Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles

Autores
Martins, Cauê A.; Fernández, Pablo Sebastián; Troiani, Horacio Esteban; Martins, María Elisa; Câmara, Giuseppe A.
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the last decades ethanol and glycerol arose as potential fuels for fuel cells. Based on their importance to the field and molecular similarity, here we compare the electrooxidation of ethanol and glycerol on platinum nanoparticles as an attempt to learn about their differences and similarities in terms of oxidation pathways. By using in situ FTIR we interpret the electrochemical behavior in terms of different pathways involving the production of carboxylic acids for both alcohols. For ethanol, CO2 is produced from CO in a direct pathway involving several electrons, while acetic acid is produced through a parallel pathway. Conversely, for glycerol CO2 seems to be mainly produced through a sequential pathway involving carboxylic acids, each one involving few electrons. The results suggest that glycerol demands surfaces that speed up the oxidation of partially oxidized species formed at intermediate potentials.
Fil: Martins, Cauê A.. Institute of Chemistry; Brasil
Fil: Fernández, Pablo Sebastián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Troiani, Horacio Esteban. División Metales, Centro Atómico Bariloche, Argentina;
Fil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Câmara, Giuseppe A.. Institute of Chemistry; Brasil
Materia
Ethanol
Glycerol
Oxidation Pathways
Platinum Nanomaterials
Direct Alcohol Fuel Cells
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/29479
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticlesMartins, Cauê A.Fernández, Pablo SebastiánTroiani, Horacio EstebanMartins, María ElisaCâmara, Giuseppe A.EthanolGlycerolOxidation PathwaysPlatinum NanomaterialsDirect Alcohol Fuel Cellshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the last decades ethanol and glycerol arose as potential fuels for fuel cells. Based on their importance to the field and molecular similarity, here we compare the electrooxidation of ethanol and glycerol on platinum nanoparticles as an attempt to learn about their differences and similarities in terms of oxidation pathways. By using in situ FTIR we interpret the electrochemical behavior in terms of different pathways involving the production of carboxylic acids for both alcohols. For ethanol, CO2 is produced from CO in a direct pathway involving several electrons, while acetic acid is produced through a parallel pathway. Conversely, for glycerol CO2 seems to be mainly produced through a sequential pathway involving carboxylic acids, each one involving few electrons. The results suggest that glycerol demands surfaces that speed up the oxidation of partially oxidized species formed at intermediate potentials.Fil: Martins, Cauê A.. Institute of Chemistry; BrasilFil: Fernández, Pablo Sebastián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Troiani, Horacio Esteban. División Metales, Centro Atómico Bariloche, Argentina;Fil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Câmara, Giuseppe A.. Institute of Chemistry; BrasilElsevier Science Sa2014-03-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/29479Martins, Cauê A.; Fernández, Pablo Sebastián; Troiani, Horacio Esteban; Martins, María Elisa; Câmara, Giuseppe A.; Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 717 - 718; 2014; 15-3-2014; 231-2361572-6657CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2014.01.027info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1572665714000484?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:50Zoai:ri.conicet.gov.ar:11336/29479instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:50.635CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
title Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
spellingShingle Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
Martins, Cauê A.
Ethanol
Glycerol
Oxidation Pathways
Platinum Nanomaterials
Direct Alcohol Fuel Cells
title_short Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
title_full Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
title_fullStr Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
title_full_unstemmed Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
title_sort Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles
dc.creator.none.fl_str_mv Martins, Cauê A.
Fernández, Pablo Sebastián
Troiani, Horacio Esteban
Martins, María Elisa
Câmara, Giuseppe A.
author Martins, Cauê A.
author_facet Martins, Cauê A.
Fernández, Pablo Sebastián
Troiani, Horacio Esteban
Martins, María Elisa
Câmara, Giuseppe A.
author_role author
author2 Fernández, Pablo Sebastián
Troiani, Horacio Esteban
Martins, María Elisa
Câmara, Giuseppe A.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ethanol
Glycerol
Oxidation Pathways
Platinum Nanomaterials
Direct Alcohol Fuel Cells
topic Ethanol
Glycerol
Oxidation Pathways
Platinum Nanomaterials
Direct Alcohol Fuel Cells
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In the last decades ethanol and glycerol arose as potential fuels for fuel cells. Based on their importance to the field and molecular similarity, here we compare the electrooxidation of ethanol and glycerol on platinum nanoparticles as an attempt to learn about their differences and similarities in terms of oxidation pathways. By using in situ FTIR we interpret the electrochemical behavior in terms of different pathways involving the production of carboxylic acids for both alcohols. For ethanol, CO2 is produced from CO in a direct pathway involving several electrons, while acetic acid is produced through a parallel pathway. Conversely, for glycerol CO2 seems to be mainly produced through a sequential pathway involving carboxylic acids, each one involving few electrons. The results suggest that glycerol demands surfaces that speed up the oxidation of partially oxidized species formed at intermediate potentials.
Fil: Martins, Cauê A.. Institute of Chemistry; Brasil
Fil: Fernández, Pablo Sebastián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Troiani, Horacio Esteban. División Metales, Centro Atómico Bariloche, Argentina;
Fil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Câmara, Giuseppe A.. Institute of Chemistry; Brasil
description In the last decades ethanol and glycerol arose as potential fuels for fuel cells. Based on their importance to the field and molecular similarity, here we compare the electrooxidation of ethanol and glycerol on platinum nanoparticles as an attempt to learn about their differences and similarities in terms of oxidation pathways. By using in situ FTIR we interpret the electrochemical behavior in terms of different pathways involving the production of carboxylic acids for both alcohols. For ethanol, CO2 is produced from CO in a direct pathway involving several electrons, while acetic acid is produced through a parallel pathway. Conversely, for glycerol CO2 seems to be mainly produced through a sequential pathway involving carboxylic acids, each one involving few electrons. The results suggest that glycerol demands surfaces that speed up the oxidation of partially oxidized species formed at intermediate potentials.
publishDate 2014
dc.date.none.fl_str_mv 2014-03-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/29479
Martins, Cauê A.; Fernández, Pablo Sebastián; Troiani, Horacio Esteban; Martins, María Elisa; Câmara, Giuseppe A.; Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 717 - 718; 2014; 15-3-2014; 231-236
1572-6657
CONICET Digital
CONICET
url http://hdl.handle.net/11336/29479
identifier_str_mv Martins, Cauê A.; Fernández, Pablo Sebastián; Troiani, Horacio Esteban; Martins, María Elisa; Câmara, Giuseppe A.; Ethanol vs. glycerol: Understanding the lack of correlation between the oxidation currents and the production of CO2 on Pt nanoparticles; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 717 - 718; 2014; 15-3-2014; 231-236
1572-6657
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2014.01.027
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1572665714000484?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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