Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid

Autores
Baran, Enrique José
Año de publicación
1972
Idioma
indeterminado
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In an earlier work we have theoretically derived and explained certain rules relating the v₁/v₃ frequency ratio of tetrahedral oxoanions of the transition metals with some basic properties of the anions. It is now demonstrated that these rules are also valid for oxoanions of the main group elements of the periodic system. Applying these and other relations it was possible to predict the value of the symmetric stretching frequency v₁ (A₁) of xenon tetroxide. Some vibrational properties of Xe0₄ (force constants, mean amplitudes of vibration, the Coriolis coupling constant and the bond order) are also calculated and compared with those of related species.
Publicado on line en 2014.
Facultad de Ciencias Exactas
Materia
Química
Oxoanions
Symmetric stretching frequency
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/3.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/120279
Acceder
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network_name_str SEDICI (UNLP)
spelling Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-TetroxidThe v₁/v₃ frequency ratio in tetrahedral oxoanions of the main group elements and the vibrational properties of xenon tetroxideBaran, Enrique JoséQuímicaOxoanionsSymmetric stretching frequencyIn an earlier work we have theoretically derived and explained certain rules relating the v₁/v₃ frequency ratio of tetrahedral oxoanions of the transition metals with some basic properties of the anions. It is now demonstrated that these rules are also valid for oxoanions of the main group elements of the periodic system. Applying these and other relations it was possible to predict the value of the symmetric stretching frequency v₁ (A₁) of xenon tetroxide. Some vibrational properties of Xe0₄ (force constants, mean amplitudes of vibration, the Coriolis coupling constant and the bond order) are also calculated and compared with those of related species.Publicado on line en 2014.Facultad de Ciencias Exactas1972info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1000-1004http://sedici.unlp.edu.ar/handle/10915/120279undinfo:eu-repo/semantics/altIdentifier/issn/1865-7109info:eu-repo/semantics/altIdentifier/doi/10.1515/zna-1972-0618info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/3.0/Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-17T10:11:12Zoai:sedici.unlp.edu.ar:10915/120279Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-17 10:11:13.012SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
The v₁/v₃ frequency ratio in tetrahedral oxoanions of the main group elements and the vibrational properties of xenon tetroxide
title Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
spellingShingle Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
Baran, Enrique José
Química
Oxoanions
Symmetric stretching frequency
title_short Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
title_full Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
title_fullStr Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
title_full_unstemmed Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
title_sort Das v₁/v₃-Frequenzen-Verhältnis bei tetraedrischen Oxoanionen der Hauptgruppenelemente und die Schwingungseigenschaften von Xenon-Tetroxid
dc.creator.none.fl_str_mv Baran, Enrique José
author Baran, Enrique José
author_facet Baran, Enrique José
author_role author
dc.subject.none.fl_str_mv Química
Oxoanions
Symmetric stretching frequency
topic Química
Oxoanions
Symmetric stretching frequency
dc.description.none.fl_txt_mv In an earlier work we have theoretically derived and explained certain rules relating the v₁/v₃ frequency ratio of tetrahedral oxoanions of the transition metals with some basic properties of the anions. It is now demonstrated that these rules are also valid for oxoanions of the main group elements of the periodic system. Applying these and other relations it was possible to predict the value of the symmetric stretching frequency v₁ (A₁) of xenon tetroxide. Some vibrational properties of Xe0₄ (force constants, mean amplitudes of vibration, the Coriolis coupling constant and the bond order) are also calculated and compared with those of related species.
Publicado on line en 2014.
Facultad de Ciencias Exactas
description In an earlier work we have theoretically derived and explained certain rules relating the v₁/v₃ frequency ratio of tetrahedral oxoanions of the transition metals with some basic properties of the anions. It is now demonstrated that these rules are also valid for oxoanions of the main group elements of the periodic system. Applying these and other relations it was possible to predict the value of the symmetric stretching frequency v₁ (A₁) of xenon tetroxide. Some vibrational properties of Xe0₄ (force constants, mean amplitudes of vibration, the Coriolis coupling constant and the bond order) are also calculated and compared with those of related species.
publishDate 1972
dc.date.none.fl_str_mv 1972
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/120279
url http://sedici.unlp.edu.ar/handle/10915/120279
dc.language.none.fl_str_mv und
language und
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1865-7109
info:eu-repo/semantics/altIdentifier/doi/10.1515/zna-1972-0618
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/3.0/
Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/3.0/
Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
dc.format.none.fl_str_mv application/pdf
1000-1004
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.001348

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