Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel
- Autores
- Navas, Marisa Belén; Lick, Ileana Daniela; Bolla, Patricia Araceli; Casella, Mónica Laura; Ruggera, José Fernando
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This paper focuses on the preparation and characterization of CaO, MgO and ZnO, both bulk and supported on γ-Al2O3 and their catalytic activity in the transesterification of soybean oil and castor oil with methanol and butanol in order to produce biodiesel. XRD, SEM, CO2-adsorption followed by TGA and N2 adsorption have been employed to characterize the prepared catalysts. In supported catalysts, the presence of γ-Al2O3 improves alcohol dissociation on the superficial basic sites. The first step of the reaction mechanism is then favored (hydrogen abstraction). In the transesterification of castor oil with butanol, MgO/γ -Al2O3 and ZnO/γ-Al2O3 catalysts showed high yields to FABE (Fatty Acid Butyl Ester) (97% and 85%, respectively). These last catalysts constitute an efficient alternative for obtaining second-generation biodiesel, taking into account that castor oil is a nonedible source and butanol is an alcohol that can be obtained from biomass.
Centro de Investigación y Desarrollo en Ciencias Aplicadas - Materia
-
Química
Ciencias Exactas
Biodiesel
Castor oil
Heterogeneous catalysts
Mixed metal oxide
Soybean oil
Transesterification - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/98231
Ver los metadatos del registro completo
id |
SEDICI_0b0381276a43a50b1ed6b26a9a4f0a4b |
---|---|
oai_identifier_str |
oai:sedici.unlp.edu.ar:10915/98231 |
network_acronym_str |
SEDICI |
repository_id_str |
1329 |
network_name_str |
SEDICI (UNLP) |
spelling |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodieselNavas, Marisa BelénLick, Ileana DanielaBolla, Patricia AraceliCasella, Mónica LauraRuggera, José FernandoQuímicaCiencias ExactasBiodieselCastor oilHeterogeneous catalystsMixed metal oxideSoybean oilTransesterificationThis paper focuses on the preparation and characterization of CaO, MgO and ZnO, both bulk and supported on γ-Al2O3 and their catalytic activity in the transesterification of soybean oil and castor oil with methanol and butanol in order to produce biodiesel. XRD, SEM, CO2-adsorption followed by TGA and N2 adsorption have been employed to characterize the prepared catalysts. In supported catalysts, the presence of γ-Al2O3 improves alcohol dissociation on the superficial basic sites. The first step of the reaction mechanism is then favored (hydrogen abstraction). In the transesterification of castor oil with butanol, MgO/γ -Al2O3 and ZnO/γ-Al2O3 catalysts showed high yields to FABE (Fatty Acid Butyl Ester) (97% and 85%, respectively). These last catalysts constitute an efficient alternative for obtaining second-generation biodiesel, taking into account that castor oil is a nonedible source and butanol is an alcohol that can be obtained from biomass.Centro de Investigación y Desarrollo en Ciencias Aplicadas2018-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf444-454http://sedici.unlp.edu.ar/handle/10915/98231enginfo:eu-repo/semantics/altIdentifier/url/https://ri.conicet.gov.ar/11336/85909info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250918302823?via%3Dihubinfo:eu-repo/semantics/altIdentifier/issn/0009-2509info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2018.04.068info:eu-repo/semantics/altIdentifier/hdl/11336/85909info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/2.5/ar/Creative Commons Attribution-NonCommercial-NoDerivs 2.5 Argentina (CC BY-NC-ND 2.5)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T10:52:46Zoai:sedici.unlp.edu.ar:10915/98231Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 10:52:46.339SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
title |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
spellingShingle |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel Navas, Marisa Belén Química Ciencias Exactas Biodiesel Castor oil Heterogeneous catalysts Mixed metal oxide Soybean oil Transesterification |
title_short |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
title_full |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
