Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology

Autores
Salvatori, Pablo Ernesto; Sánchez, Gastón; Lombardi, Aldo; Nicocia, Esteban; Bortolato, Santiago Andres; Boschetti, Carlos Eugenio
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In order to find the best combination of three synthetic rubbers, that is, styrene-butadiene rubber (SBR) grade 1712, SBR grade 1721 and high-1,4-cis polybutadiene, that produce a compound with specific end-use properties, a statistical experimental design is proposed in this work. The design consists of ten mixtures containing specific amounts of total styrene and BR content. A number of properties are tested in each mixture, selecting those related to requirements for the tread of a high performance tire: glass transition temperature (Tg), the ratio between the viscous modulus and the elastic modulus (tanδ@60 °C), Mooney viscosity, and the tensile properties. The values obtained for each property are fit to statistically significant models, obtaining the respective response surfaces. These are next used to define a desirable formulation with the optimal ratio of each rubber, and finally the optimized formulation is validated by comparing the experimental and predicted values for each modeled property.
Fil: Salvatori, Pablo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
Fil: Sánchez, Gastón. Pampa Energia Sa-planat Puerto General San Martín; Argentina
Fil: Lombardi, Aldo. Pampa Energia Sa-planat Puerto General San Martín; Argentina
Fil: Nicocia, Esteban. Pampa Energia Sa-planat Puerto General San Martín; Argentina
Fil: Bortolato, Santiago Andres. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina
Fil: Boschetti, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
Materia
BLENDS
MANUFACTURING
MECHANICAL PROPERTIES
RUBBER
THERMAL PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86760
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/86760
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodologySalvatori, Pablo ErnestoSánchez, GastónLombardi, AldoNicocia, EstebanBortolato, Santiago AndresBoschetti, Carlos EugenioBLENDSMANUFACTURINGMECHANICAL PROPERTIESRUBBERTHERMAL PROPERTIEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In order to find the best combination of three synthetic rubbers, that is, styrene-butadiene rubber (SBR) grade 1712, SBR grade 1721 and high-1,4-cis polybutadiene, that produce a compound with specific end-use properties, a statistical experimental design is proposed in this work. The design consists of ten mixtures containing specific amounts of total styrene and BR content. A number of properties are tested in each mixture, selecting those related to requirements for the tread of a high performance tire: glass transition temperature (Tg), the ratio between the viscous modulus and the elastic modulus (tanδ@60 °C), Mooney viscosity, and the tensile properties. The values obtained for each property are fit to statistically significant models, obtaining the respective response surfaces. These are next used to define a desirable formulation with the optimal ratio of each rubber, and finally the optimized formulation is validated by comparing the experimental and predicted values for each modeled property.Fil: Salvatori, Pablo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; ArgentinaFil: Sánchez, Gastón. Pampa Energia Sa-planat Puerto General San Martín; ArgentinaFil: Lombardi, Aldo. Pampa Energia Sa-planat Puerto General San Martín; ArgentinaFil: Nicocia, Esteban. Pampa Energia Sa-planat Puerto General San Martín; ArgentinaFil: Bortolato, Santiago Andres. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; ArgentinaFil: Boschetti, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; ArgentinaJohn Wiley & Sons Inc2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86760Salvatori, Pablo Ernesto; Sánchez, Gastón; Lombardi, Aldo; Nicocia, Esteban; Bortolato, Santiago Andres; et al.; Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology; John Wiley & Sons Inc; Journal of Applied Polymer Science; 135; 30; 8-2018; 1-9; 465480021-89951097-4628CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.46548info:eu-repo/semantics/altIdentifier/doi/10.1002/app.46548info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T11:22:29Zoai:ri.conicet.gov.ar:11336/86760instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 11:22:29.85CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
title Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
spellingShingle Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
Salvatori, Pablo Ernesto
BLENDS
