The anti-corrosion performance of water-borne paints in long term tests

Autores
Roselli, Sol Natacha; Deyá, Marta Cecilia; Romagnoli, Roberto
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
One of the most inexpensive and effective method to protect steel against corrosion is paints containing active pigments. The traditional way to test these coatings performance is by accelerated tests (exposition to salt spray and/or humidity chambers) and electrochemical tests (corrosion potential, ionic resistance and electrochemical impedance spectroscopy). However, these tests give incomplete information if the results are not correlated to outdoor or service tests. The aim of this work was to evaluate water-borne epoxy anticorrosion paints containing different commercial phosphate pigments. The paints were exposed to a semi-industrial atmosphere for 7 years. Electrochemical tests and accelerated assays were also done in order to find a correlation between laboratory and service tests. The results obtained showed no correlation between those from pigment suspensions and those from painted panels, as it seemed that paint performance is highly dependent on the resin. The pigments zinc iron phosphate and zinc aluminium phosphate performed poorly in pigment suspensions. However, the coatings containing them exhibited the highest ionic resistance, the lowest film capacitance and gave the better results in outdoor tests. Results in outdoor exposure tests correlated with those from impedance measurements.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Materia
Ingeniería Química
Phosphate pigments
Water-borne paints
Outdoor tests
Electrochemical impedance spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/97304
Acceder
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network_name_str SEDICI (UNLP)
spelling The anti-corrosion performance of water-borne paints in long term testsRoselli, Sol NatachaDeyá, Marta CeciliaRomagnoli, RobertoIngeniería QuímicaPhosphate pigmentsWater-borne paintsOutdoor testsElectrochemical impedance spectroscopyOne of the most inexpensive and effective method to protect steel against corrosion is paints containing active pigments. The traditional way to test these coatings performance is by accelerated tests (exposition to salt spray and/or humidity chambers) and electrochemical tests (corrosion potential, ionic resistance and electrochemical impedance spectroscopy). However, these tests give incomplete information if the results are not correlated to outdoor or service tests. The aim of this work was to evaluate water-borne epoxy anticorrosion paints containing different commercial phosphate pigments. The paints were exposed to a semi-industrial atmosphere for 7 years. Electrochemical tests and accelerated assays were also done in order to find a correlation between laboratory and service tests. The results obtained showed no correlation between those from pigment suspensions and those from painted panels, as it seemed that paint performance is highly dependent on the resin. The pigments zinc iron phosphate and zinc aluminium phosphate performed poorly in pigment suspensions. However, the coatings containing them exhibited the highest ionic resistance, the lowest film capacitance and gave the better results in outdoor tests. Results in outdoor exposure tests correlated with those from impedance measurements.Centro de Investigación y Desarrollo en Tecnología de Pinturas2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf172-178http://sedici.unlp.edu.ar/handle/10915/97304enginfo:eu-repo/semantics/altIdentifier/issn/0300-9440info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2017.04.031info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:20:55Zoai:sedici.unlp.edu.ar:10915/97304Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:20:55.481SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv The anti-corrosion performance of water-borne paints in long term tests
title The anti-corrosion performance of water-borne paints in long term tests
spellingShingle The anti-corrosion performance of water-borne paints in long term tests
Roselli, Sol Natacha
Ingeniería Química
Phosphate pigments
Water-borne paints
Outdoor tests
Electrochemical impedance spectroscopy
title_short The anti-corrosion performance of water-borne paints in long term tests
title_full The anti-corrosion performance of water-borne paints in long term tests
title_fullStr The anti-corrosion performance of water-borne paints in long term tests
title_full_unstemmed The anti-corrosion performance of water-borne paints in long term tests
title_sort The anti-corrosion performance of water-borne paints in long term tests
dc.creator.none.fl_str_mv Roselli, Sol Natacha
Deyá, Marta Cecilia
Romagnoli, Roberto
author Roselli, Sol Natacha
author_facet Roselli, Sol Natacha
Deyá, Marta Cecilia
Romagnoli, Roberto
author_role author
author2 Deyá, Marta Cecilia
Romagnoli, Roberto
author2_role author
author
dc.subject.none.fl_str_mv Ingeniería Química
Phosphate pigments
Water-borne paints
Outdoor tests
Electrochemical impedance spectroscopy
topic Ingeniería Química
Phosphate pigments
Water-borne paints
Outdoor tests
Electrochemical impedance spectroscopy
dc.description.none.fl_txt_mv One of the most inexpensive and effective method to protect steel against corrosion is paints containing active pigments. The traditional way to test these coatings performance is by accelerated tests (exposition to salt spray and/or humidity chambers) and electrochemical tests (corrosion potential, ionic resistance and electrochemical impedance spectroscopy). However, these tests give incomplete information if the results are not correlated to outdoor or service tests. The aim of this work was to evaluate water-borne epoxy anticorrosion paints containing different commercial phosphate pigments. The paints were exposed to a semi-industrial atmosphere for 7 years. Electrochemical tests and accelerated assays were also done in order to find a correlation between laboratory and service tests. The results obtained showed no correlation between those from pigment suspensions and those from painted panels, as it seemed that paint performance is highly dependent on the resin. The pigments zinc iron phosphate and zinc aluminium phosphate performed poorly in pigment suspensions. However, the coatings containing them exhibited the highest ionic resistance, the lowest film capacitance and gave the better results in outdoor tests. Results in outdoor exposure tests correlated with those from impedance measurements.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
description One of the most inexpensive and effective method to protect steel against corrosion is paints containing active pigments. The traditional way to test these coatings performance is by accelerated tests (exposition to salt spray and/or humidity chambers) and electrochemical tests (corrosion potential, ionic resistance and electrochemical impedance spectroscopy). However, these tests give incomplete information if the results are not correlated to outdoor or service tests. The aim of this work was to evaluate water-borne epoxy anticorrosion paints containing different commercial phosphate pigments. The paints were exposed to a semi-industrial atmosphere for 7 years. Electrochemical tests and accelerated assays were also done in order to find a correlation between laboratory and service tests. The results obtained showed no correlation between those from pigment suspensions and those from painted panels, as it seemed that paint performance is highly dependent on the resin. The pigments zinc iron phosphate and zinc aluminium phosphate performed poorly in pigment suspensions. However, the coatings containing them exhibited the highest ionic resistance, the lowest film capacitance and gave the better results in outdoor tests. Results in outdoor exposure tests correlated with those from impedance measurements.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/97304
url http://sedici.unlp.edu.ar/handle/10915/97304
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0300-9440
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2017.04.031
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
172-178
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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