Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)

Autores
Abraham, Gustavo Abel; Gallardo, Alberto; Mota, Antonella; Migliaresi, Claudio; San Roman, Julio
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Poly(methyl methacrylate) – polycaprolactone (PMMA/PCL) microheterogeneous beads were synthesized by suspension polymerization starting from methyl methacrylate (MMA) monomer and PCL, which was synthesized by ring-opening polymerization of ε-caprolactone using ZnCl2 as initiator. The resulting polymer was fully characterized by 1H and 13C NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC) and dynamic mechanical thermal analysis (DMTA). The size distribution and morphology of the resulting beads were investigated by optical microscopy and scanning electron microscopy (SEM). Moreover, blends of PMMA beads and PCL in different proportions were prepared and the morphology of the films was examined by optical microscopy. The low compatibility between PMMA and PCL was clearly evidenced through these experiments.
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Gallardo, Alberto. Instituto de Ciencia y Tecnologia de Polimeros; España
Fil: Mota, Antonella. Universita´ di Trento; Italia
Fil: Migliaresi, Claudio. Universita´ di Trento; Italia
Fil: San Roman, Julio. Instituto de Ciencia y Tecnologia de Polimeros; España
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/35734
Acceder
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spelling Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)Abraham, Gustavo AbelGallardo, AlbertoMota, AntonellaMigliaresi, ClaudioSan Roman, Juliohttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Poly(methyl methacrylate) – polycaprolactone (PMMA/PCL) microheterogeneous beads were synthesized by suspension polymerization starting from methyl methacrylate (MMA) monomer and PCL, which was synthesized by ring-opening polymerization of ε-caprolactone using ZnCl2 as initiator. The resulting polymer was fully characterized by 1H and 13C NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC) and dynamic mechanical thermal analysis (DMTA). The size distribution and morphology of the resulting beads were investigated by optical microscopy and scanning electron microscopy (SEM). Moreover, blends of PMMA beads and PCL in different proportions were prepared and the morphology of the films was examined by optical microscopy. The low compatibility between PMMA and PCL was clearly evidenced through these experiments.Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Gallardo, Alberto. Instituto de Ciencia y Tecnologia de Polimeros; EspañaFil: Mota, Antonella. Universita´ di Trento; ItaliaFil: Migliaresi, Claudio. Universita´ di Trento; ItaliaFil: San Roman, Julio. Instituto de Ciencia y Tecnologia de Polimeros; EspañaWiley VCH Verlag2000-10-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/35734Abraham, Gustavo Abel; Gallardo, Alberto; Mota, Antonella; Migliaresi, Claudio; San Roman, Julio; Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone); Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 282; 1; 19-10-2000; 44-501438-7492CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/1439-2054(20001001)282:1<44::AID-MAME44>3.0.CO;2-Kinfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1439-2054(20001001)282:1%3C44::AID-MAME44%3E3.0.CO;2-K/fullinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:22Zoai:ri.conicet.gov.ar:11336/35734instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:22.915CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
title Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
spellingShingle Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
Abraham, Gustavo Abel
title_short Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
title_full Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
title_fullStr Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
title_full_unstemmed Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
title_sort Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
dc.creator.none.fl_str_mv Abraham, Gustavo Abel
Gallardo, Alberto
Mota, Antonella
Migliaresi, Claudio
San Roman, Julio
author Abraham, Gustavo Abel
author_facet Abraham, Gustavo Abel
Gallardo, Alberto
Mota, Antonella
Migliaresi, Claudio
San Roman, Julio
author_role author
author2 Gallardo, Alberto
Mota, Antonella
Migliaresi, Claudio
San Roman, Julio
author2_role author
author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Poly(methyl methacrylate) – polycaprolactone (PMMA/PCL) microheterogeneous beads were synthesized by suspension polymerization starting from methyl methacrylate (MMA) monomer and PCL, which was synthesized by ring-opening polymerization of ε-caprolactone using ZnCl2 as initiator. The resulting polymer was fully characterized by 1H and 13C NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC) and dynamic mechanical thermal analysis (DMTA). The size distribution and morphology of the resulting beads were investigated by optical microscopy and scanning electron microscopy (SEM). Moreover, blends of PMMA beads and PCL in different proportions were prepared and the morphology of the films was examined by optical microscopy. The low compatibility between PMMA and PCL was clearly evidenced through these experiments.
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Gallardo, Alberto. Instituto de Ciencia y Tecnologia de Polimeros; España
Fil: Mota, Antonella. Universita´ di Trento; Italia
Fil: Migliaresi, Claudio. Universita´ di Trento; Italia
Fil: San Roman, Julio. Instituto de Ciencia y Tecnologia de Polimeros; España
description Poly(methyl methacrylate) – polycaprolactone (PMMA/PCL) microheterogeneous beads were synthesized by suspension polymerization starting from methyl methacrylate (MMA) monomer and PCL, which was synthesized by ring-opening polymerization of ε-caprolactone using ZnCl2 as initiator. The resulting polymer was fully characterized by 1H and 13C NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC) and dynamic mechanical thermal analysis (DMTA). The size distribution and morphology of the resulting beads were investigated by optical microscopy and scanning electron microscopy (SEM). Moreover, blends of PMMA beads and PCL in different proportions were prepared and the morphology of the films was examined by optical microscopy. The low compatibility between PMMA and PCL was clearly evidenced through these experiments.
publishDate 2000
dc.date.none.fl_str_mv 2000-10-19
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/35734
Abraham, Gustavo Abel; Gallardo, Alberto; Mota, Antonella; Migliaresi, Claudio; San Roman, Julio; Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone); Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 282; 1; 19-10-2000; 44-50
1438-7492
CONICET Digital
CONICET
url http://hdl.handle.net/11336/35734
identifier_str_mv Abraham, Gustavo Abel; Gallardo, Alberto; Mota, Antonella; Migliaresi, Claudio; San Roman, Julio; Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone); Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 282; 1; 19-10-2000; 44-50
1438-7492
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/1439-2054(20001001)282:1<44::AID-MAME44>3.0.CO;2-K
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1439-2054(20001001)282:1%3C44::AID-MAME44%3E3.0.CO;2-K/full
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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