Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses

Autores
Vázquez, Ana María; Demmel, Gabriela Inés; Criado, Silvia Gertrudis; Aimar, Mario Leandro; Cantero, Juan; Rossi, Laura I.; Velasco, Manuel I.
Año de publicación
2011
Idioma
español castellano
Tipo de recurso
artículo
Estado
versión aceptada
Descripción
A headspace solid-phase microextraction (HS-SPME) method followed by gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detection (GC-FID) is described for the analysis of volatile compounds in Tagetes minuta L. Five types of SPME commercial fibers including PA, PDMS, CAR-PDMS, PDMS-DVB and DVB-CAR-PDMS were investigated and the best extraction was achieved with the mixed fiber DVB-CAR-PDMS. Parameters for HS-SPME in terms of equilibrium time of HS, fiber exposition time and extraction temperature were also investigated. Additionally, the composition of inflorescences, leaves and stems was also studied separately by HS-SPME. As a result, 68 compounds were determined and 53 were identified. A comparison was made between results obtained by HS-SPME-GC-MS and steam distillation of essential oil of the aerial parts of the plant. In both analyses, the major components were: cis-tagetenone and trans-tagetenone. Using much smaller samples, a shorter extraction time and a simpler procedure, the HS-SPME method can achieve similar results to those obtained by EO analysis. In conclusion, the HS-SPME method is simple, rapid, effective and free of solvent, and can be used for the analysis of volatile compounds in samples of different populations of T. minuta.
Fil: Vázquez, Ana María. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Demmel, Gabriela Inés. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Criado, Silvia Gertrudis. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Aimar, Mario Leandro. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Cantero, Juan. Universidad Nacional de Río Cuarto. Facultad de Agronomía y Veterinaria; Argentina
Fil: Rossi, Laura I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Velasco, Manuel I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina
Fuente
Vázquez, Ana María ORCID: https://orcid.org/0000-0002-8466-3471 , Demmel, Gabriela Inés ORCID: https://orcid.org/0000-0002-6939-1391 , Criado, Silvia Gertrudis ORCID: https://orcid.org/0000-0003-3689-7326 , Aimar, Mario Leandro ORCID: https://orcid.org/0000-0001-8547-7198 , Cantero, Juan ORCID: https://orcid.org/0000-0003-1193-6050 , Rossi, Laura I. and Velasco, Manuel I. (2011) Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses. Boletín Latinoamericano y del Caribe de Plantas Medicinales y Aromáticas, 10 (4). pp. 351-362. ISSN 0717-7917
Materia
QD Química
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
Repositorio
Producción Académica (UCC)
Institución
Universidad Católica de Córdoba
OAI Identificador
oai:pa.bibdigital.uccor.edu.ar:3457
Acceder
id PAUCC_62023492c25648e6a26c9957cef24cd0
oai_identifier_str oai:pa.bibdigital.uccor.edu.ar:3457
network_acronym_str PAUCC
repository_id_str 2718
network_name_str Producción Académica (UCC)
spelling Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analysesVázquez, Ana MaríaDemmel, Gabriela InésCriado, Silvia GertrudisAimar, Mario LeandroCantero, JuanRossi, Laura I.Velasco, Manuel I.QD QuímicaA headspace solid-phase microextraction (HS-SPME) method followed by gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detection (GC-FID) is described for the analysis of volatile compounds in Tagetes minuta L. Five types of SPME commercial fibers including PA, PDMS, CAR-PDMS, PDMS-DVB and DVB-CAR-PDMS were investigated and the best extraction was achieved with the mixed fiber DVB-CAR-PDMS. Parameters for HS-SPME in terms of equilibrium time of HS, fiber exposition time and extraction temperature were also investigated. Additionally, the composition of inflorescences, leaves and stems was also studied separately by HS-SPME. As a result, 68 compounds were determined and 53 were identified. A comparison was made between results obtained by HS-SPME-GC-MS and steam distillation of essential oil of the aerial parts of the plant. In both analyses, the major components were: cis-tagetenone and trans-tagetenone. Using much smaller samples, a shorter extraction time and a simpler procedure, the HS-SPME method can achieve similar results to those obtained by EO analysis. In conclusion, the HS-SPME method is simple, rapid, effective and free of solvent, and can be used for the analysis of volatile compounds in samples of different populations of T. minuta.Fil: Vázquez, Ana María. