A multi-scale perspective of gas transport through soap-film membranes

Autores
Falciani, Gabriele; Franklin Mergarejo, Ricardo; Cagna, Alain; Sen, Indraneel; Hassanali, Ali; Chiavazzo, Eliodoro
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Soap films represent unique aqueous systems, whose physical properties can be tuned by acting on their nanoscale structure. Here, we specifically focus on transport properties through membranes realized in the form of soap films. While diffusion phenomena in the water core and surfactant monolayers are described using a continuum model, molecular dynamics is used to compute the static and dynamical properties of water, gases and the surfactant in the monolayers which is hexaethylene glycol monododecyl ether (C12E6). The obtained atomistic details are then incorporated into a drift-diffusion model for consistently extracting a boundary condition for the above continuum model describing transport phenomena at a larger scale. Numerical predictions are validated against experimental data from both properly designed experiments and the literature. Finally, the developed model is used to estimate the characteristic time for disparate gas mixing when initially separated by soap film membranes.
Fil: Falciani, Gabriele. Politecnico di Torino; Italia
Fil: Franklin Mergarejo, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. The Abdus Salam. International Centre for Theoretical Physics; Italia. Universidad Nacional de Quilmes; Argentina
Fil: Cagna, Alain. Teclis Scientific; Francia
Fil: Sen, Indraneel. Uppsala Universitet; Suecia
Fil: Hassanali, Ali. The Abdus Salam. International Centre for Theoretical Physics; Italia
Fil: Chiavazzo, Eliodoro. Politecnico di Torino; Italia
Materia
MOLECULAR-ENGINEERING
SOAP-FILM MEMBRANES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/156151
Acceder
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network_name_str CONICET Digital (CONICET)
spelling A multi-scale perspective of gas transport through soap-film membranesFalciani, GabrieleFranklin Mergarejo, RicardoCagna, AlainSen, IndraneelHassanali, AliChiavazzo, EliodoroMOLECULAR-ENGINEERINGSOAP-FILM MEMBRANEShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Soap films represent unique aqueous systems, whose physical properties can be tuned by acting on their nanoscale structure. Here, we specifically focus on transport properties through membranes realized in the form of soap films. While diffusion phenomena in the water core and surfactant monolayers are described using a continuum model, molecular dynamics is used to compute the static and dynamical properties of water, gases and the surfactant in the monolayers which is hexaethylene glycol monododecyl ether (C12E6). The obtained atomistic details are then incorporated into a drift-diffusion model for consistently extracting a boundary condition for the above continuum model describing transport phenomena at a larger scale. Numerical predictions are validated against experimental data from both properly designed experiments and the literature. Finally, the developed model is used to estimate the characteristic time for disparate gas mixing when initially separated by soap film membranes.Fil: Falciani, Gabriele. Politecnico di Torino; ItaliaFil: Franklin Mergarejo, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. The Abdus Salam. International Centre for Theoretical Physics; Italia. Universidad Nacional de Quilmes; ArgentinaFil: Cagna, Alain. Teclis Scientific; FranciaFil: Sen, Indraneel. Uppsala Universitet; SueciaFil: Hassanali, Ali. The Abdus Salam. International Centre for Theoretical Physics; ItaliaFil: Chiavazzo, Eliodoro. Politecnico di Torino; ItaliaRoyal Society of Chemistry2020-03-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/156151Falciani, Gabriele; Franklin Mergarejo, Ricardo; Cagna, Alain; Sen, Indraneel; Hassanali, Ali; et al.; A multi-scale perspective of gas transport through soap-film membranes; Royal Society of Chemistry; Molecular Systems Design and Engineering; 5; 5; 16-3-2020; 911-9212058-9689CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c9me00186ginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2020/ME/C9ME00186Ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:37Zoai:ri.conicet.gov.ar:11336/156151instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:38.15CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A multi-scale perspective of gas transport through soap-film membranes
title A multi-scale perspective of gas transport through soap-film membranes
spellingShingle A multi-scale perspective of gas transport through soap-film membranes
