Solid films and interfaces in fused salt electrochemical systems
- Autores
- Arvia, Alejandro Jorge; Tacconi, Norma R. de
- Año de publicación
- 1977
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
thin solid films
electroformation
fused salt - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/126600
Ver los metadatos del registro completo
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Solid films and interfaces in fused salt electrochemical systemsArvia, Alejandro JorgeTacconi, Norma R. deCiencias ExactasQuímicathin solid filmselectroformationfused saltThe present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1977-05-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf173-187http://sedici.unlp.edu.ar/handle/10915/126600enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0040609077903844info:eu-repo/semantics/altIdentifier/issn/0040-6090info:eu-repo/semantics/altIdentifier/doi/10.1016/0040-6090(77)90384-4info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:11:25Zoai:sedici.unlp.edu.ar:10915/126600Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:11:26.264SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Solid films and interfaces in fused salt electrochemical systems |
| title |
Solid films and interfaces in fused salt electrochemical systems |
| spellingShingle |
Solid films and interfaces in fused salt electrochemical systems Arvia, Alejandro Jorge Ciencias Exactas Química thin solid films electroformation fused salt |
| title_short |
Solid films and interfaces in fused salt electrochemical systems |
| title_full |
Solid films and interfaces in fused salt electrochemical systems |
| title_fullStr |
Solid films and interfaces in fused salt electrochemical systems |
| title_full_unstemmed |
Solid films and interfaces in fused salt electrochemical systems |
| title_sort |
Solid films and interfaces in fused salt electrochemical systems |
| dc.creator.none.fl_str_mv |
Arvia, Alejandro Jorge Tacconi, Norma R. de |
| author |
Arvia, Alejandro Jorge |
| author_facet |
Arvia, Alejandro Jorge Tacconi, Norma R. de |
| author_role |
author |
| author2 |
Tacconi, Norma R. de |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas Química thin solid films electroformation fused salt |
| topic |
Ciencias Exactas Química thin solid films electroformation fused salt |
| dc.description.none.fl_txt_mv |
The present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
| description |
The present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces. |
| publishDate |
1977 |
| dc.date.none.fl_str_mv |
1977-05-16 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/126600 |
| url |
http://sedici.unlp.edu.ar/handle/10915/126600 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0040609077903844 info:eu-repo/semantics/altIdentifier/issn/0040-6090 info:eu-repo/semantics/altIdentifier/doi/10.1016/0040-6090(77)90384-4 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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application/pdf 173-187 |
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