Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations

Autores
Casero, Carina Noelia; Oberti, Juan Carlos María; Orozco, Clara I.; Cárdenas, Alejandro; Brito, Iván; Barboza, Gloria Estela; Nicotra, Viviana Estela
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nine withanolides were isolated from the aerial parts of Deprea bitteriana, Deprea cuyacensis, and Deprea zamorae. D. bitteriana yielded two withaphysalins, D. cuyacensis gave two 13,14-seco withaphysalins, while D. zamorae yielded five physangulidines. The compounds were fully characterized by a combination of spectroscopic methods (1D and 2D NMR and MS). All compounds isolated from D. bitteriana and D. cuyacensis were obtained as epimeric mixtures at C-18. The structure of physangulidine D was confirmed by X-ray diffraction analysis. The skeletons found in this research support the chemotaxonomical position of the genus Deprea in the tribe Physalideae.
Fil: Casero, Carina Noelia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina
Fil: Oberti, Juan Carlos María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Orozco, Clara I.. Universidad Nacional de Colombia; Colombia
Fil: Cárdenas, Alejandro. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-orgánica "antonio Gonzalez"; España
Fil: Brito, Iván. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-orgánica "antonio Gonzalez"; España
Fil: Barboza, Gloria Estela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Nicotra, Viviana Estela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Materia
Deprea
Solanaceae
Withanolides
Chemataxonomic Markers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/15563
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerationsCasero, Carina NoeliaOberti, Juan Carlos MaríaOrozco, Clara I.Cárdenas, AlejandroBrito, IvánBarboza, Gloria EstelaNicotra, Viviana EstelaDepreaSolanaceaeWithanolidesChemataxonomic Markershttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Nine withanolides were isolated from the aerial parts of Deprea bitteriana, Deprea cuyacensis, and Deprea zamorae. D. bitteriana yielded two withaphysalins, D. cuyacensis gave two 13,14-seco withaphysalins, while D. zamorae yielded five physangulidines. The compounds were fully characterized by a combination of spectroscopic methods (1D and 2D NMR and MS). All compounds isolated from D. bitteriana and D. cuyacensis were obtained as epimeric mixtures at C-18. The structure of physangulidine D was confirmed by X-ray diffraction analysis. The skeletons found in this research support the chemotaxonomical position of the genus Deprea in the tribe Physalideae.Fil: Casero, Carina Noelia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; ArgentinaFil: Oberti, Juan Carlos María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); ArgentinaFil: Orozco, Clara I.. Universidad Nacional de Colombia; ColombiaFil: Cárdenas, Alejandro. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-orgánica "antonio Gonzalez"; EspañaFil: Brito, Iván. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-orgánica "antonio Gonzalez"; EspañaFil: Barboza, Gloria Estela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); ArgentinaFil: Nicotra, Viviana Estela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); ArgentinaElsevier2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/15563Casero, Carina Noelia; Oberti, Juan Carlos María; Orozco, Clara I.; Cárdenas, Alejandro; Brito, Iván; et al.; Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations; Elsevier; Phytochemistry; 110; 1-2015; 83-900031-94221873-3700enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0031942214004981info:eu-repo/semantics/altIdentifier/doi/10.1016/j.phytochem.2014.11.015info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:54:06Zoai:ri.conicet.gov.ar:11336/15563instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:54:06.964CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
title Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
spellingShingle Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
Casero, Carina Noelia
Deprea
Solanaceae
Withanolides
Chemataxonomic Markers
title_short Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
title_full Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
title_fullStr Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
title_full_unstemmed Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
title_sort Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations
dc.creator.none.fl_str_mv Casero, Carina Noelia
Oberti, Juan Carlos María
Orozco, Clara I.
Cárdenas, Alejandro
Brito, Iván
Barboza, Gloria Estela
Nicotra, Viviana Estela
author Casero, Carina Noelia
author_facet Casero, Carina Noelia
Oberti, Juan Carlos María
Orozco, Clara I.
Cárdenas, Alejandro
Brito, Iván
Barboza, Gloria Estela
Nicotra, Viviana Estela
author_role author
author2 Oberti, Juan Carlos María
Orozco, Clara I.
Cárdenas, Alejandro
Brito, Iván
Barboza, Gloria Estela
Nicotra, Viviana Estela
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Deprea
Solanaceae
Withanolides
Chemataxonomic Markers
topic Deprea
Solanaceae
Withanolides
Chemataxonomic Markers
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Nine withanolides were isolated from the aerial parts of Deprea bitteriana, Deprea cuyacensis, and Deprea zamorae. D. bitteriana yielded two withaphysalins, D. cuyacensis gave two 13,14-seco withaphysalins, while D. zamorae yielded five physangulidines. The compounds were fully characterized by a combination of spectroscopic methods (1D and 2D NMR and MS). All compounds isolated from D. bitteriana and D. cuyacensis were obtained as epimeric mixtures at C-18. The structure of physangulidine D was confirmed by X-ray diffraction analysis. The skeletons found in this research support the chemotaxonomical position of the genus Deprea in the tribe Physalideae.
Fil: Casero, Carina Noelia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina
Fil: Oberti, Juan Carlos María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Orozco, Clara I.. Universidad Nacional de Colombia; Colombia
Fil: Cárdenas, Alejandro. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-orgánica "antonio Gonzalez"; España
Fil: Brito, Iván. Universidad de la Laguna. Departamento de Química Orgánica. Instituto Universitario de Bio-orgánica "antonio Gonzalez"; España
Fil: Barboza, Gloria Estela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Nicotra, Viviana Estela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
description Nine withanolides were isolated from the aerial parts of Deprea bitteriana, Deprea cuyacensis, and Deprea zamorae. D. bitteriana yielded two withaphysalins, D. cuyacensis gave two 13,14-seco withaphysalins, while D. zamorae yielded five physangulidines. The compounds were fully characterized by a combination of spectroscopic methods (1D and 2D NMR and MS). All compounds isolated from D. bitteriana and D. cuyacensis were obtained as epimeric mixtures at C-18. The structure of physangulidine D was confirmed by X-ray diffraction analysis. The skeletons found in this research support the chemotaxonomical position of the genus Deprea in the tribe Physalideae.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/15563
Casero, Carina Noelia; Oberti, Juan Carlos María; Orozco, Clara I.; Cárdenas, Alejandro; Brito, Iván; et al.; Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations; Elsevier; Phytochemistry; 110; 1-2015; 83-90
0031-9422
1873-3700
url http://hdl.handle.net/11336/15563
identifier_str_mv Casero, Carina Noelia; Oberti, Juan Carlos María; Orozco, Clara I.; Cárdenas, Alejandro; Brito, Iván; et al.; Withanolides from three species of the genus Deprea (Solanaceae). Chemotaxonomical considerations; Elsevier; Phytochemistry; 110; 1-2015; 83-90
0031-9422
1873-3700
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0031942214004981
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.phytochem.2014.11.015
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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