Dynamic response of transiently trapped entanglements in polymer networks

Autores
Agudelo Mora, Diana Carolina; Roth, Leandro E.; Vega, Daniel Alberto; Valles, Enrique Marcelo; Villar, Marcelo Armando
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The structure and viscoelastic response of polymer networks are highly sensitive to the presence of pendant chains. These imperfections, that are unavoidable produced during a cross-linking reaction, reduce the cross-linking density and affect the damping response of elastomers. In this work the dynamics of pendant chains present in a cross-linked network is investigated using end-linked poly(dimethyl-siloxane) networks with well defined structure. For this purpose, model networks containing 10 and 20 wt% of two different monodisperse pendant chains with molecular weights well above the critical entanglement molecular weight and some of their blends were prepared. It was found that, within this range of concentration of pendant chains, the long-time dynamic response of the networks was nearly insensitive to the content of pendant material but deeply influenced by the average molar mass of these defects. While the equilibrium behavior of the networks can be well described by a mean field theory for rubber elasticity, the long time relaxational dynamics can be rationalized in terms of the Pearson-Helfand picture for the arm retraction process. Within this theoretical picture, the dynamics can be explained in terms of the molecular architecture of the network, the Rouse time and the weight average molar mass of the pendant material.
Fil: Agudelo Mora, Diana Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Roth, Leandro E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Vega, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Física del Sur; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Materia
Model Networks
Pendant Chains
Dangling Chains
Arm Retraction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13540
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/13540
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network_name_str CONICET Digital (CONICET)
spelling Dynamic response of transiently trapped entanglements in polymer networksAgudelo Mora, Diana CarolinaRoth, Leandro E.Vega, Daniel AlbertoValles, Enrique MarceloVillar, Marcelo ArmandoModel NetworksPendant ChainsDangling ChainsArm Retractionhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The structure and viscoelastic response of polymer networks are highly sensitive to the presence of pendant chains. These imperfections, that are unavoidable produced during a cross-linking reaction, reduce the cross-linking density and affect the damping response of elastomers. In this work the dynamics of pendant chains present in a cross-linked network is investigated using end-linked poly(dimethyl-siloxane) networks with well defined structure. For this purpose, model networks containing 10 and 20 wt% of two different monodisperse pendant chains with molecular weights well above the critical entanglement molecular weight and some of their blends were prepared. It was found that, within this range of concentration of pendant chains, the long-time dynamic response of the networks was nearly insensitive to the content of pendant material but deeply influenced by the average molar mass of these defects. While the equilibrium behavior of the networks can be well described by a mean field theory for rubber elasticity, the long time relaxational dynamics can be rationalized in terms of the Pearson-Helfand picture for the arm retraction process. Within this theoretical picture, the dynamics can be explained in terms of the molecular architecture of the network, the Rouse time and the weight average molar mass of the pendant material.Fil: Agudelo Mora, Diana Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; ArgentinaFil: Roth, Leandro E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; ArgentinaFil: Vega, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Física del Sur; Argentina. Universidad Nacional del Sur. Departamento de Física; ArgentinaFil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; ArgentinaFil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; ArgentinaElsevier2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13540Agudelo Mora, Diana Carolina; Roth, Leandro E.; Vega, Daniel Alberto; Valles, Enrique Marcelo; Villar, Marcelo Armando; Dynamic response of transiently trapped entanglements in polymer networks; Elsevier; Polymer; 55; 4; 2-2014; 1061-10690032-3861enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0032386114000251info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2014.01.010info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:10:32Zoai:ri.conicet.gov.ar:11336/13540instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:10:33.089CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dynamic response of transiently trapped entanglements in polymer networks
title Dynamic response of transiently trapped entanglements in polymer networks
spellingShingle Dynamic response of transiently trapped entanglements in polymer networks
Agudelo Mora, Diana Carolina
Model Networks
Pendant Chains
Dangling Chains
Arm Retraction
title_short Dynamic response of transiently trapped entanglements in polymer networks
title_full Dynamic response of transiently trapped entanglements in polymer networks
title_fullStr Dynamic response of transiently trapped entanglements in polymer networks
title_full_unstemmed Dynamic response of transiently trapped entanglements in polymer networks
title_sort Dynamic response of transiently trapped entanglements in polymer networks
dc.creator.none.fl_str_mv Agudelo Mora, Diana Carolina
Roth, Leandro E.
