Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals
- Autores
- Chiappero, Malisa Susana; Argüello, Gustavo Alejandro; Hurley, M. D.; Wallington, T. J.
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Smog chamber/FTIR techniques were used to measure a 92 ± 7% yield of C8F17CH2CHO in the chlorine atom initiated oxidation of C8F17CH2CH2OH (8:2 FTOH) in 700 Torr of air. Relative rate techniques were used to measure k(Cl + C8F17CH2CHO) = (1.9 ± 0.4) × 10-11 and k(OH + C8F17CH2CHO) = (2.0 ± 0.4) × 10-12 cm3 molecule-1 s-1 in 700 Torr of N2 or air diluent at 296 K. The results are discussed with respect to the atmospheric chemistry of fluorotelomer alcohols.
Fil: Chiappero, Malisa Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Hurley, M. D.. Ford Motor Company; Estados Unidos
Fil: Wallington, T. J.. Ford Motor Company; Estados Unidos - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/75665
Ver los metadatos del registro completo
| id |
CONICETDig_f8b33ba17edaf381d77806e3036ee259 |
|---|---|
| oai_identifier_str |
oai:ri.conicet.gov.ar:11336/75665 |
| network_acronym_str |
CONICETDig |
| repository_id_str |
3498 |
| network_name_str |
CONICET Digital (CONICET) |
| spelling |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicalsChiappero, Malisa SusanaArgüello, Gustavo AlejandroHurley, M. D.Wallington, T. J.https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Smog chamber/FTIR techniques were used to measure a 92 ± 7% yield of C8F17CH2CHO in the chlorine atom initiated oxidation of C8F17CH2CH2OH (8:2 FTOH) in 700 Torr of air. Relative rate techniques were used to measure k(Cl + C8F17CH2CHO) = (1.9 ± 0.4) × 10-11 and k(OH + C8F17CH2CHO) = (2.0 ± 0.4) × 10-12 cm3 molecule-1 s-1 in 700 Torr of N2 or air diluent at 296 K. The results are discussed with respect to the atmospheric chemistry of fluorotelomer alcohols.Fil: Chiappero, Malisa Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Hurley, M. D.. Ford Motor Company; Estados UnidosFil: Wallington, T. J.. Ford Motor Company; Estados UnidosElsevier Science2008-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/75665Chiappero, Malisa Susana; Argüello, Gustavo Alejandro; Hurley, M. D.; Wallington, T. J.; Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals; Elsevier Science; Chemical Physics Letters; 461; 4-6; 8-2008; 198-2020009-2614CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cplett.2008.06.088info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261408009172info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:58:41Zoai:ri.conicet.gov.ar:11336/75665instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:58:41.477CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| title |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| spellingShingle |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals Chiappero, Malisa Susana |
| title_short |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| title_full |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| title_fullStr |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| title_full_unstemmed |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| title_sort |
Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals |
| dc.creator.none.fl_str_mv |
Chiappero, Malisa Susana Argüello, Gustavo Alejandro Hurley, M. D. Wallington, T. J. |
| author |
Chiappero, Malisa Susana |
| author_facet |
Chiappero, Malisa Susana Argüello, Gustavo Alejandro Hurley, M. D. Wallington, T. J. |
| author_role |
author |
| author2 |
Argüello, Gustavo Alejandro Hurley, M. D. Wallington, T. J. |
| author2_role |
author author author |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
Smog chamber/FTIR techniques were used to measure a 92 ± 7% yield of C8F17CH2CHO in the chlorine atom initiated oxidation of C8F17CH2CH2OH (8:2 FTOH) in 700 Torr of air. Relative rate techniques were used to measure k(Cl + C8F17CH2CHO) = (1.9 ± 0.4) × 10-11 and k(OH + C8F17CH2CHO) = (2.0 ± 0.4) × 10-12 cm3 molecule-1 s-1 in 700 Torr of N2 or air diluent at 296 K. The results are discussed with respect to the atmospheric chemistry of fluorotelomer alcohols. Fil: Chiappero, Malisa Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Hurley, M. D.. Ford Motor Company; Estados Unidos Fil: Wallington, T. J.. Ford Motor Company; Estados Unidos |
| description |
Smog chamber/FTIR techniques were used to measure a 92 ± 7% yield of C8F17CH2CHO in the chlorine atom initiated oxidation of C8F17CH2CH2OH (8:2 FTOH) in 700 Torr of air. Relative rate techniques were used to measure k(Cl + C8F17CH2CHO) = (1.9 ± 0.4) × 10-11 and k(OH + C8F17CH2CHO) = (2.0 ± 0.4) × 10-12 cm3 molecule-1 s-1 in 700 Torr of N2 or air diluent at 296 K. The results are discussed with respect to the atmospheric chemistry of fluorotelomer alcohols. |
| publishDate |
2008 |
| dc.date.none.fl_str_mv |
2008-08 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/75665 Chiappero, Malisa Susana; Argüello, Gustavo Alejandro; Hurley, M. D.; Wallington, T. J.; Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals; Elsevier Science; Chemical Physics Letters; 461; 4-6; 8-2008; 198-202 0009-2614 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/75665 |
| identifier_str_mv |
Chiappero, Malisa Susana; Argüello, Gustavo Alejandro; Hurley, M. D.; Wallington, T. J.; Atmospheric chemistry of C8F17CH2CHO: Yield from C8F17CH2CH2OH (8:2 FTOH) oxidation, kinetics and mechanisms of reactions with Cl atoms and OH radicals; Elsevier Science; Chemical Physics Letters; 461; 4-6; 8-2008; 198-202 0009-2614 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cplett.2008.06.088 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261408009172 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
| eu_rights_str_mv |
openAccess |
| rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
| dc.format.none.fl_str_mv |
application/pdf application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier Science |
| publisher.none.fl_str_mv |
Elsevier Science |
| dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
| reponame_str |
CONICET Digital (CONICET) |
| collection |
CONICET Digital (CONICET) |
| instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
| repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
| repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
| _version_ |
1842269535666700288 |
| score |
13.13397 |