Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation

Autores
Pinzón Rueda, Carlos Alberto; Martínez Clemente, Nahuel Facundo; Casas, Guillermo; Alvira, Fernando Carlos; Denon, Nicole Alexandra; Brusasco, Carlos Gaston; Medina Chanduvi, Hugo Harold; Gil Rebaza, Arles Víctor; Cappelletti, Marcelo Angel
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Perovskite solar cells (PSCs) have substantially increased their power conversion efficiency(PCE) to more than 25% in recent years. However, the instability of these devices is still astrong obstacle for their commercial applications. Recently, all-inorganic PSCs based on CsPbI3 andCsPbI2Br as the perovskite layer have shown enhanced long-term stability, which makes them potentialcandidates for commercialization. Currently, all-inorganic PSCs with inverted p-i-n configurationhave not yet reached the high efficiency achieved in the normal n-i-p structure. However, theinverted p-i-n architecture has recently drawn attention of researchers because it is more suitable toprepare tandem solar cells. In this work, a theoretical study of inverted p-i-n all-inorganic PSCsbased on CsPbI3 and CsPbI2Br as the perovskite layer was carried out using SCAPS-1D software.The performance of different architectures of PSC was examined and compared by means of numericalsimulations using various inorganic materials as the hole transport layer (HTL) and theelectron transport layer (ETL). The results reveal that CuI and ZnO are the most suitable as HTLand ETL, respectively. In addition, the performance of the devices was significantly improved byoptimizing the hole mobility in CuI as well as the thickness, doping density, and defect density inthe absorber layer. Maximum efficiencies of 26.5% and 20.6% were obtained under optimized conditionsfor the inverted all-inorganic CsPbI3- and CsPbI2Br-based PSCs, respectively. These resultsindicate that further improvements in the performance of such devices are still possible.
Fil: Pinzón Rueda, Carlos Alberto. Universidad Nacional de Quilmes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto Multidisciplinario de Biología Celular. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto Multidisciplinario de Biología Celular. Universidad Nacional de La Plata. Instituto Multidisciplinario de Biología Celular; Argentina
Fil: Martínez Clemente, Nahuel Facundo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. Sede Olavarría del Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aire. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. Sede Olavarría del Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional de Quilmes; Argentina
Fil: Casas, Guillermo. Universidad Nacional de Quilmes; Argentina
Fil: Alvira, Fernando Carlos. Universidad Nacional de Quilmes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Denon, Nicole Alexandra. Universidad Nacional Arturo Jauretche; Argentina
Fil: Brusasco, Carlos Gaston. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Medina Chanduvi, Hugo Harold. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Gil Rebaza, Arles Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Cappelletti, Marcelo Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones en Electrónica, Control y Procesamiento de Señales. Universidad Nacional de La Plata. Instituto de Investigaciones en Electrónica, Control y Procesamiento de Señales; Argentina
Materia
ALL-INORGANIC PEROVSKITE SOLAR CELLS
CSPBI3
CSPBI2BR
INVERTED P-I-N ARCHITECTURE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/211495
Acceder
id CONICETDig_f5a27ded1ab1cfb3f9ba228178f90c3c
oai_identifier_str oai:ri.conicet.gov.ar:11336/211495
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D SimulationPinzón Rueda, Carlos AlbertoMartínez Clemente, Nahuel FacundoCasas, GuillermoAlvira, Fernando CarlosDenon, Nicole AlexandraBrusasco, Carlos GastonMedina Chanduvi, Hugo HaroldGil Rebaza, Arles VíctorCappelletti, Marcelo AngelALL-INORGANIC PEROVSKITE SOLAR CELLSCSPBI3CSPBI2BRINVERTED P-I-N ARCHITECTUREhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Perovskite solar cells (PSCs) have substantially increased their power conversion efficiency(PCE) to more than 25% in recent years. However, the instability of these devices is still astrong obstacle for their commercial applications. Recently, all-inorganic PSCs based on CsPbI3 andCsPbI2Br as the perovskite layer have shown enhanced long-term stability, which makes them potentialcandidates for commercialization. Currently, all-inorganic PSCs with inverted p-i-n configurationhave not yet reached the high efficiency achieved in the normal n-i-p structure. However, theinverted p-i-n architecture has recently drawn attention of researchers because it is more suitable toprepare tandem solar cells. In this work, a theoretical study of inverted p-i-n all-inorganic PSCsbased on CsPbI3 and CsPbI2Br as the perovskite layer was carried out using SCAPS-1D software.The performance of different architectures of PSC was examined and compared by means of numericalsimulations using various inorganic materials as the hole transport layer (HTL) and theelectron transport layer (ETL). The results reveal that CuI and ZnO are the most suitable as HTLand ETL, respectively. In addition, the performance of the devices was significantly improved byoptimizing the hole mobility in CuI as well as the thickness, doping density, and defect density inthe absorber layer. Maximum efficiencies of 26.5% and 20.6% were obtained under optimized conditionsfor the inverted all-inorganic CsPbI3- and CsPbI2Br-based PSCs, respectively. These resultsindicate that further improvements in the performance of such devices are still possible.Fil: Pinzón Rueda, Carlos Alberto. Universidad Nacional de Quilmes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto Multidisciplinario de Biología Celular. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto Multidisciplinario de Biología Celular. Universidad Nacional de La Plata. Instituto Multidisciplinario de Biología Celular; ArgentinaFil: Martínez Clemente, Nahuel Facundo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. Sede Olavarría del Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aire. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. Sede Olavarría del Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional de Quilmes; ArgentinaFil: Casas, Guillermo. Universidad Nacional de Quilmes; ArgentinaFil: Alvira, Fernando Carlos. Universidad Nacional de Quilmes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Denon, Nicole Alexandra. Universidad Nacional Arturo Jauretche; ArgentinaFil: Brusasco, Carlos Gaston. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Medina Chanduvi, Hugo Harold. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Gil Rebaza, Arles Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Cappelletti, Marcelo Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones en Electrónica, Control y Procesamiento de Señales. Universidad Nacional de La Plata. Instituto de Investigaciones en Electrónica, Control y Procesamiento de Señales; ArgentinaMDPI2022-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/211495Pinzón Rueda, Carlos Alberto; Martínez Clemente, Nahuel Facundo; Casas, Guillermo; Alvira, Fernando Carlos; Denon, Nicole Alexandra; et al.; Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation; MDPI; Solar; 2; 12-2022; 1-131816-2924CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/solar2040033info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:46Zoai:ri.conicet.gov.ar:11336/211495instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:46.633CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
title Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
spellingShingle Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
Pinzón Rueda, Carlos Alberto
ALL-INORGANIC PEROVSKITE SOLAR CELLS
CSPBI3
CSPBI2BR
INVERTED P-I-N ARCHITECTURE
title_short Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
title_full Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
title_fullStr Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
title_full_unstemmed Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
title_sort Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation
dc.creator.none.fl_str_mv Pinzón Rueda, Carlos Alberto
Martínez Clemente, Nahuel Facundo
Casas, Guillermo
Alvira, Fernando Carlos
Denon, Nicole Alexandra
Brusasco, Carlos Gaston
Medina Chanduvi, Hugo Harold
Gil Rebaza, Arles Víctor
Cappelletti, Marcelo Angel
author Pinzón Rueda, Carlos Alberto
author_facet Pinzón Rueda, Carlos Alberto
Martínez Clemente, Nahuel Facundo
Casas, Guillermo
Alvira, Fernando Carlos
Denon, Nicole Alexandra
Brusasco, Carlos Gaston
Medina Chanduvi, Hugo Harold
Gil Rebaza, Arles Víctor
Cappelletti, Marcelo Angel
author_role author
author2 Martínez Clemente, Nahuel Facundo
Casas, Guillermo
Alvira, Fernando Carlos
Denon, Nicole Alexandra
Brusasco, Carlos Gaston
Medina Chanduvi, Hugo Harold
Gil Rebaza, Arles Víctor
Cappelletti, Marcelo Angel
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv ALL-INORGANIC PEROVSKITE SOLAR CELLS
CSPBI3
CSPBI2BR
INVERTED P-I-N ARCHITECTURE
topic ALL-INORGANIC PEROVSKITE SOLAR CELLS
CSPBI3
CSPBI2BR
INVERTED P-I-N ARCHITECTURE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Perovskite solar cells (PSCs) have substantially increased their power conversion efficiency(PCE) to more than 25% in recent years. However, the instability of these devices is still astrong obstacle for their commercial applications. Recently, all-inorganic PSCs based on CsPbI3 andCsPbI2Br as the perovskite layer have shown enhanced long-term stability, which makes them potentialcandidates for commercialization. Currently, all-inorganic PSCs with inverted p-i-n configurationhave not yet reached the high efficiency achieved in the normal n-i-p structure. However, theinverted p-i-n architecture has recently drawn attention of researchers because it is more suitable toprepare tandem solar cells. In this work, a theoretical study of inverted p-i-n all-inorganic PSCsbased on CsPbI3 and CsPbI2Br as the perovskite layer was carried out using SCAPS-1D software.The performance of different architectures of PSC was examined and compared by means of numericalsimulations using various inorganic materials as the hole transport layer (HTL) and theelectron transport layer (ETL). The results reveal that CuI and ZnO are the most suitable as HTLand ETL, respectively. In addition, the performance of the devices was significantly improved byoptimizing the hole mobility in CuI as well as the thickness, doping density, and defect density inthe absorber layer. Maximum efficiencies of 26.5% and 20.6% were obtained under optimized conditionsfor the inverted all-inorganic CsPbI3- and CsPbI2Br-based PSCs, respectively. These resultsindicate that further improvements in the performance of such devices are still possible.
