γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR...
- Autores
- Cabello, Carmen Inés; Botto, Irma Lía; Cabrerizo, Franco Martín; González, María Gloria; Thomas, Horacio Jorge
- Año de publicación
- 2000
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The support-overlayer adsorptive interactions, generated when solutions of Anderson heteropolyoxomolybdates were supported as a monolayer on γ-Al₂O₃ by means of the equilibrium adsorption method, were studied by XRD analysis, DR spectroscopy, electron microscopy (SEM-EDAX) and TPR methods. The adsorption isotherms and corresponding adsorption parameters (number of active sites and adsorption constants) of the γ-Al₂O₃-supported ammonium heptamolybdate were obtained and discussed. The following sequence of adsorption strength was suggested: CoMo₆ > CrMo₆ > TeMo₆ ~ AlMo₆ > NiMo₆. The effectiveness of the TPR technique as a tool for elucidating interaction effects was clearly demonstrated. The formation of a γ-Al₂O₃-supported Te-Mo mixed valence oxide appears to provide new and interesting catalytic possibilities.
Facultad de Ciencias Exactas
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Centro de Química Inorgánica - Materia
-
Ciencias Exactas
Química
Heteropolyoxomolybdates
adsorption - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/123748
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γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR AnalysisCabello, Carmen InésBotto, Irma LíaCabrerizo, Franco MartínGonzález, María GloriaThomas, Horacio JorgeCiencias ExactasQuímicaHeteropolyoxomolybdatesadsorptionThe support-overlayer adsorptive interactions, generated when solutions of Anderson heteropolyoxomolybdates were supported as a monolayer on γ-Al₂O₃ by means of the equilibrium adsorption method, were studied by XRD analysis, DR spectroscopy, electron microscopy (SEM-EDAX) and TPR methods. The adsorption isotherms and corresponding adsorption parameters (number of active sites and adsorption constants) of the γ-Al₂O₃-supported ammonium heptamolybdate were obtained and discussed. The following sequence of adsorption strength was suggested: CoMo₆ > CrMo₆ > TeMo₆ ~ AlMo₆ > NiMo₆. The effectiveness of the TPR technique as a tool for elucidating interaction effects was clearly demonstrated. The formation of a γ-Al₂O₃-supported Te-Mo mixed valence oxide appears to provide new and interesting catalytic possibilities.Facultad de Ciencias ExactasCentro de Investigación y Desarrollo en Ciencias AplicadasCentro de Química Inorgánica2000info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf591-608http://sedici.unlp.edu.ar/handle/10915/123748enginfo:eu-repo/semantics/altIdentifier/issn/0263-6174info:eu-repo/semantics/altIdentifier/issn/2048-4038info:eu-repo/semantics/altIdentifier/doi/10.1260/0263617001493657info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:29:29Zoai:sedici.unlp.edu.ar:10915/123748Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:29:29.671SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
title |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
spellingShingle |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis Cabello, Carmen Inés Ciencias Exactas Química Heteropolyoxomolybdates adsorption |
title_short |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
title_full |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
title_fullStr |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
title_full_unstemmed |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
title_sort |
γ-Al₂O₃-Supported XMo₆ Anderson Heteropolyoxomolybdates: Adsorption Studies for X = Te<sup>VI</sup>, Al<sup>III</sup>, Co<sup>III</sup>, Cr<sup>III</sup> and Ni<sup>II</sup> by DR Spectroscopy and TPR Analysis |
dc.creator.none.fl_str_mv |
Cabello, Carmen Inés Botto, Irma Lía Cabrerizo, Franco Martín González, María Gloria Thomas, Horacio Jorge |
author |
Cabello, Carmen Inés |
author_facet |
Cabello, Carmen Inés Botto, Irma Lía Cabrerizo, Franco Martín González, María Gloria Thomas, Horacio Jorge |
author_role |
author |
author2 |
Botto, Irma Lía Cabrerizo, Franco Martín González, María Gloria Thomas, Horacio Jorge |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Ciencias Exactas Química Heteropolyoxomolybdates adsorption |
topic |
Ciencias Exactas Química Heteropolyoxomolybdates adsorption |
dc.description.none.fl_txt_mv |
The support-overlayer adsorptive interactions, generated when solutions of Anderson heteropolyoxomolybdates were supported as a monolayer on γ-Al₂O₃ by means of the equilibrium adsorption method, were studied by XRD analysis, DR spectroscopy, electron microscopy (SEM-EDAX) and TPR methods. The adsorption isotherms and corresponding adsorption parameters (number of active sites and adsorption constants) of the γ-Al₂O₃-supported ammonium heptamolybdate were obtained and discussed. The following sequence of adsorption strength was suggested: CoMo₆ > CrMo₆ > TeMo₆ ~ AlMo₆ > NiMo₆. The effectiveness of the TPR technique as a tool for elucidating interaction effects was clearly demonstrated. The formation of a γ-Al₂O₃-supported Te-Mo mixed valence oxide appears to provide new and interesting catalytic possibilities. Facultad de Ciencias Exactas Centro de Investigación y Desarrollo en Ciencias Aplicadas Centro de Química Inorgánica |
description |
The support-overlayer adsorptive interactions, generated when solutions of Anderson heteropolyoxomolybdates were supported as a monolayer on γ-Al₂O₃ by means of the equilibrium adsorption method, were studied by XRD analysis, DR spectroscopy, electron microscopy (SEM-EDAX) and TPR methods. The adsorption isotherms and corresponding adsorption parameters (number of active sites and adsorption constants) of the γ-Al₂O₃-supported ammonium heptamolybdate were obtained and discussed. The following sequence of adsorption strength was suggested: CoMo₆ > CrMo₆ > TeMo₆ ~ AlMo₆ > NiMo₆. The effectiveness of the TPR technique as a tool for elucidating interaction effects was clearly demonstrated. The formation of a γ-Al₂O₃-supported Te-Mo mixed valence oxide appears to provide new and interesting catalytic possibilities. |
publishDate |
2000 |
dc.date.none.fl_str_mv |
2000 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/123748 |
url |
http://sedici.unlp.edu.ar/handle/10915/123748 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
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dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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application/pdf 591-608 |
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