Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe

Autores
Villa Perez, Cristian; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the absorption and emission behavior of the cationic hemicyanine trans-4-[4(dimethylamino)styryl]-N-methylpyridinium iodide (HC) in reverse micelles (RMs) formed by the catanionic surfactants benzyl-n-hexadecyldimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-BHD) and cetyltrimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-CTA) have been investigated. Our results show that the spectroscopic behavior of HC changes when the dye is dissolved in AOT-BHD or in AOT-CTA RMs. While HC undergoes an intramolecular charge-transfer process upon excitation in AOT-CTA RMs, in AOT-BHD RMs this process is inhibited due to a specific interaction between HC and the polar head group of the BHD+ cation. This implies that the chemical structure of CTA+ and BHD+ cations has a large impact on the excited stated from which HC emission occurs. Additionally, the structural difference between the two cations impacts on the water–RM interface interaction, which provides a way of controlling the solvation process in these RMs. Furthermore, differences in the interfacial fluidity between the two catanionic RMs is observed, a result that is particularly interesting with regard to these systems being used as nanoreactors.
Fil: Villa Perez, Cristian. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Silber, Juana J.. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Falcone, Ruben Dario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Materia
Catanionic Surfactant
Hc
Reverse Micelles
Water Entrapped Supplementary Material For this Article Is Available Online
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/67636
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/67636
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probeVilla Perez, CristianSilber, Juana J.Falcone, Ruben DarioCorrea, Nestor MarianoCatanionic SurfactantHcReverse MicellesWater Entrapped Supplementary Material For this Article Is Available Onlinehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, the absorption and emission behavior of the cationic hemicyanine trans-4-[4(dimethylamino)styryl]-N-methylpyridinium iodide (HC) in reverse micelles (RMs) formed by the catanionic surfactants benzyl-n-hexadecyldimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-BHD) and cetyltrimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-CTA) have been investigated. Our results show that the spectroscopic behavior of HC changes when the dye is dissolved in AOT-BHD or in AOT-CTA RMs. While HC undergoes an intramolecular charge-transfer process upon excitation in AOT-CTA RMs, in AOT-BHD RMs this process is inhibited due to a specific interaction between HC and the polar head group of the BHD+ cation. This implies that the chemical structure of CTA+ and BHD+ cations has a large impact on the excited stated from which HC emission occurs. Additionally, the structural difference between the two cations impacts on the water–RM interface interaction, which provides a way of controlling the solvation process in these RMs. Furthermore, differences in the interfacial fluidity between the two catanionic RMs is observed, a result that is particularly interesting with regard to these systems being used as nanoreactors.Fil: Villa Perez, Cristian. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Silber, Juana J.. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Falcone, Ruben Dario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaIOP Publishing Ltd2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/67636Villa Perez, Cristian; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano; Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe; IOP Publishing Ltd; Methods and Applications in Fluorescence; 5; 4; 12-2017; 1-122050-6120CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://stacks.iop.org/2050-6120/5/i=4/a=044001?key=crossref.0e37d462e980abe9956655cb4fb52b02info:eu-repo/semantics/altIdentifier/doi/10.1088/2050-6120/aa7b64info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:47:08Zoai:ri.conicet.gov.ar:11336/67636instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:47:09.087CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
title Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
spellingShingle Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
Villa Perez, Cristian
Catanionic Surfactant
Hc
Reverse Micelles
Water Entrapped Supplementary Material For this Article Is Available Online
title_short Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
title_full Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
title_fullStr Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
title_full_unstemmed Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
title_sort Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
dc.creator.none.fl_str_mv Villa Perez, Cristian
Silber, Juana J.
Falcone, Ruben Dario
Correa, Nestor Mariano
author Villa Perez, Cristian
author_facet Villa Perez, Cristian
Silber, Juana J.
Falcone, Ruben Dario
Correa, Nestor Mariano
author_role author
author2 Silber, Juana J.
Falcone, Ruben Dario
Correa, Nestor Mariano
author2_role author
author
author
dc.subject.none.fl_str_mv Catanionic Surfactant
Hc
Reverse Micelles
Water Entrapped Supplementary Material For this Article Is Available Online
topic Catanionic Surfactant
Hc
Reverse Micelles
Water Entrapped Supplementary Material For this Article Is Available Online
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, the absorption and emission behavior of the cationic hemicyanine trans-4-[4(dimethylamino)styryl]-N-methylpyridinium iodide (HC) in reverse micelles (RMs) formed by the catanionic surfactants benzyl-n-hexadecyldimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-BHD) and cetyltrimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-CTA) have been investigated. Our results show that the spectroscopic behavior of HC changes when the dye is dissolved in AOT-BHD or in AOT-CTA RMs. While HC undergoes an intramolecular charge-transfer process upon excitation in AOT-CTA RMs, in AOT-BHD RMs this process is inhibited due to a specific interaction between HC and the polar head group of the BHD+ cation. This implies that the chemical structure of CTA+ and BHD+ cations has a large impact on the excited stated from which HC emission occurs. Additionally, the structural difference between the two cations impacts on the water–RM interface interaction, which provides a way of controlling the solvation process in these RMs. Furthermore, differences in the interfacial fluidity between the two catanionic RMs is observed, a result that is particularly interesting with regard to these systems being used as nanoreactors.
Fil: Villa Perez, Cristian. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Silber, Juana J.. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Falcone, Ruben Dario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
description In this work, the absorption and emission behavior of the cationic hemicyanine trans-4-[4(dimethylamino)styryl]-N-methylpyridinium iodide (HC) in reverse micelles (RMs) formed by the catanionic surfactants benzyl-n-hexadecyldimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-BHD) and cetyltrimethylammonium-1,4-bis-2-ethylhexylsulfosuccinate (AOT-CTA) have been investigated. Our results show that the spectroscopic behavior of HC changes when the dye is dissolved in AOT-BHD or in AOT-CTA RMs. While HC undergoes an intramolecular charge-transfer process upon excitation in AOT-CTA RMs, in AOT-BHD RMs this process is inhibited due to a specific interaction between HC and the polar head group of the BHD+ cation. This implies that the chemical structure of CTA+ and BHD+ cations has a large impact on the excited stated from which HC emission occurs. Additionally, the structural difference between the two cations impacts on the water–RM interface interaction, which provides a way of controlling the solvation process in these RMs. Furthermore, differences in the interfacial fluidity between the two catanionic RMs is observed, a result that is particularly interesting with regard to these systems being used as nanoreactors.
publishDate 2017
dc.date.none.fl_str_mv 2017-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/67636
Villa Perez, Cristian; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano; Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe; IOP Publishing Ltd; Methods and Applications in Fluorescence; 5; 4; 12-2017; 1-12
2050-6120
CONICET Digital
CONICET
url http://hdl.handle.net/11336/67636
identifier_str_mv Villa Perez, Cristian; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano; Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe; IOP Publishing Ltd; Methods and Applications in Fluorescence; 5; 4; 12-2017; 1-12
2050-6120
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://stacks.iop.org/2050-6120/5/i=4/a=044001?key=crossref.0e37d462e980abe9956655cb4fb52b02
info:eu-repo/semantics/altIdentifier/doi/10.1088/2050-6120/aa7b64
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv IOP Publishing Ltd
publisher.none.fl_str_mv IOP Publishing Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.087074

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