Fil: Pinzón Rueda, Carlos Alberto. Universidad Nacional de Quilmes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto Multidisciplinario de Biología Celular. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto Multidisciplinario de Biología Celular. Universidad Nacional de La Plata. Instituto Multidisciplinario de Biología Celular; Argentina
Fil: Martínez Clemente, Nahuel Facundo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. Sede Olavarría del Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aire. Universidad Nacional del Centro de la Provincia de Buenos Aires. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires. Sede Olavarría del Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina. Universidad Nacional de Quilmes; Argentina
Fil: Casas, Guillermo. Universidad Nacional de Quilmes; Argentina
Fil: Alvira, Fernando Carlos. Universidad Nacional de Quilmes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Denon, Nicole Alexandra. Universidad Nacional Arturo Jauretche; Argentina
Fil: Brusasco, Carlos Gaston. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Medina Chanduvi, Hugo Harold. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Gil Rebaza, Arles Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Cappelletti, Marcelo Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones en Electrónica, Control y Procesamiento de Señales. Universidad Nacional de La Plata. Instituto de Investigaciones en Electrónica, Control y Procesamiento de Señales; Argentina
description Perovskite solar cells (PSCs) have substantially increased their power conversion efficiency(PCE) to more than 25% in recent years. However, the instability of these devices is still astrong obstacle for their commercial applications. Recently, all-inorganic PSCs based on CsPbI3 andCsPbI2Br as the perovskite layer have shown enhanced long-term stability, which makes them potentialcandidates for commercialization. Currently, all-inorganic PSCs with inverted p-i-n configurationhave not yet reached the high efficiency achieved in the normal n-i-p structure. However, theinverted p-i-n architecture has recently drawn attention of researchers because it is more suitable toprepare tandem solar cells. In this work, a theoretical study of inverted p-i-n all-inorganic PSCsbased on CsPbI3 and CsPbI2Br as the perovskite layer was carried out using SCAPS-1D software.The performance of different architectures of PSC was examined and compared by means of numericalsimulations using various inorganic materials as the hole transport layer (HTL) and theelectron transport layer (ETL). The results reveal that CuI and ZnO are the most suitable as HTLand ETL, respectively. In addition, the performance of the devices was significantly improved byoptimizing the hole mobility in CuI as well as the thickness, doping density, and defect density inthe absorber layer. Maximum efficiencies of 26.5% and 20.6% were obtained under optimized conditionsfor the inverted all-inorganic CsPbI3- and CsPbI2Br-based PSCs, respectively. These resultsindicate that further improvements in the performance of such devices are still possible.
publishDate 2022
dc.date.none.fl_str_mv 2022-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/211495
Pinzón Rueda, Carlos Alberto; Martínez Clemente, Nahuel Facundo; Casas, Guillermo; Alvira, Fernando Carlos; Denon, Nicole Alexandra; et al.; Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation; MDPI; Solar; 2; 12-2022; 1-13
1816-2924
CONICET Digital
CONICET
url http://hdl.handle.net/11336/211495
identifier_str_mv Pinzón Rueda, Carlos Alberto; Martínez Clemente, Nahuel Facundo; Casas, Guillermo; Alvira, Fernando Carlos; Denon, Nicole Alexandra; et al.; Optimization of Inverted All-Inorganic CsPbI3 and CsPbI2Br Perovskite Solar Cells by SCAPS-1D Simulation; MDPI; Solar; 2; 12-2022; 1-13
1816-2924
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/solar2040033
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613408828162048
score 13.070432

Publicaciones similares