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; ArgentinaFil: Demmel, Gabriela Inés. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; ArgentinaFil: Criado, Silvia Gertrudis. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; ArgentinaFil: Aimar, Mario Leandro. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; ArgentinaFil: Cantero, Juan. Universidad Nacional de Río Cuarto. Facultad de Agronomía y Veterinaria; ArgentinaFil: Rossi, Laura I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; ArgentinaFil: Velasco, Manuel I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; ArgentinaUniversidad de Santiago de Chile2011-07-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://pa.bibdigital.ucc.edu.ar/3457/1/A_V%C3%A1zquez_Demmel_Criado_Aimar_Cantero_Rossi_Velasco.pdf Vázquez, Ana María ORCID: https://orcid.org/0000-0002-8466-3471 <https://orcid.org/0000-0002-8466-3471>, Demmel, Gabriela Inés ORCID: https://orcid.org/0000-0002-6939-1391 <https://orcid.org/0000-0002-6939-1391>, Criado, Silvia Gertrudis ORCID: https://orcid.org/0000-0003-3689-7326 <https://orcid.org/0000-0003-3689-7326>, Aimar, Mario Leandro ORCID: https://orcid.org/0000-0001-8547-7198 <https://orcid.org/0000-0001-8547-7198>, Cantero, Juan ORCID: https://orcid.org/0000-0003-1193-6050 <https://orcid.org/0000-0003-1193-6050>, Rossi, Laura I. and Velasco, Manuel I. (2011) Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses. Boletín Latinoamericano y del Caribe de Plantas Medicinales y Aromáticas, 10 (4). pp. 351-362. ISSN 0717-7917 reponame:Producción Académica (UCC)instname:Universidad Católica de Córdobaspahttp://pa.bibdigital.ucc.edu.ar/3457/https://www.redalyc.org/articulo.oa?id=85619300008info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es2025-10-16T10:06:24Zoai:pa.bibdigital.uccor.edu.ar:3457instacron:UCCInstitucionalhttp://pa.bibdigital.uccor.edu.ar/Universidad privadaNo correspondehttp://pa.bibdigital.uccor.edu.ar/cgi/oai2bibdir@uccor.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:27182025-10-16 10:06:24.339Producción Académica (UCC) - Universidad Católica de Córdobafalse
dc.title.none.fl_str_mv Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
title Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
spellingShingle Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
Vázquez, Ana María
QD Química
title_short Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
title_full Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
title_fullStr Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
title_full_unstemmed Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
title_sort Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses
dc.creator.none.fl_str_mv Vázquez, Ana María
Demmel, Gabriela Inés
Criado, Silvia Gertrudis
Aimar, Mario Leandro
Cantero, Juan
Rossi, Laura I.
Velasco, Manuel I.
author Vázquez, Ana María
author_facet Vázquez, Ana María
Demmel, Gabriela Inés
Criado, Silvia Gertrudis
Aimar, Mario Leandro
Cantero, Juan
Rossi, Laura I.
Velasco, Manuel I.
author_role author
author2 Demmel, Gabriela Inés
Criado, Silvia Gertrudis
Aimar, Mario Leandro
Cantero, Juan
Rossi, Laura I.
Velasco, Manuel I.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv QD Química
topic QD Química
dc.description.none.fl_txt_mv A headspace solid-phase microextraction (HS-SPME) method followed by gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detection (GC-FID) is described for the analysis of volatile compounds in Tagetes minuta L. Five types of SPME commercial fibers including PA, PDMS, CAR-PDMS, PDMS-DVB and DVB-CAR-PDMS were investigated and the best extraction was achieved with the mixed fiber DVB-CAR-PDMS. Parameters for HS-SPME in terms of equilibrium time of HS, fiber exposition time and extraction temperature were also investigated. Additionally, the composition of inflorescences, leaves and stems was also studied separately by HS-SPME. As a result, 68 compounds were determined and 53 were identified. A comparison was made between results obtained by HS-SPME-GC-MS and steam distillation of essential oil of the aerial parts of the plant. In both analyses, the major components were: cis-tagetenone and trans-tagetenone. Using much smaller samples, a shorter extraction time and a simpler procedure, the HS-SPME method can achieve similar results to those obtained by EO analysis. In conclusion, the HS-SPME method is simple, rapid, effective and free of solvent, and can be used for the analysis of volatile compounds in samples of different populations of T. minuta.