MANUFACTURING
MECHANICAL PROPERTIES
RUBBER
THERMAL PROPERTIES
title_short Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
title_full Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
title_fullStr Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
title_full_unstemmed Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
title_sort Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology
dc.creator.none.fl_str_mv Salvatori, Pablo Ernesto
Sánchez, Gastón
Lombardi, Aldo
Nicocia, Esteban
Bortolato, Santiago Andres
Boschetti, Carlos Eugenio
author Salvatori, Pablo Ernesto
author_facet Salvatori, Pablo Ernesto
Sánchez, Gastón
Lombardi, Aldo
Nicocia, Esteban
Bortolato, Santiago Andres
Boschetti, Carlos Eugenio
author_role author
author2 Sánchez, Gastón
Lombardi, Aldo
Nicocia, Esteban
Bortolato, Santiago Andres
Boschetti, Carlos Eugenio
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv BLENDS
MANUFACTURING
MECHANICAL PROPERTIES
RUBBER
THERMAL PROPERTIES
topic BLENDS
MANUFACTURING
MECHANICAL PROPERTIES
RUBBER
THERMAL PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In order to find the best combination of three synthetic rubbers, that is, styrene-butadiene rubber (SBR) grade 1712, SBR grade 1721 and high-1,4-cis polybutadiene, that produce a compound with specific end-use properties, a statistical experimental design is proposed in this work. The design consists of ten mixtures containing specific amounts of total styrene and BR content. A number of properties are tested in each mixture, selecting those related to requirements for the tread of a high performance tire: glass transition temperature (Tg), the ratio between the viscous modulus and the elastic modulus (tanδ@60 °C), Mooney viscosity, and the tensile properties. The values obtained for each property are fit to statistically significant models, obtaining the respective response surfaces. These are next used to define a desirable formulation with the optimal ratio of each rubber, and finally the optimized formulation is validated by comparing the experimental and predicted values for each modeled property.
Fil: Salvatori, Pablo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
Fil: Sánchez, Gastón. Pampa Energia Sa-planat Puerto General San Martín; Argentina
Fil: Lombardi, Aldo. Pampa Energia Sa-planat Puerto General San Martín; Argentina
Fil: Nicocia, Esteban. Pampa Energia Sa-planat Puerto General San Martín; Argentina
Fil: Bortolato, Santiago Andres. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina
Fil: Boschetti, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
description In order to find the best combination of three synthetic rubbers, that is, styrene-butadiene rubber (SBR) grade 1712, SBR grade 1721 and high-1,4-cis polybutadiene, that produce a compound with specific end-use properties, a statistical experimental design is proposed in this work. The design consists of ten mixtures containing specific amounts of total styrene and BR content. A number of properties are tested in each mixture, selecting those related to requirements for the tread of a high performance tire: glass transition temperature (Tg), the ratio between the viscous modulus and the elastic modulus (tanδ@60 °C), Mooney viscosity, and the tensile properties. The values obtained for each property are fit to statistically significant models, obtaining the respective response surfaces. These are next used to define a desirable formulation with the optimal ratio of each rubber, and finally the optimized formulation is validated by comparing the experimental and predicted values for each modeled property.
publishDate 2018
dc.date.none.fl_str_mv 2018-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86760
Salvatori, Pablo Ernesto; Sánchez, Gastón; Lombardi, Aldo; Nicocia, Esteban; Bortolato, Santiago Andres; et al.; Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology; John Wiley & Sons Inc; Journal of Applied Polymer Science; 135; 30; 8-2018; 1-9; 46548
0021-8995
1097-4628
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86760
identifier_str_mv Salvatori, Pablo Ernesto; Sánchez, Gastón; Lombardi, Aldo; Nicocia, Esteban; Bortolato, Santiago Andres; et al.; Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology; John Wiley & Sons Inc; Journal of Applied Polymer Science; 135; 30; 8-2018; 1-9; 46548
0021-8995
1097-4628
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.46548
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.46548
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1847426176866320384
score 13.10058

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