Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
- Autores
- Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; Fa Ge, Mao; Della Vedova, Carlos Omar
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19.
Fil: Cayón, Vanina Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania
Fil: Mitzel, Norbert W.. Universitat Bielefeld; Alemania
Fil: Fa Ge, Mao. Chinese Academy of Sciences; República de China
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina - Materia
-
CONFORMATION
CRYSTAL STRUCTURE
DISULFIDES
ELECTRONIC STRUCTURE
PHOTOELECTRON SPECTROSCOPY - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/226796
Ver los metadatos del registro completo
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Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent ProcessesCayón, Vanina MabelErben, Mauricio FedericoRomano, Rosana MarielStammler, Hans GeorgMitzel, Norbert W.Fa Ge, MaoDella Vedova, Carlos OmarCONFORMATIONCRYSTAL STRUCTUREDISULFIDESELECTRONIC STRUCTUREPHOTOELECTRON SPECTROSCOPYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19.Fil: Cayón, Vanina Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Stammler, Hans Georg. Universitat Bielefeld; AlemaniaFil: Mitzel, Norbert W.. Universitat Bielefeld; AlemaniaFil: Fa Ge, Mao. Chinese Academy of Sciences; República de ChinaFil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaWiley2023-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226796Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; et al.; Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes; Wiley; ChemistrySelect; 8; 39; 10-2023; 1-122365-6549CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202302560info:eu-repo/semantics/altIdentifier/doi/10.1002/slct.202302560info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:02Zoai:ri.conicet.gov.ar:11336/226796instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:03.251CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
title |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
spellingShingle |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes Cayón, Vanina Mabel CONFORMATION CRYSTAL STRUCTURE DISULFIDES ELECTRONIC STRUCTURE PHOTOELECTRON SPECTROSCOPY |
title_short |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
title_full |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
title_fullStr |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
title_full_unstemmed |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
title_sort |
Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes |
dc.creator.none.fl_str_mv |
Cayón, Vanina Mabel Erben, Mauricio Federico Romano, Rosana Mariel Stammler, Hans Georg Mitzel, Norbert W. Fa Ge, Mao Della Vedova, Carlos Omar |
author |
Cayón, Vanina Mabel |
author_facet |
Cayón, Vanina Mabel Erben, Mauricio Federico Romano, Rosana Mariel Stammler, Hans Georg Mitzel, Norbert W. Fa Ge, Mao Della Vedova, Carlos Omar |
author_role |
author |
author2 |
Erben, Mauricio Federico Romano, Rosana Mariel Stammler, Hans Georg Mitzel, Norbert W. Fa Ge, Mao Della Vedova, Carlos Omar |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
CONFORMATION CRYSTAL STRUCTURE DISULFIDES ELECTRONIC STRUCTURE PHOTOELECTRON SPECTROSCOPY |
topic |
CONFORMATION CRYSTAL STRUCTURE DISULFIDES ELECTRONIC STRUCTURE PHOTOELECTRON SPECTROSCOPY |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19. Fil: Cayón, Vanina Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania Fil: Mitzel, Norbert W.. Universitat Bielefeld; Alemania Fil: Fa Ge, Mao. Chinese Academy of Sciences; República de China Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina |
description |
Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/226796 Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; et al.; Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes; Wiley; ChemistrySelect; 8; 39; 10-2023; 1-12 2365-6549 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/226796 |
identifier_str_mv |
Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; et al.; Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes; Wiley; ChemistrySelect; 8; 39; 10-2023; 1-12 2365-6549 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202302560 info:eu-repo/semantics/altIdentifier/doi/10.1002/slct.202302560 |
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info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
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openAccess |
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https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
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application/pdf application/pdf application/pdf |
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Wiley |
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Wiley |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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