Fil: Vázquez, Ana María. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Demmel, Gabriela Inés. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Criado, Silvia Gertrudis. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Aimar, Mario Leandro. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Cantero, Juan. Universidad Nacional de Río Cuarto. Facultad de Agronomía y Veterinaria; Argentina
Fil: Rossi, Laura I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina
Fil: Velasco, Manuel I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina
description A headspace solid-phase microextraction (HS-SPME) method followed by gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detection (GC-FID) is described for the analysis of volatile compounds in Tagetes minuta L. Five types of SPME commercial fibers including PA, PDMS, CAR-PDMS, PDMS-DVB and DVB-CAR-PDMS were investigated and the best extraction was achieved with the mixed fiber DVB-CAR-PDMS. Parameters for HS-SPME in terms of equilibrium time of HS, fiber exposition time and extraction temperature were also investigated. Additionally, the composition of inflorescences, leaves and stems was also studied separately by HS-SPME. As a result, 68 compounds were determined and 53 were identified. A comparison was made between results obtained by HS-SPME-GC-MS and steam distillation of essential oil of the aerial parts of the plant. In both analyses, the major components were: cis-tagetenone and trans-tagetenone. Using much smaller samples, a shorter extraction time and a simpler procedure, the HS-SPME method can achieve similar results to those obtained by EO analysis. In conclusion, the HS-SPME method is simple, rapid, effective and free of solvent, and can be used for the analysis of volatile compounds in samples of different populations of T. minuta.
publishDate 2011
dc.date.none.fl_str_mv 2011-07-31
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://pa.bibdigital.ucc.edu.ar/3457/1/A_V%C3%A1zquez_Demmel_Criado_Aimar_Cantero_Rossi_Velasco.pdf
url http://pa.bibdigital.ucc.edu.ar/3457/1/A_V%C3%A1zquez_Demmel_Criado_Aimar_Cantero_Rossi_Velasco.pdf
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv http://pa.bibdigital.ucc.edu.ar/3457/
https://www.redalyc.org/articulo.oa?id=85619300008
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidad de Santiago de Chile
publisher.none.fl_str_mv Universidad de Santiago de Chile
dc.source.none.fl_str_mv Vázquez, Ana María ORCID: https://orcid.org/0000-0002-8466-3471 <https://orcid.org/0000-0002-8466-3471>, Demmel, Gabriela Inés ORCID: https://orcid.org/0000-0002-6939-1391 <https://orcid.org/0000-0002-6939-1391>, Criado, Silvia Gertrudis ORCID: https://orcid.org/0000-0003-3689-7326 <https://orcid.org/0000-0003-3689-7326>, Aimar, Mario Leandro ORCID: https://orcid.org/0000-0001-8547-7198 <https://orcid.org/0000-0001-8547-7198>, Cantero, Juan ORCID: https://orcid.org/0000-0003-1193-6050 <https://orcid.org/0000-0003-1193-6050>, Rossi, Laura I. and Velasco, Manuel I. (2011) Phytochemistry of Tagetes minuta L. (Asteraceae) from Córdoba, Argentina: comparative study between essential oil and HS-SPME analyses. Boletín Latinoamericano y del Caribe de Plantas Medicinales y Aromáticas, 10 (4). pp. 351-362. ISSN 0717-7917
reponame:Producción Académica (UCC)
instname:Universidad Católica de Córdoba
reponame_str Producción Académica (UCC)
collection Producción Académica (UCC)
instname_str Universidad Católica de Córdoba
repository.name.fl_str_mv Producción Académica (UCC) - Universidad Católica de Córdoba
repository.mail.fl_str_mv bibdir@uccor.edu.ar
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