| publishDate |
1992 |
| dc.date.none.fl_str_mv |
1992 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
| status_str |
publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/142626 |
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http://sedici.unlp.edu.ar/handle/10915/142626 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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info:eu-repo/semantics/altIdentifier/issn/0368-4466 info:eu-repo/semantics/altIdentifier/issn/1572-8943 info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01979735 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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