Soil properties of sugarcane fields controlling triazine leaching potential.
- Autores
- Portocarrero, Rocio; Aparicio, Virginia Carolina; De Geronimo, Eduardo; Costa, Jose Luis
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Atrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water.
EEA Balcarce
Fil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina.
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina. - Fuente
- Soil Research Published online: 21 August 2019
- Materia
-
Propiedades del Suelo
Caña de Azúcar
Atrazina
Ametrina
Lixiviación
Soil Properties
Sugarcane
Atrazine
Anmetryn
Leaching - Nivel de accesibilidad
- acceso restringido
- Condiciones de uso
- Repositorio
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/5850
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Soil properties of sugarcane fields controlling triazine leaching potential.Portocarrero, RocioAparicio, Virginia CarolinaDe Geronimo, EduardoCosta, Jose LuisPropiedades del SueloCaña de AzúcarAtrazinaAmetrinaLixiviaciónSoil PropertiesSugarcaneAtrazineAnmetrynLeachingAtrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water.EEA BalcarceFil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina.Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.CSIRO PUBLISHING2019-09-11T16:40:21Z2019-09-11T16:40:21Z2019-08-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/5850http://www.publish.csiro.au/SR/SR183421838-675X1838-6768https://doi.org/10.1071/SR18342Soil Research Published online: 21 August 2019reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-29T13:44:45Zoai:localhost:20.500.12123/5850instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:46.004INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
dc.title.none.fl_str_mv |
Soil properties of sugarcane fields controlling triazine leaching potential. |
title |
Soil properties of sugarcane fields controlling triazine leaching potential. |
spellingShingle |
Soil properties of sugarcane fields controlling triazine leaching potential. Portocarrero, Rocio Propiedades del Suelo Caña de Azúcar Atrazina Ametrina Lixiviación Soil Properties Sugarcane Atrazine Anmetryn Leaching |
title_short |
Soil properties of sugarcane fields controlling triazine leaching potential. |
title_full |
Soil properties of sugarcane fields controlling triazine leaching potential. |
title_fullStr |
Soil properties of sugarcane fields controlling triazine leaching potential. |
title_full_unstemmed |
Soil properties of sugarcane fields controlling triazine leaching potential. |
title_sort |
Soil properties of sugarcane fields controlling triazine leaching potential. |
dc.creator.none.fl_str_mv |
Portocarrero, Rocio Aparicio, Virginia Carolina De Geronimo, Eduardo Costa, Jose Luis |
author |
Portocarrero, Rocio |
author_facet |
Portocarrero, Rocio Aparicio, Virginia Carolina De Geronimo, Eduardo Costa, Jose Luis |
author_role |
author |
author2 |
Aparicio, Virginia Carolina De Geronimo, Eduardo Costa, Jose Luis |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Propiedades del Suelo Caña de Azúcar Atrazina Ametrina Lixiviación Soil Properties Sugarcane Atrazine Anmetryn Leaching |
topic |
Propiedades del Suelo Caña de Azúcar Atrazina Ametrina Lixiviación Soil Properties Sugarcane Atrazine Anmetryn Leaching |
dc.description.none.fl_txt_mv |
Atrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water. EEA Balcarce Fil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina. Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina. |
description |
Atrazine and ametryn are pre- and post-emergence herbicides widely used in sugarcane fields. Both herbicides are characterized by their moderate to high mobility in soil and are regarded as a threat to hydrologic systems. Physical and chemical soil properties are highlighted as one of the factors governing the fate of pesticides in hydrologic systems. The aim of our study was to estimate the leaching potential of atrazine and ametryn in soils of the saline alluvial plain of Tucumán cultivated with sugarcane crop. Miscible displacement experiments were carried out in triplicate using undisturbed topsoil cores from four farm fields. Field 1 was in plant, fields 2 and 3 were in second ratoon, and field 4 was in third ratoon. Experimental breakthrough curves were fitted to the convection-dispersion equation; results showed that hydraulic transport was in equilibrium conditions, meaning that all the soil water was involved in solute convective transport. Atrazine had asymmetric breakthrough curves, revealing chemical non-equilibrium conditions, with at least two sorption-desorption sites participating in the process. In contrast, ametryn concentrations in leached samples were low and inconsistent; therefore, no breakthrough curves could be described. Total recoveries reached 10% and 2% for leached atrazine and ametryn, respectively, of the total applied. For an estimated annual recharge of 100 mm, these leached amounts would exceed the international reference values for drinking water. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-09-11T16:40:21Z 2019-09-11T16:40:21Z 2019-08-21 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/20.500.12123/5850 http://www.publish.csiro.au/SR/SR18342 1838-675X 1838-6768 https://doi.org/10.1071/SR18342 |
url |
http://hdl.handle.net/20.500.12123/5850 http://www.publish.csiro.au/SR/SR18342 https://doi.org/10.1071/SR18342 |
identifier_str_mv |
1838-675X 1838-6768 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/restrictedAccess |
eu_rights_str_mv |
restrictedAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
CSIRO PUBLISHING |
publisher.none.fl_str_mv |
CSIRO PUBLISHING |
dc.source.none.fl_str_mv |
Soil Research Published online: 21 August 2019 reponame:INTA Digital (INTA) instname:Instituto Nacional de Tecnología Agropecuaria |
reponame_str |
INTA Digital (INTA) |
collection |
INTA Digital (INTA) |
instname_str |
Instituto Nacional de Tecnología Agropecuaria |
repository.name.fl_str_mv |
INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria |
repository.mail.fl_str_mv |
tripaldi.nicolas@inta.gob.ar |
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1844619137398079488 |
score |
12.558318 |