Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes

Autores
Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; Fa Ge, Mao; Della Vedova, Carlos Omar
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19.
Fil: Cayón, Vanina Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania
Fil: Mitzel, Norbert W.. Universitat Bielefeld; Alemania
Fil: Fa Ge, Mao. Chinese Academy of Sciences; República de China
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
CONFORMATION
CRYSTAL STRUCTURE
DISULFIDES
ELECTRONIC STRUCTURE
PHOTOELECTRON SPECTROSCOPY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/226796
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent ProcessesCayón, Vanina MabelErben, Mauricio FedericoRomano, Rosana MarielStammler, Hans GeorgMitzel, Norbert W.Fa Ge, MaoDella Vedova, Carlos OmarCONFORMATIONCRYSTAL STRUCTUREDISULFIDESELECTRONIC STRUCTUREPHOTOELECTRON SPECTROSCOPYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19.Fil: Cayón, Vanina Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Stammler, Hans Georg. Universitat Bielefeld; AlemaniaFil: Mitzel, Norbert W.. Universitat Bielefeld; AlemaniaFil: Fa Ge, Mao. Chinese Academy of Sciences; República de ChinaFil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaWiley2023-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226796Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; et al.; Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes; Wiley; ChemistrySelect; 8; 39; 10-2023; 1-122365-6549CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202302560info:eu-repo/semantics/altIdentifier/doi/10.1002/slct.202302560info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:21:28Zoai:ri.conicet.gov.ar:11336/226796instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:21:28.789CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
title Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
spellingShingle Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
Cayón, Vanina Mabel
CONFORMATION
CRYSTAL STRUCTURE
DISULFIDES
ELECTRONIC STRUCTURE
PHOTOELECTRON SPECTROSCOPY
title_short Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
title_full Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
title_fullStr Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
title_full_unstemmed Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
title_sort Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes
dc.creator.none.fl_str_mv Cayón, Vanina Mabel
Erben, Mauricio Federico
Romano, Rosana Mariel
Stammler, Hans Georg
Mitzel, Norbert W.
Fa Ge, Mao
Della Vedova, Carlos Omar
author Cayón, Vanina Mabel
author_facet Cayón, Vanina Mabel
Erben, Mauricio Federico
Romano, Rosana Mariel
Stammler, Hans Georg
Mitzel, Norbert W.
Fa Ge, Mao
Della Vedova, Carlos Omar
author_role author
author2 Erben, Mauricio Federico
Romano, Rosana Mariel
Stammler, Hans Georg
Mitzel, Norbert W.
Fa Ge, Mao
Della Vedova, Carlos Omar
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv CONFORMATION
CRYSTAL STRUCTURE
DISULFIDES
ELECTRONIC STRUCTURE
PHOTOELECTRON SPECTROSCOPY
topic CONFORMATION
CRYSTAL STRUCTURE
DISULFIDES
ELECTRONIC STRUCTURE
PHOTOELECTRON SPECTROSCOPY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19.
Fil: Cayón, Vanina Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania
Fil: Mitzel, Norbert W.. Universitat Bielefeld; Alemania
Fil: Fa Ge, Mao. Chinese Academy of Sciences; República de China
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description Exploring the fundamental chemistry and intrinsic properties of disulfide-containing species has become an increasingly popular means to understand their action in various scientific fields, applications, and systems. In this study several representatives of this extensive family with the general formula CCl3SSR, where R represents CH2CH3, CH2CF3, C(CH3)3, C6H5 and C(O)CH3,were prepared and characterized by vibrational spectroscopy methods (FTIR and Raman), NMR spectroscopy, mass spectrometry, X-ray structure determinations and photo electron spectroscopy. When complemented with computational chemistry, this range of methods and techniques sheds new light on numerous different processes. It is worth noting that the importance in disulfides compounds is related to inherent properties of this chemical family, such as chirality, theories involving the origin of life and its evolution, and, lately, the mechanisms of S−S bond formation in processes concerning therapies based on the use of peptides and COVID-19.
publishDate 2023
dc.date.none.fl_str_mv 2023-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/226796
Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; et al.; Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes; Wiley; ChemistrySelect; 8; 39; 10-2023; 1-12
2365-6549
CONICET Digital
CONICET
url http://hdl.handle.net/11336/226796
identifier_str_mv Cayón, Vanina Mabel; Erben, Mauricio Federico; Romano, Rosana Mariel; Stammler, Hans Georg; Mitzel, Norbert W.; et al.; Simple Disulfides: Studies of Some Exponents of a Family Involved in Prominent Processes; Wiley; ChemistrySelect; 8; 39; 10-2023; 1-12
2365-6549
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202302560
info:eu-repo/semantics/altIdentifier/doi/10.1002/slct.202302560
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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