Falciani, Gabriele
MOLECULAR-ENGINEERING
SOAP-FILM MEMBRANES
title_short A multi-scale perspective of gas transport through soap-film membranes
title_full A multi-scale perspective of gas transport through soap-film membranes
title_fullStr A multi-scale perspective of gas transport through soap-film membranes
title_full_unstemmed A multi-scale perspective of gas transport through soap-film membranes
title_sort A multi-scale perspective of gas transport through soap-film membranes
dc.creator.none.fl_str_mv Falciani, Gabriele
Franklin Mergarejo, Ricardo
Cagna, Alain
Sen, Indraneel
Hassanali, Ali
Chiavazzo, Eliodoro
author Falciani, Gabriele
author_facet Falciani, Gabriele
Franklin Mergarejo, Ricardo
Cagna, Alain
Sen, Indraneel
Hassanali, Ali
Chiavazzo, Eliodoro
author_role author
author2 Franklin Mergarejo, Ricardo
Cagna, Alain
Sen, Indraneel
Hassanali, Ali
Chiavazzo, Eliodoro
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv MOLECULAR-ENGINEERING
SOAP-FILM MEMBRANES
topic MOLECULAR-ENGINEERING
SOAP-FILM MEMBRANES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Soap films represent unique aqueous systems, whose physical properties can be tuned by acting on their nanoscale structure. Here, we specifically focus on transport properties through membranes realized in the form of soap films. While diffusion phenomena in the water core and surfactant monolayers are described using a continuum model, molecular dynamics is used to compute the static and dynamical properties of water, gases and the surfactant in the monolayers which is hexaethylene glycol monododecyl ether (C12E6). The obtained atomistic details are then incorporated into a drift-diffusion model for consistently extracting a boundary condition for the above continuum model describing transport phenomena at a larger scale. Numerical predictions are validated against experimental data from both properly designed experiments and the literature. Finally, the developed model is used to estimate the characteristic time for disparate gas mixing when initially separated by soap film membranes.
Fil: Falciani, Gabriele. Politecnico di Torino; Italia
Fil: Franklin Mergarejo, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. The Abdus Salam. International Centre for Theoretical Physics; Italia. Universidad Nacional de Quilmes; Argentina
Fil: Cagna, Alain. Teclis Scientific; Francia
Fil: Sen, Indraneel. Uppsala Universitet; Suecia
Fil: Hassanali, Ali. The Abdus Salam. International Centre for Theoretical Physics; Italia
Fil: Chiavazzo, Eliodoro. Politecnico di Torino; Italia
description Soap films represent unique aqueous systems, whose physical properties can be tuned by acting on their nanoscale structure. Here, we specifically focus on transport properties through membranes realized in the form of soap films. While diffusion phenomena in the water core and surfactant monolayers are described using a continuum model, molecular dynamics is used to compute the static and dynamical properties of water, gases and the surfactant in the monolayers which is hexaethylene glycol monododecyl ether (C12E6). The obtained atomistic details are then incorporated into a drift-diffusion model for consistently extracting a boundary condition for the above continuum model describing transport phenomena at a larger scale. Numerical predictions are validated against experimental data from both properly designed experiments and the literature. Finally, the developed model is used to estimate the characteristic time for disparate gas mixing when initially separated by soap film membranes.
publishDate 2020
dc.date.none.fl_str_mv 2020-03-16
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/156151
Falciani, Gabriele; Franklin Mergarejo, Ricardo; Cagna, Alain; Sen, Indraneel; Hassanali, Ali; et al.; A multi-scale perspective of gas transport through soap-film membranes; Royal Society of Chemistry; Molecular Systems Design and Engineering; 5; 5; 16-3-2020; 911-921
2058-9689
CONICET Digital
CONICET
url http://hdl.handle.net/11336/156151
identifier_str_mv Falciani, Gabriele; Franklin Mergarejo, Ricardo; Cagna, Alain; Sen, Indraneel; Hassanali, Ali; et al.; A multi-scale perspective of gas transport through soap-film membranes; Royal Society of Chemistry; Molecular Systems Design and Engineering; 5; 5; 16-3-2020; 911-921
2058-9689
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c9me00186g
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2020/ME/C9ME00186G
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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