Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites

Autores
Gómez Costa, Marcos Bruno; Juarez, Juliana; Martinez, Maria Laura; Beltramone, Andrea Raquel; Cussa, Jorgelina; Anunziata, Oscar Alfredo
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Si-SBA-3 and Na-AlSBA-3 materials were synthesized for application in the preparation of composites. Silica mesoporous materials were obtained following the sol-gel method and post-synthesis alumination. Pyrrole-saturated hosts were prepared by adsorption of pyrrole into the mesoporous materials. The adsorption/desorption of pyrrole was studied by FTIR. Molecules of pyrrole would be adsorbed through aromatic ring to the host. The polymerization technique was performed by oxidative way using different oxidizing agents, ammonium persulfate and ferric chloride, after pyrrole adsorption on both hosts. TG, FTIR, BET, XRD, SEM and TEM were used to characterize the resulting composites. These studies show that polypyrrole is generated inside the channel of the hosts; conductivity studies show that the composites exhibit conductivities at room temperature and in the range of 1x10 7 and 1x10 6 Scm 1depending on the host and the oxidizing agents.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Juarez, Juliana. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Martinez, Maria Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Materia
Composites
Nanostructures
Polymers
Infrared Spectroscopy
X-Ray Diffraction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/79366

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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 compositesGómez Costa, Marcos BrunoJuarez, JulianaMartinez, Maria LauraBeltramone, Andrea RaquelCussa, JorgelinaAnunziata, Oscar AlfredoCompositesNanostructuresPolymersInfrared SpectroscopyX-Ray Diffractionhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Si-SBA-3 and Na-AlSBA-3 materials were synthesized for application in the preparation of composites. Silica mesoporous materials were obtained following the sol-gel method and post-synthesis alumination. Pyrrole-saturated hosts were prepared by adsorption of pyrrole into the mesoporous materials. The adsorption/desorption of pyrrole was studied by FTIR. Molecules of pyrrole would be adsorbed through aromatic ring to the host. The polymerization technique was performed by oxidative way using different oxidizing agents, ammonium persulfate and ferric chloride, after pyrrole adsorption on both hosts. TG, FTIR, BET, XRD, SEM and TEM were used to characterize the resulting composites. These studies show that polypyrrole is generated inside the channel of the hosts; conductivity studies show that the composites exhibit conductivities at room temperature and in the range of 1x10 7 and 1x10 6 Scm 1depending on the host and the oxidizing agents.Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Juarez, Juliana. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Martinez, Maria Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaPergamon-Elsevier Science Ltd2013-02-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79366Gómez Costa, Marcos Bruno; Juarez, Juliana; Martinez, Maria Laura; Beltramone, Andrea Raquel; Cussa, Jorgelina; et al.; Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 48; 2; 15-2-2013; 661-6670025-5408CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540812008653info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2012.11.030info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:19Zoai:ri.conicet.gov.ar:11336/79366instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:20.23CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
title Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
spellingShingle Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
Gómez Costa, Marcos Bruno
Composites
Nanostructures
Polymers
Infrared Spectroscopy
X-Ray Diffraction
title_short Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
title_full Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
title_fullStr Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
title_full_unstemmed Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
title_sort Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites
dc.creator.none.fl_str_mv Gómez Costa, Marcos Bruno
Juarez, Juliana
Martinez, Maria Laura
Beltramone, Andrea Raquel
Cussa, Jorgelina
Anunziata, Oscar Alfredo
author Gómez Costa, Marcos Bruno
author_facet Gómez Costa, Marcos Bruno
Juarez, Juliana
Martinez, Maria Laura
Beltramone, Andrea Raquel
Cussa, Jorgelina
Anunziata, Oscar Alfredo
author_role author
author2 Juarez, Juliana
Martinez, Maria Laura
Beltramone, Andrea Raquel
Cussa, Jorgelina
Anunziata, Oscar Alfredo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Composites
Nanostructures
Polymers
Infrared Spectroscopy
X-Ray Diffraction
topic Composites
Nanostructures
Polymers
Infrared Spectroscopy
X-Ray Diffraction
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Si-SBA-3 and Na-AlSBA-3 materials were synthesized for application in the preparation of composites. Silica mesoporous materials were obtained following the sol-gel method and post-synthesis alumination. Pyrrole-saturated hosts were prepared by adsorption of pyrrole into the mesoporous materials. The adsorption/desorption of pyrrole was studied by FTIR. Molecules of pyrrole would be adsorbed through aromatic ring to the host. The polymerization technique was performed by oxidative way using different oxidizing agents, ammonium persulfate and ferric chloride, after pyrrole adsorption on both hosts. TG, FTIR, BET, XRD, SEM and TEM were used to characterize the resulting composites. These studies show that polypyrrole is generated inside the channel of the hosts; conductivity studies show that the composites exhibit conductivities at room temperature and in the range of 1x10 7 and 1x10 6 Scm 1depending on the host and the oxidizing agents.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Juarez, Juliana. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Martinez, Maria Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
description Si-SBA-3 and Na-AlSBA-3 materials were synthesized for application in the preparation of composites. Silica mesoporous materials were obtained following the sol-gel method and post-synthesis alumination. Pyrrole-saturated hosts were prepared by adsorption of pyrrole into the mesoporous materials. The adsorption/desorption of pyrrole was studied by FTIR. Molecules of pyrrole would be adsorbed through aromatic ring to the host. The polymerization technique was performed by oxidative way using different oxidizing agents, ammonium persulfate and ferric chloride, after pyrrole adsorption on both hosts. TG, FTIR, BET, XRD, SEM and TEM were used to characterize the resulting composites. These studies show that polypyrrole is generated inside the channel of the hosts; conductivity studies show that the composites exhibit conductivities at room temperature and in the range of 1x10 7 and 1x10 6 Scm 1depending on the host and the oxidizing agents.
publishDate 2013
dc.date.none.fl_str_mv 2013-02-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/79366
Gómez Costa, Marcos Bruno; Juarez, Juliana; Martinez, Maria Laura; Beltramone, Andrea Raquel; Cussa, Jorgelina; et al.; Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 48; 2; 15-2-2013; 661-667
0025-5408
CONICET Digital
CONICET
url http://hdl.handle.net/11336/79366
identifier_str_mv Gómez Costa, Marcos Bruno; Juarez, Juliana; Martinez, Maria Laura; Beltramone, Andrea Raquel; Cussa, Jorgelina; et al.; Synthesis and characterization of conducting polypyrrole/SBA-3 and polypyrrole/Na-AlSBA-3 composites; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 48; 2; 15-2-2013; 661-667
0025-5408
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540812008653
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2012.11.030
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
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application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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