Soil properties of sugarcane fields controlling triazine leaching potential.

Autores
Portocarrero, Rocio; Aparicio, Virginia Carolina; De Geronimo, Eduardo; Costa, Jose Luis
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Atrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water.
EEA Balcarce
Fil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina.
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.
Fuente
Soil Research Published online: 21 August 2019
Materia
Propiedades del Suelo
Caña de Azúcar
Atrazina
Ametrina
Lixiviación
Soil Properties
Sugarcane
Atrazine
Anmetryn
Leaching
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/5850

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spelling Soil properties of sugarcane fields controlling triazine leaching potential.Portocarrero, RocioAparicio, Virginia CarolinaDe Geronimo, EduardoCosta, Jose LuisPropiedades del SueloCaña de AzúcarAtrazinaAmetrinaLixiviaciónSoil PropertiesSugarcaneAtrazineAnmetrynLeachingAtrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water.EEA BalcarceFil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina.Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.CSIRO PUBLISHING2019-09-11T16:40:21Z2019-09-11T16:40:21Z2019-08-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/5850http://www.publish.csiro.au/SR/SR183421838-675X1838-6768https://doi.org/10.1071/SR18342Soil Research Published online: 21 August 2019reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-29T13:44:45Zoai:localhost:20.500.12123/5850instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:46.004INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Soil properties of sugarcane fields controlling triazine leaching potential.
title Soil properties of sugarcane fields controlling triazine leaching potential.
spellingShingle Soil properties of sugarcane fields controlling triazine leaching potential.
Portocarrero, Rocio
Propiedades del Suelo
Caña de Azúcar
Atrazina
Ametrina
Lixiviación
Soil Properties
Sugarcane
Atrazine
Anmetryn
Leaching
title_short Soil properties of sugarcane fields controlling triazine leaching potential.
title_full Soil properties of sugarcane fields controlling triazine leaching potential.
title_fullStr Soil properties of sugarcane fields controlling triazine leaching potential.
title_full_unstemmed Soil properties of sugarcane fields controlling triazine leaching potential.
title_sort Soil properties of sugarcane fields controlling triazine leaching potential.
dc.creator.none.fl_str_mv Portocarrero, Rocio
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Costa, Jose Luis
author Portocarrero, Rocio
author_facet Portocarrero, Rocio
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Costa, Jose Luis
author_role author
author2 Aparicio, Virginia Carolina
De Geronimo, Eduardo
Costa, Jose Luis
author2_role author
author
author
dc.subject.none.fl_str_mv Propiedades del Suelo
Caña de Azúcar
Atrazina
Ametrina
Lixiviación
Soil Properties
Sugarcane
Atrazine
Anmetryn
Leaching
topic Propiedades del Suelo
Caña de Azúcar
Atrazina
Ametrina
Lixiviación
Soil Properties
Sugarcane
Atrazine
Anmetryn
Leaching
dc.description.none.fl_txt_mv Atrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water.
EEA Balcarce
Fil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina.
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.
description Atrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water.
publishDate 2019
dc.date.none.fl_str_mv 2019-09-11T16:40:21Z
2019-09-11T16:40:21Z
2019-08-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/5850
http://www.publish.csiro.au/SR/SR18342
1838-675X
1838-6768
https://doi.org/10.1071/SR18342
url http://hdl.handle.net/20.500.12123/5850
http://www.publish.csiro.au/SR/SR18342
https://doi.org/10.1071/SR18342
identifier_str_mv 1838-675X
1838-6768
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv CSIRO PUBLISHING
publisher.none.fl_str_mv CSIRO PUBLISHING
dc.source.none.fl_str_mv Soil Research Published online: 21 August 2019
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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