Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques

Autores
Damonte, Laura Cristina; Rivas, Patricia Claudia; Pasquevich, Alberto Felipe; Andreola, Fernanda; Bondioli, Federica; Ferrari, Anna M.; Tositti, Laura; Cinelli, Giorgia
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In ceramic industry, zircon sand is widely used in different applications because zirconia plays a role as common opacifying constituent. In particular, it is used as a basic component of glazes applied to ceramic tiles and sanitary ware as well as an opacifier in unglazed bulk porcelain stoneware. Natural zircon sands are the major source of zirconium minerals for industrial applications. In this paper, long, medium, and short range studies were conducted on zirconium minerals originated from Australia, South Africa, and United States of America using conventional and less conventional techniques (i.e., X-Ray Diffraction (XRD), Positron Annihilation Lifetime Spectroscopy (PALS), and Perturbed Angular Correlations (PAC)) in order to reveal the type and the extension of the regions that constitute the metamict state of zircon sands and themodifications therein produced as a consequence of the industrial milling process and the thermal treatment in the production line. Additionally, HPGe gamma-ray spectroscopy confirms the occurrence of significant levels of natural radioactivity responsible for metamictization in the investigated zircon samples. Results from XRD, PALS, and PAC analysis confirm that the metamict state of zircon is a dispersion of submicron disordered domains in a crystalline matrix of zircon.
Facultad de Ciencias Exactas
Materia
Ciencias Exactas
Física
zirconium, XRD, PALS, PAC
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/68065

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spelling Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear TechniquesDamonte, Laura CristinaRivas, Patricia ClaudiaPasquevich, Alberto FelipeAndreola, FernandaBondioli, FedericaFerrari, Anna M.Tositti, LauraCinelli, GiorgiaCiencias ExactasFísicazirconium, XRD, PALS, PACIn ceramic industry, zircon sand is widely used in different applications because zirconia plays a role as common opacifying constituent. In particular, it is used as a basic component of glazes applied to ceramic tiles and sanitary ware as well as an opacifier in unglazed bulk porcelain stoneware. Natural zircon sands are the major source of zirconium minerals for industrial applications. In this paper, long, medium, and short range studies were conducted on zirconium minerals originated from Australia, South Africa, and United States of America using conventional and less conventional techniques (i.e., X-Ray Diffraction (XRD), Positron Annihilation Lifetime Spectroscopy (PALS), and Perturbed Angular Correlations (PAC)) in order to reveal the type and the extension of the regions that constitute the metamict state of zircon sands and themodifications therein produced as a consequence of the industrial milling process and the thermal treatment in the production line. Additionally, HPGe gamma-ray spectroscopy confirms the occurrence of significant levels of natural radioactivity responsible for metamictization in the investigated zircon samples. Results from XRD, PALS, and PAC analysis confirm that the metamict state of zircon is a dispersion of submicron disordered domains in a crystalline matrix of zircon.Facultad de Ciencias Exactas2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/68065enginfo:eu-repo/semantics/altIdentifier/url/https://www.hindawi.com/journals/acmp/2017/9707604/info:eu-repo/semantics/altIdentifier/doi/10.1155/2017/9707604info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:10:30Zoai:sedici.unlp.edu.ar:10915/68065Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:10:30.771SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
title Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
spellingShingle Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
Damonte, Laura Cristina
Ciencias Exactas
Física
zirconium, XRD, PALS, PAC
title_short Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
title_full Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
title_fullStr Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
title_full_unstemmed Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
title_sort Structural Characterization of Natural and Processed Zircons with X-Rays and Nuclear Techniques
dc.creator.none.fl_str_mv Damonte, Laura Cristina
Rivas, Patricia Claudia
Pasquevich, Alberto Felipe
Andreola, Fernanda
Bondioli, Federica
Ferrari, Anna M.
Tositti, Laura
Cinelli, Giorgia
author Damonte, Laura Cristina
author_facet Damonte, Laura Cristina
Rivas, Patricia Claudia
Pasquevich, Alberto Felipe
Andreola, Fernanda
Bondioli, Federica
Ferrari, Anna M.
Tositti, Laura
Cinelli, Giorgia
author_role author
author2 Rivas, Patricia Claudia
Pasquevich, Alberto Felipe
Andreola, Fernanda
Bondioli, Federica
Ferrari, Anna M.
Tositti, Laura
Cinelli, Giorgia
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Física
zirconium, XRD, PALS, PAC
topic Ciencias Exactas
Física
zirconium, XRD, PALS, PAC
dc.description.none.fl_txt_mv In ceramic industry, zircon sand is widely used in different applications because zirconia plays a role as common opacifying constituent. In particular, it is used as a basic component of glazes applied to ceramic tiles and sanitary ware as well as an opacifier in unglazed bulk porcelain stoneware. Natural zircon sands are the major source of zirconium minerals for industrial applications. In this paper, long, medium, and short range studies were conducted on zirconium minerals originated from Australia, South Africa, and United States of America using conventional and less conventional techniques (i.e., X-Ray Diffraction (XRD), Positron Annihilation Lifetime Spectroscopy (PALS), and Perturbed Angular Correlations (PAC)) in order to reveal the type and the extension of the regions that constitute the metamict state of zircon sands and themodifications therein produced as a consequence of the industrial milling process and the thermal treatment in the production line. Additionally, HPGe gamma-ray spectroscopy confirms the occurrence of significant levels of natural radioactivity responsible for metamictization in the investigated zircon samples. Results from XRD, PALS, and PAC analysis confirm that the metamict state of zircon is a dispersion of submicron disordered domains in a crystalline matrix of zircon.
Facultad de Ciencias Exactas
description In ceramic industry, zircon sand is widely used in different applications because zirconia plays a role as common opacifying constituent. In particular, it is used as a basic component of glazes applied to ceramic tiles and sanitary ware as well as an opacifier in unglazed bulk porcelain stoneware. Natural zircon sands are the major source of zirconium minerals for industrial applications. In this paper, long, medium, and short range studies were conducted on zirconium minerals originated from Australia, South Africa, and United States of America using conventional and less conventional techniques (i.e., X-Ray Diffraction (XRD), Positron Annihilation Lifetime Spectroscopy (PALS), and Perturbed Angular Correlations (PAC)) in order to reveal the type and the extension of the regions that constitute the metamict state of zircon sands and themodifications therein produced as a consequence of the industrial milling process and the thermal treatment in the production line. Additionally, HPGe gamma-ray spectroscopy confirms the occurrence of significant levels of natural radioactivity responsible for metamictization in the investigated zircon samples. Results from XRD, PALS, and PAC analysis confirm that the metamict state of zircon is a dispersion of submicron disordered domains in a crystalline matrix of zircon.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/68065
url http://sedici.unlp.edu.ar/handle/10915/68065
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.hindawi.com/journals/acmp/2017/9707604/
info:eu-repo/semantics/altIdentifier/doi/10.1155/2017/9707604
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
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reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
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repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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