Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy

Autores
Bravo, M.; Aguilar, L. F.; Quiroz, W.; Olivieri, Alejandro Cesar; Escandar, Graciela Monica
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work presents a non-sophisticated approach for the trace determination of tributyltin, the most toxic organotin species, in very interfering environments, combining fluorescence measurements of its morin complex and the selectivity of second-order chemometric algorithms. The power of MCR-ALS (multivariate curve resolution/alternating least-squares) to quantify tributyltin through fluorescence excitation-emission matrices in the presence of its main degradation products and of a pool of additional twenty-three metal ions is demonstrated. The applied algorithm successfully faces the challenge of solving the strong overlapping among the spectra of the several sample components. The proposed methodology was applied to tap, river, lagoon and seawater spiked samples, obtaining satisfactory results at ngL -1 levels, after a pre-concentration step on a C18 membrane, demonstrating the analytical potential of the proposed methodology.
Fil: Bravo, M.. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Aguilar, L. F.. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Quiroz, W.. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Olivieri, Alejandro Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Materia
Fluorescence Spectroscopy
Multivariate Calibration
Natural Samples
Tributyltin
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/83892
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/83892
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopyBravo, M.Aguilar, L. F.Quiroz, W.Olivieri, Alejandro CesarEscandar, Graciela MonicaFluorescence SpectroscopyMultivariate CalibrationNatural SamplesTributyltinhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work presents a non-sophisticated approach for the trace determination of tributyltin, the most toxic organotin species, in very interfering environments, combining fluorescence measurements of its morin complex and the selectivity of second-order chemometric algorithms. The power of MCR-ALS (multivariate curve resolution/alternating least-squares) to quantify tributyltin through fluorescence excitation-emission matrices in the presence of its main degradation products and of a pool of additional twenty-three metal ions is demonstrated. The applied algorithm successfully faces the challenge of solving the strong overlapping among the spectra of the several sample components. The proposed methodology was applied to tap, river, lagoon and seawater spiked samples, obtaining satisfactory results at ngL -1 levels, after a pre-concentration step on a C18 membrane, demonstrating the analytical potential of the proposed methodology.Fil: Bravo, M.. Pontificia Universidad Católica de Valparaíso; ChileFil: Aguilar, L. F.. Pontificia Universidad Católica de Valparaíso; ChileFil: Quiroz, W.. Pontificia Universidad Católica de Valparaíso; ChileFil: Olivieri, Alejandro Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaFil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaElsevier Science2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83892Bravo, M.; Aguilar, L. F.; Quiroz, W.; Olivieri, Alejandro Cesar; Escandar, Graciela Monica; Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy; Elsevier Science; Microchemical Journal; 106; 1-2013; 95-1010026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X12001312info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.05.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:48:48Zoai:ri.conicet.gov.ar:11336/83892instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:48:48.81CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
title Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
spellingShingle Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
Bravo, M.
Fluorescence Spectroscopy
Multivariate Calibration
Natural Samples
Tributyltin
title_short Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
title_full Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
title_fullStr Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
title_full_unstemmed Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
title_sort Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy
dc.creator.none.fl_str_mv Bravo, M.
Aguilar, L. F.
Quiroz, W.
Olivieri, Alejandro Cesar
Escandar, Graciela Monica
author Bravo, M.
author_facet Bravo, M.
Aguilar, L. F.
Quiroz, W.
Olivieri, Alejandro Cesar
Escandar, Graciela Monica
author_role author
author2 Aguilar, L. F.
Quiroz, W.
Olivieri, Alejandro Cesar
Escandar, Graciela Monica
author2_role author
author
author
author
dc.subject.none.fl_str_mv Fluorescence Spectroscopy
Multivariate Calibration
Natural Samples
Tributyltin
topic Fluorescence Spectroscopy
Multivariate Calibration
Natural Samples
Tributyltin
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work presents a non-sophisticated approach for the trace determination of tributyltin, the most toxic organotin species, in very interfering environments, combining fluorescence measurements of its morin complex and the selectivity of second-order chemometric algorithms. The power of MCR-ALS (multivariate curve resolution/alternating least-squares) to quantify tributyltin through fluorescence excitation-emission matrices in the presence of its main degradation products and of a pool of additional twenty-three metal ions is demonstrated. The applied algorithm successfully faces the challenge of solving the strong overlapping among the spectra of the several sample components. The proposed methodology was applied to tap, river, lagoon and seawater spiked samples, obtaining satisfactory results at ngL -1 levels, after a pre-concentration step on a C18 membrane, demonstrating the analytical potential of the proposed methodology.
Fil: Bravo, M.. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Aguilar, L. F.. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Quiroz, W.. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Olivieri, Alejandro Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
description This work presents a non-sophisticated approach for the trace determination of tributyltin, the most toxic organotin species, in very interfering environments, combining fluorescence measurements of its morin complex and the selectivity of second-order chemometric algorithms. The power of MCR-ALS (multivariate curve resolution/alternating least-squares) to quantify tributyltin through fluorescence excitation-emission matrices in the presence of its main degradation products and of a pool of additional twenty-three metal ions is demonstrated. The applied algorithm successfully faces the challenge of solving the strong overlapping among the spectra of the several sample components. The proposed methodology was applied to tap, river, lagoon and seawater spiked samples, obtaining satisfactory results at ngL -1 levels, after a pre-concentration step on a C18 membrane, demonstrating the analytical potential of the proposed methodology.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83892
Bravo, M.; Aguilar, L. F.; Quiroz, W.; Olivieri, Alejandro Cesar; Escandar, Graciela Monica; Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy; Elsevier Science; Microchemical Journal; 106; 1-2013; 95-101
0026-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83892
identifier_str_mv Bravo, M.; Aguilar, L. F.; Quiroz, W.; Olivieri, Alejandro Cesar; Escandar, Graciela Monica; Determination of tributyltin at parts-per-trillion levels in natural waters by second-order multivariate calibration and fluorescence spectroscopy; Elsevier Science; Microchemical Journal; 106; 1-2013; 95-101
0026-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X12001312
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.05.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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