Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions

Autores
Mártin, Daniel A.; Cavagna, Andrea; Grigera, Tomás Sebastián
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We study the specific heat of a model supercooled liquid confined in a spherical cavity with amorphous boundary conditions. We find the equilibrium specific heat has a cavity-size-dependent peak as a function of temperature. The cavity allows us to perform a finite-size scaling (FSS) analysis, which indicates that the peak persists at a finite temperature in the thermodynamic limit. We attempt to collapse the data onto a FSS curve according to different theoretical scenarios, obtaining reasonable results in two cases: a "not-so-simple" liquid with nonstandard values of the exponents α and ν, and random first-order theory, with two different length scales.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ingeniería
Facultad de Ciencias Exactas
Materia
Física
Boundary conditions
Cavity
Liquids
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/86680

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network_name_str SEDICI (UNLP)
spelling Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary ConditionsMártin, Daniel A.Cavagna, AndreaGrigera, Tomás SebastiánFísicaBoundary conditionsCavityLiquidsWe study the specific heat of a model supercooled liquid confined in a spherical cavity with amorphous boundary conditions. We find the equilibrium specific heat has a cavity-size-dependent peak as a function of temperature. The cavity allows us to perform a finite-size scaling (FSS) analysis, which indicates that the peak persists at a finite temperature in the thermodynamic limit. We attempt to collapse the data onto a FSS curve according to different theoretical scenarios, obtaining reasonable results in two cases: a "not-so-simple" liquid with nonstandard values of the exponents α and ν, and random first-order theory, with two different length scales.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de IngenieríaFacultad de Ciencias Exactas2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/86680enginfo:eu-repo/semantics/altIdentifier/issn/0031-9007info:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevLett.114.225901info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:16:55Zoai:sedici.unlp.edu.ar:10915/86680Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:16:55.426SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
title Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
spellingShingle Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
Mártin, Daniel A.
Física
Boundary conditions
Cavity
Liquids
title_short Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
title_full Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
title_fullStr Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
title_full_unstemmed Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
title_sort Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
dc.creator.none.fl_str_mv Mártin, Daniel A.
Cavagna, Andrea
Grigera, Tomás Sebastián
author Mártin, Daniel A.
author_facet Mártin, Daniel A.
Cavagna, Andrea
Grigera, Tomás Sebastián
author_role author
author2 Cavagna, Andrea
Grigera, Tomás Sebastián
author2_role author
author
dc.subject.none.fl_str_mv Física
Boundary conditions
Cavity
Liquids
topic Física
Boundary conditions
Cavity
Liquids
dc.description.none.fl_txt_mv We study the specific heat of a model supercooled liquid confined in a spherical cavity with amorphous boundary conditions. We find the equilibrium specific heat has a cavity-size-dependent peak as a function of temperature. The cavity allows us to perform a finite-size scaling (FSS) analysis, which indicates that the peak persists at a finite temperature in the thermodynamic limit. We attempt to collapse the data onto a FSS curve according to different theoretical scenarios, obtaining reasonable results in two cases: a "not-so-simple" liquid with nonstandard values of the exponents α and ν, and random first-order theory, with two different length scales.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ingeniería
Facultad de Ciencias Exactas
description We study the specific heat of a model supercooled liquid confined in a spherical cavity with amorphous boundary conditions. We find the equilibrium specific heat has a cavity-size-dependent peak as a function of temperature. The cavity allows us to perform a finite-size scaling (FSS) analysis, which indicates that the peak persists at a finite temperature in the thermodynamic limit. We attempt to collapse the data onto a FSS curve according to different theoretical scenarios, obtaining reasonable results in two cases: a "not-so-simple" liquid with nonstandard values of the exponents α and ν, and random first-order theory, with two different length scales.
publishDate 2015
dc.date.none.fl_str_mv 2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/86680
url http://sedici.unlp.edu.ar/handle/10915/86680
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0031-9007
info:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevLett.114.225901
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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