Vega, Daniel Alberto
Valles, Enrique Marcelo
Villar, Marcelo Armando
author Agudelo Mora, Diana Carolina
author_facet Agudelo Mora, Diana Carolina
Roth, Leandro E.
Vega, Daniel Alberto
Valles, Enrique Marcelo
Villar, Marcelo Armando
author_role author
author2 Roth, Leandro E.
Vega, Daniel Alberto
Valles, Enrique Marcelo
Villar, Marcelo Armando
author2_role author
author
author
author
dc.subject.none.fl_str_mv Model Networks
Pendant Chains
Dangling Chains
Arm Retraction
topic Model Networks
Pendant Chains
Dangling Chains
Arm Retraction
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The structure and viscoelastic response of polymer networks are highly sensitive to the presence of pendant chains. These imperfections, that are unavoidable produced during a cross-linking reaction, reduce the cross-linking density and affect the damping response of elastomers. In this work the dynamics of pendant chains present in a cross-linked network is investigated using end-linked poly(dimethyl-siloxane) networks with well defined structure. For this purpose, model networks containing 10 and 20 wt% of two different monodisperse pendant chains with molecular weights well above the critical entanglement molecular weight and some of their blends were prepared. It was found that, within this range of concentration of pendant chains, the long-time dynamic response of the networks was nearly insensitive to the content of pendant material but deeply influenced by the average molar mass of these defects. While the equilibrium behavior of the networks can be well described by a mean field theory for rubber elasticity, the long time relaxational dynamics can be rationalized in terms of the Pearson-Helfand picture for the arm retraction process. Within this theoretical picture, the dynamics can be explained in terms of the molecular architecture of the network, the Rouse time and the weight average molar mass of the pendant material.
Fil: Agudelo Mora, Diana Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Roth, Leandro E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Vega, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Física del Sur; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
description The structure and viscoelastic response of polymer networks are highly sensitive to the presence of pendant chains. These imperfections, that are unavoidable produced during a cross-linking reaction, reduce the cross-linking density and affect the damping response of elastomers. In this work the dynamics of pendant chains present in a cross-linked network is investigated using end-linked poly(dimethyl-siloxane) networks with well defined structure. For this purpose, model networks containing 10 and 20 wt% of two different monodisperse pendant chains with molecular weights well above the critical entanglement molecular weight and some of their blends were prepared. It was found that, within this range of concentration of pendant chains, the long-time dynamic response of the networks was nearly insensitive to the content of pendant material but deeply influenced by the average molar mass of these defects. While the equilibrium behavior of the networks can be well described by a mean field theory for rubber elasticity, the long time relaxational dynamics can be rationalized in terms of the Pearson-Helfand picture for the arm retraction process. Within this theoretical picture, the dynamics can be explained in terms of the molecular architecture of the network, the Rouse time and the weight average molar mass of the pendant material.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13540
Agudelo Mora, Diana Carolina; Roth, Leandro E.; Vega, Daniel Alberto; Valles, Enrique Marcelo; Villar, Marcelo Armando; Dynamic response of transiently trapped entanglements in polymer networks; Elsevier; Polymer; 55; 4; 2-2014; 1061-1069
0032-3861
url http://hdl.handle.net/11336/13540
identifier_str_mv Agudelo Mora, Diana Carolina; Roth, Leandro E.; Vega, Daniel Alberto; Valles, Enrique Marcelo; Villar, Marcelo Armando; Dynamic response of transiently trapped entanglements in polymer networks; Elsevier; Polymer; 55; 4; 2-2014; 1061-1069
0032-3861
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0032386114000251
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2014.01.010
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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