A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity

Autores
León Boigues, Laia; Bilderling, Catalina von; Pietrasanta, Lía I.; Azzaroni, Omar; Giussi, Juan Martín; Mijangos, Carmen
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young’s modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Química
anodic aluminum oxide template
free radical copolymerization
swelling and mechanical properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/107776
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/107776
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling CapacityLeón Boigues, LaiaBilderling, Catalina vonPietrasanta, Lía I.Azzaroni, OmarGiussi, Juan MartínMijangos, CarmenQuímicaanodic aluminum oxide templatefree radical copolymerizationswelling and mechanical propertiesThe tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young’s modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/107776enginfo:eu-repo/semantics/altIdentifier/url/http://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC6419064&blobtype=pdfinfo:eu-repo/semantics/altIdentifier/issn/2073-4360info:eu-repo/semantics/altIdentifier/pmid/30960274info:eu-repo/semantics/altIdentifier/doi/10.3390/polym11020290info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:15:46Zoai:sedici.unlp.edu.ar:10915/107776Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:15:46.873SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
title A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
spellingShingle A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
León Boigues, Laia
Química
anodic aluminum oxide template
free radical copolymerization
swelling and mechanical properties
title_short A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
title_full A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
title_fullStr A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
title_full_unstemmed A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
title_sort A Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity
dc.creator.none.fl_str_mv León Boigues, Laia
Bilderling, Catalina von
Pietrasanta, Lía I.
Azzaroni, Omar
Giussi, Juan Martín
Mijangos, Carmen
author León Boigues, Laia
author_facet León Boigues, Laia
Bilderling, Catalina von
Pietrasanta, Lía I.
Azzaroni, Omar
Giussi, Juan Martín
Mijangos, Carmen
author_role author
author2 Bilderling, Catalina von
Pietrasanta, Lía I.
Azzaroni, Omar
Giussi, Juan Martín
Mijangos, Carmen
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Química
anodic aluminum oxide template
free radical copolymerization
swelling and mechanical properties
topic Química
anodic aluminum oxide template
free radical copolymerization
swelling and mechanical properties
dc.description.none.fl_txt_mv The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young’s modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young’s modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture.
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/107776
url http://sedici.unlp.edu.ar/handle/10915/107776
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC6419064&blobtype=pdf
info:eu-repo/semantics/altIdentifier/issn/2073-4360
info:eu-repo/semantics/altIdentifier/pmid/30960274
info:eu-repo/semantics/altIdentifier/doi/10.3390/polym11020290
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.22299

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