Solid films and interfaces in fused salt electrochemical systems

Autores
Arvia, Alejandro Jorge; Tacconi, Norma R. de
Año de publicación
1977
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
thin solid films
electroformation
fused salt
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/126600

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network_name_str SEDICI (UNLP)
spelling Solid films and interfaces in fused salt electrochemical systemsArvia, Alejandro JorgeTacconi, Norma R. deCiencias ExactasQuímicathin solid filmselectroformationfused saltThe present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1977-05-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf173-187http://sedici.unlp.edu.ar/handle/10915/126600enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0040609077903844info:eu-repo/semantics/altIdentifier/issn/0040-6090info:eu-repo/semantics/altIdentifier/doi/10.1016/0040-6090(77)90384-4info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:30:32Zoai:sedici.unlp.edu.ar:10915/126600Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:30:33.063SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Solid films and interfaces in fused salt electrochemical systems
title Solid films and interfaces in fused salt electrochemical systems
spellingShingle Solid films and interfaces in fused salt electrochemical systems
Arvia, Alejandro Jorge
Ciencias Exactas
Química
thin solid films
electroformation
fused salt
title_short Solid films and interfaces in fused salt electrochemical systems
title_full Solid films and interfaces in fused salt electrochemical systems
title_fullStr Solid films and interfaces in fused salt electrochemical systems
title_full_unstemmed Solid films and interfaces in fused salt electrochemical systems
title_sort Solid films and interfaces in fused salt electrochemical systems
dc.creator.none.fl_str_mv Arvia, Alejandro Jorge
Tacconi, Norma R. de
author Arvia, Alejandro Jorge
author_facet Arvia, Alejandro Jorge
Tacconi, Norma R. de
author_role author
author2 Tacconi, Norma R. de
author2_role author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
thin solid films
electroformation
fused salt
topic Ciencias Exactas
Química
thin solid films
electroformation
fused salt
dc.description.none.fl_txt_mv The present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The present review deals with two main aspects of the electrochemical formation and characteristics of thin solid films. The first shows, through a few typical examples, that these films occur at different metal-molten electrolyte interfaces and that their average composition depends on how they are formed, i.e. anodically or cathodically. The second aspect deals with the kinetics of thin film formation. The first reaction, which has undoubtedly been the more thoroughly investigated, involves the early stages in the formation of an oxygen monolayer on platinum in molten alkali bisulphates. The electrochemical features of this interface are also found at other metal-molten electrolyte interfaces. Finally, the kinetics of multilayer thin film electroformation are presented to show that the nucleation and film growth laws derived for film formation at metal-solution interfaces also apply to metal-melt interfaces.
publishDate 1977
dc.date.none.fl_str_mv 1977-05-16
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/126600
url http://sedici.unlp.edu.ar/handle/10915/126600
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0040609077903844
info:eu-repo/semantics/altIdentifier/issn/0040-6090
info:eu-repo/semantics/altIdentifier/doi/10.1016/0040-6090(77)90384-4
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
173-187
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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