title_fullStr |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
title_full_unstemmed |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
title_sort |
Transesterification of soybean and castor oil with methanol and butanol using heterogeneous basic catalysts to obtain biodiesel |
dc.creator.none.fl_str_mv |
Navas, Marisa Belén Lick, Ileana Daniela Bolla, Patricia Araceli Casella, Mónica Laura Ruggera, José Fernando |
author |
Navas, Marisa Belén |
author_facet |
Navas, Marisa Belén Lick, Ileana Daniela Bolla, Patricia Araceli Casella, Mónica Laura Ruggera, José Fernando |
author_role |
author |
author2 |
Lick, Ileana Daniela Bolla, Patricia Araceli Casella, Mónica Laura Ruggera, José Fernando |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Química Ciencias Exactas Biodiesel Castor oil Heterogeneous catalysts Mixed metal oxide Soybean oil Transesterification |
topic |
Química Ciencias Exactas Biodiesel Castor oil Heterogeneous catalysts Mixed metal oxide Soybean oil Transesterification |
dc.description.none.fl_txt_mv |
This paper focuses on the preparation and characterization of CaO, MgO and ZnO, both bulk and supported on γ-Al2O3 and their catalytic activity in the transesterification of soybean oil and castor oil with methanol and butanol in order to produce biodiesel. XRD, SEM, CO2-adsorption followed by TGA and N2 adsorption have been employed to characterize the prepared catalysts. In supported catalysts, the presence of γ-Al2O3 improves alcohol dissociation on the superficial basic sites. The first step of the reaction mechanism is then favored (hydrogen abstraction). In the transesterification of castor oil with butanol, MgO/γ -Al2O3 and ZnO/γ-Al2O3 catalysts showed high yields to FABE (Fatty Acid Butyl Ester) (97% and 85%, respectively). These last catalysts constitute an efficient alternative for obtaining second-generation biodiesel, taking into account that castor oil is a nonedible source and butanol is an alcohol that can be obtained from biomass. Centro de Investigación y Desarrollo en Ciencias Aplicadas |
description |
This paper focuses on the preparation and characterization of CaO, MgO and ZnO, both bulk and supported on γ-Al2O3 and their catalytic activity in the transesterification of soybean oil and castor oil with methanol and butanol in order to produce biodiesel. XRD, SEM, CO2-adsorption followed by TGA and N2 adsorption have been employed to characterize the prepared catalysts. In supported catalysts, the presence of γ-Al2O3 improves alcohol dissociation on the superficial basic sites. The first step of the reaction mechanism is then favored (hydrogen abstraction). In the transesterification of castor oil with butanol, MgO/γ -Al2O3 and ZnO/γ-Al2O3 catalysts showed high yields to FABE (Fatty Acid Butyl Ester) (97% and 85%, respectively). These last catalysts constitute an efficient alternative for obtaining second-generation biodiesel, taking into account that castor oil is a nonedible source and butanol is an alcohol that can be obtained from biomass. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/98231 |
url |
http://sedici.unlp.edu.ar/handle/10915/98231 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://ri.conicet.gov.ar/11336/85909 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250918302823?via%3Dihub info:eu-repo/semantics/altIdentifier/issn/0009-2509 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2018.04.068 info:eu-repo/semantics/altIdentifier/hdl/11336/85909 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/2.5/ar/ Creative Commons Attribution-NonCommercial-NoDerivs 2.5 Argentina (CC BY-NC-ND 2.5) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-nd/2.5/ar/ Creative Commons Attribution-NonCommercial-NoDerivs 2.5 Argentina (CC BY-NC-ND 2.5) |
dc.format.none.fl_str_mv |
application/pdf 444-454 |
dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
reponame_str |
SEDICI (UNLP) |
collection |
SEDICI (UNLP) |
instname_str |
Universidad Nacional de La Plata |
instacron_str |
UNLP |
institution |
UNLP |
repository.name.fl_str_mv |
SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
_version_ |
1842260409880412160 |
score |
13.13397 |