Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity

Autores
Santaya, Mariano; Troiani, Horacio Esteban; Caneiro, Alberto; Mogni, Liliana Verónica
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The exsolution of Ni−Co−Fe from a Sr0.93(Ti0.3Fe0.56Ni0.07Co0.07)O3−δ perovskite (STFNC) is explored as a strategy to produce electrochemically active electrodes for symmetric-SOFC (S-SOFC). It was found that a nanostructured NiCoFe ternary alloy phase, with approximately equal amounts of each metal, can be formed by this method. The STFNC electrode is studied via electrochemical impedance spectroscopy, showing a really interesting potential as S-SOFC electrode: the anode polarization resistance was 1.12 Ω·cm2 in a wet 10%H2 atmosphere at 700 °C (exsolving in situ the NiCoFe phase), and the cathode polarization resistance at 700 °C in air was 0.054 and 0.042 Ω·cm2, before and after exsolution, respectively.
Fil: Santaya, Mariano. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro. Archivo Histórico del Centro Atómico Bariloche e Instituto Balseiro | Universidad Nacional de Cuyo. Instituto Balseiro. Archivo Histórico del Centro Atómico Bariloche e Instituto Balseiro; Argentina
Fil: Caneiro, Alberto. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Materia
EXSOLUTION
PEROVSKITE
SYMMETRIC-SOFC
TERNARY ALLOY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/146294
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/146294
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activitySantaya, MarianoTroiani, Horacio EstebanCaneiro, AlbertoMogni, Liliana VerónicaEXSOLUTIONPEROVSKITESYMMETRIC-SOFCTERNARY ALLOYhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The exsolution of Ni−Co−Fe from a Sr0.93(Ti0.3Fe0.56Ni0.07Co0.07)O3−δ perovskite (STFNC) is explored as a strategy to produce electrochemically active electrodes for symmetric-SOFC (S-SOFC). It was found that a nanostructured NiCoFe ternary alloy phase, with approximately equal amounts of each metal, can be formed by this method. The STFNC electrode is studied via electrochemical impedance spectroscopy, showing a really interesting potential as S-SOFC electrode: the anode polarization resistance was 1.12 Ω·cm2 in a wet 10%H2 atmosphere at 700 °C (exsolving in situ the NiCoFe phase), and the cathode polarization resistance at 700 °C in air was 0.054 and 0.042 Ω·cm2, before and after exsolution, respectively.Fil: Santaya, Mariano. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; ArgentinaFil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro. Archivo Histórico del Centro Atómico Bariloche e Instituto Balseiro | Universidad Nacional de Cuyo. Instituto Balseiro. Archivo Histórico del Centro Atómico Bariloche e Instituto Balseiro; ArgentinaFil: Caneiro, Alberto. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; ArgentinaAmerican Chemical Society2020-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/146294Santaya, Mariano; Troiani, Horacio Esteban; Caneiro, Alberto; Mogni, Liliana Verónica; Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity; American Chemical Society; ACS Applied Energy Materials; 3; 10; 9-2020; 9528-95332574-0962CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsaem.0c01997info:eu-repo/semantics/altIdentifier/doi/10.1021/acsaem.0c01997info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:37Zoai:ri.conicet.gov.ar:11336/146294instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:37.403CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
title Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
spellingShingle Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
Santaya, Mariano
EXSOLUTION
PEROVSKITE
SYMMETRIC-SOFC
TERNARY ALLOY
title_short Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
title_full Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
title_fullStr Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
title_full_unstemmed Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
title_sort Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity
dc.creator.none.fl_str_mv Santaya, Mariano
Troiani, Horacio Esteban
Caneiro, Alberto
Mogni, Liliana Verónica
author Santaya, Mariano
author_facet Santaya, Mariano
Troiani, Horacio Esteban
Caneiro, Alberto
Mogni, Liliana Verónica
author_role author
author2 Troiani, Horacio Esteban
Caneiro, Alberto
Mogni, Liliana Verónica
author2_role author
author
author
dc.subject.none.fl_str_mv EXSOLUTION
PEROVSKITE
SYMMETRIC-SOFC
TERNARY ALLOY
topic EXSOLUTION
PEROVSKITE
SYMMETRIC-SOFC
TERNARY ALLOY
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The exsolution of Ni−Co−Fe from a Sr0.93(Ti0.3Fe0.56Ni0.07Co0.07)O3−δ perovskite (STFNC) is explored as a strategy to produce electrochemically active electrodes for symmetric-SOFC (S-SOFC). It was found that a nanostructured NiCoFe ternary alloy phase, with approximately equal amounts of each metal, can be formed by this method. The STFNC electrode is studied via electrochemical impedance spectroscopy, showing a really interesting potential as S-SOFC electrode: the anode polarization resistance was 1.12 Ω·cm2 in a wet 10%H2 atmosphere at 700 °C (exsolving in situ the NiCoFe phase), and the cathode polarization resistance at 700 °C in air was 0.054 and 0.042 Ω·cm2, before and after exsolution, respectively.
Fil: Santaya, Mariano. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro. Archivo Histórico del Centro Atómico Bariloche e Instituto Balseiro | Universidad Nacional de Cuyo. Instituto Balseiro. Archivo Histórico del Centro Atómico Bariloche e Instituto Balseiro; Argentina
Fil: Caneiro, Alberto. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
description The exsolution of Ni−Co−Fe from a Sr0.93(Ti0.3Fe0.56Ni0.07Co0.07)O3−δ perovskite (STFNC) is explored as a strategy to produce electrochemically active electrodes for symmetric-SOFC (S-SOFC). It was found that a nanostructured NiCoFe ternary alloy phase, with approximately equal amounts of each metal, can be formed by this method. The STFNC electrode is studied via electrochemical impedance spectroscopy, showing a really interesting potential as S-SOFC electrode: the anode polarization resistance was 1.12 Ω·cm2 in a wet 10%H2 atmosphere at 700 °C (exsolving in situ the NiCoFe phase), and the cathode polarization resistance at 700 °C in air was 0.054 and 0.042 Ω·cm2, before and after exsolution, respectively.
publishDate 2020
dc.date.none.fl_str_mv 2020-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/146294
Santaya, Mariano; Troiani, Horacio Esteban; Caneiro, Alberto; Mogni, Liliana Verónica; Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity; American Chemical Society; ACS Applied Energy Materials; 3; 10; 9-2020; 9528-9533
2574-0962
CONICET Digital
CONICET
url http://hdl.handle.net/11336/146294
identifier_str_mv Santaya, Mariano; Troiani, Horacio Esteban; Caneiro, Alberto; Mogni, Liliana Verónica; Ternary Ni−Co−Fe exsolved nanoparticles/perovskite system for energy applications: Nanostructure characterization and electrochemical activity; American Chemical Society; ACS Applied Energy Materials; 3; 10; 9-2020; 9528-9533
2574-0962
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsaem.0c01997
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsaem.0c01997
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269237180104704
score 13.13397

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