Relationships between structure and physical properties in SmNi(1-x)Co(x)O3

Autores
Pérez Cacho, J. J.; Blasco, J.; García, J.; Sanchez, Rodolfo Daniel
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of SmNi(1-x)Co(x)O3 perovskites, with 0 ≤ x ≤ 1, has been determined at room temperature by Rietveld analysis from X-ray powder diffraction data. Polycrystalline samples have been prepared using high temperature and high oxygen pressure treatment. Different structural parameters such as the bond lengths or the bond angles, have been compared to the Ni/Co ratio. They have also been correlated with the magnetic and electrical properties of the series. SmNi(1-x)Co(x)O3 are orthorhombic perovskites, space group Pbnm. The expected linear dependence in the oxygen-transition metal bondlengths, d(M-O), for a solid solution, which is often described by the Vergard's law, is modulated by slight structural changes. In the 0.3 ≤ x < 0.9 range, an anomalous increase in d(M-O) can be correlated to the ferromagnetic interactions shown by these samples at low temperatures. In addition, in the x ≤ 0.1 range, there is a decrease in the orthorhombic distortion of the crystal structure along the series which agrees with a composition-driven metal insulator transition at room temperature. These structural features point out the phase diagram proposed earlier for the SmNi(1-x)CO(x)O3 series.
Fil: Pérez Cacho, J. J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: Blasco, J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: García, J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Materia
Bond Valence Calculation
Metal-Insulator Transition
Perovskite
Rietveld Analysis
Spin-Glass
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/68422
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/68422
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Relationships between structure and physical properties in SmNi(1-x)Co(x)O3Pérez Cacho, J. J.Blasco, J.García, J.Sanchez, Rodolfo DanielBond Valence CalculationMetal-Insulator TransitionPerovskiteRietveld AnalysisSpin-Glasshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The crystal structure of SmNi(1-x)Co(x)O3 perovskites, with 0 ≤ x ≤ 1, has been determined at room temperature by Rietveld analysis from X-ray powder diffraction data. Polycrystalline samples have been prepared using high temperature and high oxygen pressure treatment. Different structural parameters such as the bond lengths or the bond angles, have been compared to the Ni/Co ratio. They have also been correlated with the magnetic and electrical properties of the series. SmNi(1-x)Co(x)O3 are orthorhombic perovskites, space group Pbnm. The expected linear dependence in the oxygen-transition metal bondlengths, d(M-O), for a solid solution, which is often described by the Vergard's law, is modulated by slight structural changes. In the 0.3 ≤ x < 0.9 range, an anomalous increase in d(M-O) can be correlated to the ferromagnetic interactions shown by these samples at low temperatures. In addition, in the x ≤ 0.1 range, there is a decrease in the orthorhombic distortion of the crystal structure along the series which agrees with a composition-driven metal insulator transition at room temperature. These structural features point out the phase diagram proposed earlier for the SmNi(1-x)CO(x)O3 series.Fil: Pérez Cacho, J. J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; EspañaFil: Blasco, J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; EspañaFil: García, J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; EspañaFil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaAcademic Press Inc Elsevier Science2000-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/68422Pérez Cacho, J. J.; Blasco, J.; García, J.; Sanchez, Rodolfo Daniel; Relationships between structure and physical properties in SmNi(1-x)Co(x)O3; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 150; 1; 3-2000; 145-1530022-4596CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1006/jssc.1999.8570info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459699985705info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:36Zoai:ri.conicet.gov.ar:11336/68422instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:36.598CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
title Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
spellingShingle Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
Pérez Cacho, J. J.
Bond Valence Calculation
Metal-Insulator Transition
Perovskite
Rietveld Analysis
Spin-Glass
title_short Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
title_full Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
title_fullStr Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
title_full_unstemmed Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
title_sort Relationships between structure and physical properties in SmNi(1-x)Co(x)O3
dc.creator.none.fl_str_mv Pérez Cacho, J. J.
Blasco, J.
García, J.
Sanchez, Rodolfo Daniel
author Pérez Cacho, J. J.
author_facet Pérez Cacho, J. J.
Blasco, J.
García, J.
Sanchez, Rodolfo Daniel
author_role author
author2 Blasco, J.
García, J.
Sanchez, Rodolfo Daniel
author2_role author
author
author
dc.subject.none.fl_str_mv Bond Valence Calculation
Metal-Insulator Transition
Perovskite
Rietveld Analysis
Spin-Glass
topic Bond Valence Calculation
Metal-Insulator Transition
Perovskite
Rietveld Analysis
Spin-Glass
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The crystal structure of SmNi(1-x)Co(x)O3 perovskites, with 0 ≤ x ≤ 1, has been determined at room temperature by Rietveld analysis from X-ray powder diffraction data. Polycrystalline samples have been prepared using high temperature and high oxygen pressure treatment. Different structural parameters such as the bond lengths or the bond angles, have been compared to the Ni/Co ratio. They have also been correlated with the magnetic and electrical properties of the series. SmNi(1-x)Co(x)O3 are orthorhombic perovskites, space group Pbnm. The expected linear dependence in the oxygen-transition metal bondlengths, d(M-O), for a solid solution, which is often described by the Vergard's law, is modulated by slight structural changes. In the 0.3 ≤ x < 0.9 range, an anomalous increase in d(M-O) can be correlated to the ferromagnetic interactions shown by these samples at low temperatures. In addition, in the x ≤ 0.1 range, there is a decrease in the orthorhombic distortion of the crystal structure along the series which agrees with a composition-driven metal insulator transition at room temperature. These structural features point out the phase diagram proposed earlier for the SmNi(1-x)CO(x)O3 series.
Fil: Pérez Cacho, J. J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: Blasco, J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: García, J.. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
description The crystal structure of SmNi(1-x)Co(x)O3 perovskites, with 0 ≤ x ≤ 1, has been determined at room temperature by Rietveld analysis from X-ray powder diffraction data. Polycrystalline samples have been prepared using high temperature and high oxygen pressure treatment. Different structural parameters such as the bond lengths or the bond angles, have been compared to the Ni/Co ratio. They have also been correlated with the magnetic and electrical properties of the series. SmNi(1-x)Co(x)O3 are orthorhombic perovskites, space group Pbnm. The expected linear dependence in the oxygen-transition metal bondlengths, d(M-O), for a solid solution, which is often described by the Vergard's law, is modulated by slight structural changes. In the 0.3 ≤ x < 0.9 range, an anomalous increase in d(M-O) can be correlated to the ferromagnetic interactions shown by these samples at low temperatures. In addition, in the x ≤ 0.1 range, there is a decrease in the orthorhombic distortion of the crystal structure along the series which agrees with a composition-driven metal insulator transition at room temperature. These structural features point out the phase diagram proposed earlier for the SmNi(1-x)CO(x)O3 series.
publishDate 2000
dc.date.none.fl_str_mv 2000-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/68422
Pérez Cacho, J. J.; Blasco, J.; García, J.; Sanchez, Rodolfo Daniel; Relationships between structure and physical properties in SmNi(1-x)Co(x)O3; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 150; 1; 3-2000; 145-153
0022-4596
CONICET Digital
CONICET
url http://hdl.handle.net/11336/68422
identifier_str_mv Pérez Cacho, J. J.; Blasco, J.; García, J.; Sanchez, Rodolfo Daniel; Relationships between structure and physical properties in SmNi(1-x)Co(x)O3; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 150; 1; 3-2000; 145-153
0022-4596
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1006/jssc.1999.8570
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459699985705
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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