The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple
- Autores
- Gomez Meier, Humberto; Vilche, Jorge Roberto; Arvia, Alejandro Jorge
- Año de publicación
- 1982
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The potentiodynamic response of cobalt in KOH solutions (10−2 M⩽c⩽2.5 M) in the potential range of the thermodynamic stability of the Co(II) species reveals two limiting electrochemical behavirours. One of them corresponds to the first potentiodynamic scan and the other is associated with the stabilized E/I profile resulting after a prolonged potential scanning. The former is related to the large contribution of the metal electrodissolution process. The second is explained in terms of reactions taking place at the sandwich-type structured interface. Ageing effects of Co(II) surface species are also considered in the interpretation of results.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ciencias Exactas - Materia
-
Ciencias Exactas
Química
Electroquímica
Cobalto
potentiodynamic
Termodinámica
Metales Alcalinos
Níquel - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/81450
Ver los metadatos del registro completo
| id |
SEDICI_6942e97fa7b6f8a7b845b93ce51fce37 |
|---|---|
| oai_identifier_str |
oai:sedici.unlp.edu.ar:10915/81450 |
| network_acronym_str |
SEDICI |
| repository_id_str |
1329 |
| network_name_str |
SEDICI (UNLP) |
| spelling |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO coupleGomez Meier, HumbertoVilche, Jorge RobertoArvia, Alejandro JorgeCiencias ExactasQuímicaElectroquímicaCobaltopotentiodynamicTermodinámicaMetales AlcalinosNíquelThe potentiodynamic response of cobalt in KOH solutions (10<sup>−2</sup> <i>M⩽c⩽2.5 M</i>) in the potential range of the thermodynamic stability of the Co(II) species reveals two limiting electrochemical behavirours. One of them corresponds to the first potentiodynamic scan and the other is associated with the stabilized <i>E/I</i> profile resulting after a prolonged potential scanning. The former is related to the large contribution of the metal electrodissolution process. The second is explained in terms of reactions taking place at the sandwich-type structured interface. Ageing effects of Co(II) surface species are also considered in the interpretation of results.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de Ciencias Exactas1982-04-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf251-272http://sedici.unlp.edu.ar/handle/10915/81450enginfo:eu-repo/semantics/altIdentifier/issn/0022-0728info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(82)80005-3info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:07:06Zoai:sedici.unlp.edu.ar:10915/81450Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:07:06.764SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| title |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| spellingShingle |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple Gomez Meier, Humberto Ciencias Exactas Química Electroquímica Cobalto potentiodynamic Termodinámica Metales Alcalinos Níquel |
| title_short |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| title_full |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| title_fullStr |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| title_full_unstemmed |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| title_sort |
The electrochemical behaviour of cobalt in alkaline solutions : Part I. The potentiodynamic response in the potential region of the Co/CoO couple |
| dc.creator.none.fl_str_mv |
Gomez Meier, Humberto Vilche, Jorge Roberto Arvia, Alejandro Jorge |
| author |
Gomez Meier, Humberto |
| author_facet |
Gomez Meier, Humberto Vilche, Jorge Roberto Arvia, Alejandro Jorge |
| author_role |
author |
| author2 |
Vilche, Jorge Roberto Arvia, Alejandro Jorge |
| author2_role |
author author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas Química Electroquímica Cobalto potentiodynamic Termodinámica Metales Alcalinos Níquel |
| topic |
Ciencias Exactas Química Electroquímica Cobalto potentiodynamic Termodinámica Metales Alcalinos Níquel |
| dc.description.none.fl_txt_mv |
The potentiodynamic response of cobalt in KOH solutions (10<sup>−2</sup> <i>M⩽c⩽2.5 M</i>) in the potential range of the thermodynamic stability of the Co(II) species reveals two limiting electrochemical behavirours. One of them corresponds to the first potentiodynamic scan and the other is associated with the stabilized <i>E/I</i> profile resulting after a prolonged potential scanning. The former is related to the large contribution of the metal electrodissolution process. The second is explained in terms of reactions taking place at the sandwich-type structured interface. Ageing effects of Co(II) surface species are also considered in the interpretation of results. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Facultad de Ciencias Exactas |
| description |
The potentiodynamic response of cobalt in KOH solutions (10<sup>−2</sup> <i>M⩽c⩽2.5 M</i>) in the potential range of the thermodynamic stability of the Co(II) species reveals two limiting electrochemical behavirours. One of them corresponds to the first potentiodynamic scan and the other is associated with the stabilized <i>E/I</i> profile resulting after a prolonged potential scanning. The former is related to the large contribution of the metal electrodissolution process. The second is explained in terms of reactions taking place at the sandwich-type structured interface. Ageing effects of Co(II) surface species are also considered in the interpretation of results. |
| publishDate |
1982 |
| dc.date.none.fl_str_mv |
1982-04-09 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/81450 |
| url |
http://sedici.unlp.edu.ar/handle/10915/81450 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0022-0728 info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(82)80005-3 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
| eu_rights_str_mv |
openAccess |
| rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
| dc.format.none.fl_str_mv |
application/pdf 251-272 |
| dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
| reponame_str |
SEDICI (UNLP) |
| collection |
SEDICI (UNLP) |
| instname_str |
Universidad Nacional de La Plata |
| instacron_str |
UNLP |
| institution |
UNLP |
| repository.name.fl_str_mv |
SEDICI (UNLP) - Universidad Nacional de La Plata |
| repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
| _version_ |
1846064126511546368 |
| score |
13.22299 |