Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat

Autores
Ferrer, Evelina Gloria; Etcheverry, Susana Beatriz; Baran, Enrique José
Año de publicación
1993
Idioma
indeterminado
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
Facultad de Ciencias Exactas
Materia
Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/146414
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/146414
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repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Darstellung und Eigenschaften von Vanadyl(IV)-SaccharinatFerrer, Evelina GloriaEtcheverry, Susana BeatrizBaran, Enrique JoséQuímicaVanadyl(IV) saccharinateIR spectraElectronic spectraMagnetic and thermal behaviourThe synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.Facultad de Ciencias Exactas1993-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf355-366http://sedici.unlp.edu.ar/handle/10915/146414undinfo:eu-repo/semantics/altIdentifier/issn/0026-9247info:eu-repo/semantics/altIdentifier/issn/1434-4475info:eu-repo/semantics/altIdentifier/issn/0343-7329info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00814132info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-11-05T13:11:46Zoai:sedici.unlp.edu.ar:10915/146414Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-11-05 13:11:47.098SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
spellingShingle Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
Ferrer, Evelina Gloria
Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
title_short Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_full Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_fullStr Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_full_unstemmed Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_sort Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
dc.creator.none.fl_str_mv Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
author Ferrer, Evelina Gloria
author_facet Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
author_role author
author2 Etcheverry, Susana Beatriz
Baran, Enrique José
author2_role author
author
dc.subject.none.fl_str_mv Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
topic Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
dc.description.none.fl_txt_mv The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
Facultad de Ciencias Exactas
description The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
publishDate 1993
dc.date.none.fl_str_mv 1993-04-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146414
url http://sedici.unlp.edu.ar/handle/10915/146414
dc.language.none.fl_str_mv und
language und
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0026-9247
info:eu-repo/semantics/altIdentifier/issn/1434-4475
info:eu-repo/semantics/altIdentifier/issn/0343-7329
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00814132
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
355-366
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.142177

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