Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites

Autores
Davila, Mara Veronica; Riccardo, Jose Luis; Ramirez Pastor, Antonio Jose
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present paper, the multicomponent adsorption of polyatomic species is described as a fractional statistics problem, based on Haldane's statistics. Site exclusion is characterized by a "mutual exclusion matrix" g, which relates to the sizes of the different species and lattice geometry. The adsorption process has been monitored through total and partial isotherms, energy of adsorption and configurational entropy of the adsorbed phase. The thermodynamic functions calculated for a monomer-dimer mixture were applied to describe the adsorption of methane-ethane mixtures in zeolites. In the case of zero lateral interactions, the present approach was compared to the well-known ideal adsorbed solution theory. The results show that the treatment of this complex problem can be significantly simplified if looked up from the new theoretical perspective.
Fil: Davila, Mara Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Materia
ADSORPTION
SURFACE
MONTE CARLO SIMULATION
ZEOLITES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/128534
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Fractional statistics description applied to adsorption of alkane binary mixtures in zeolitesDavila, Mara VeronicaRiccardo, Jose LuisRamirez Pastor, Antonio JoseADSORPTIONSURFACEMONTE CARLO SIMULATIONZEOLITEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the present paper, the multicomponent adsorption of polyatomic species is described as a fractional statistics problem, based on Haldane's statistics. Site exclusion is characterized by a "mutual exclusion matrix" g, which relates to the sizes of the different species and lattice geometry. The adsorption process has been monitored through total and partial isotherms, energy of adsorption and configurational entropy of the adsorbed phase. The thermodynamic functions calculated for a monomer-dimer mixture were applied to describe the adsorption of methane-ethane mixtures in zeolites. In the case of zero lateral interactions, the present approach was compared to the well-known ideal adsorbed solution theory. The results show that the treatment of this complex problem can be significantly simplified if looked up from the new theoretical perspective.Fil: Davila, Mara Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaAmerican Institute of Physics2009-05-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/128534Davila, Mara Veronica; Riccardo, Jose Luis; Ramirez Pastor, Antonio Jose; Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites; American Institute of Physics; Journal of Chemical Physics; 130; 17; 7-5-2009; 1-9; 1747150021-96061089-7690CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.3124163info:eu-repo/semantics/altIdentifier/doi/10.1063/1.3124163info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:13:06Zoai:ri.conicet.gov.ar:11336/128534instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:13:06.33CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
title Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
spellingShingle Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
Davila, Mara Veronica
ADSORPTION
SURFACE
MONTE CARLO SIMULATION
ZEOLITES
title_short Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
title_full Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
title_fullStr Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
title_full_unstemmed Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
title_sort Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites
dc.creator.none.fl_str_mv Davila, Mara Veronica
Riccardo, Jose Luis
Ramirez Pastor, Antonio Jose
author Davila, Mara Veronica
author_facet Davila, Mara Veronica
Riccardo, Jose Luis
Ramirez Pastor, Antonio Jose
author_role author
author2 Riccardo, Jose Luis
Ramirez Pastor, Antonio Jose
author2_role author
author
dc.subject.none.fl_str_mv ADSORPTION
SURFACE
MONTE CARLO SIMULATION
ZEOLITES
topic ADSORPTION
SURFACE
MONTE CARLO SIMULATION
ZEOLITES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In the present paper, the multicomponent adsorption of polyatomic species is described as a fractional statistics problem, based on Haldane's statistics. Site exclusion is characterized by a "mutual exclusion matrix" g, which relates to the sizes of the different species and lattice geometry. The adsorption process has been monitored through total and partial isotherms, energy of adsorption and configurational entropy of the adsorbed phase. The thermodynamic functions calculated for a monomer-dimer mixture were applied to describe the adsorption of methane-ethane mixtures in zeolites. In the case of zero lateral interactions, the present approach was compared to the well-known ideal adsorbed solution theory. The results show that the treatment of this complex problem can be significantly simplified if looked up from the new theoretical perspective.
Fil: Davila, Mara Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
description In the present paper, the multicomponent adsorption of polyatomic species is described as a fractional statistics problem, based on Haldane's statistics. Site exclusion is characterized by a "mutual exclusion matrix" g, which relates to the sizes of the different species and lattice geometry. The adsorption process has been monitored through total and partial isotherms, energy of adsorption and configurational entropy of the adsorbed phase. The thermodynamic functions calculated for a monomer-dimer mixture were applied to describe the adsorption of methane-ethane mixtures in zeolites. In the case of zero lateral interactions, the present approach was compared to the well-known ideal adsorbed solution theory. The results show that the treatment of this complex problem can be significantly simplified if looked up from the new theoretical perspective.
publishDate 2009
dc.date.none.fl_str_mv 2009-05-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/128534
Davila, Mara Veronica; Riccardo, Jose Luis; Ramirez Pastor, Antonio Jose; Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites; American Institute of Physics; Journal of Chemical Physics; 130; 17; 7-5-2009; 1-9; 174715
0021-9606
1089-7690
CONICET Digital
CONICET
url http://hdl.handle.net/11336/128534
identifier_str_mv Davila, Mara Veronica; Riccardo, Jose Luis; Ramirez Pastor, Antonio Jose; Fractional statistics description applied to adsorption of alkane binary mixtures in zeolites; American Institute of Physics; Journal of Chemical Physics; 130; 17; 7-5-2009; 1-9; 174715
0021-9606
1089-7690
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.3124163
info:eu-repo/semantics/altIdentifier/doi/10.1063/1.3124163
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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