Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states

Autores
Ruderman, Andres; Dente, Axel Damián; Santos, Elizabeth del Carmen; Pastawski, Horacio Miguel
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Weaddress a molecular dissociation mechanism that is known to occur when aH2 molecule approaches a catalyst with its molecular axis parallel to the surface. It is found that molecular dissociation is a form of quantum dynamical phase transition associated to an analytic discontinuity of quite unusual nature: the molecule is destabilized by the transition from non-physical virtual states into actual localized states. Current description complements our recent results for a molecule approaching the catalyst with its molecular axis perpendicular to the surface (Ruderman et al 2015 J. Phys.: Condens. Matter 27 315501). Also, such a description can be seen as a further successful implementation of a non-Hermitian Hamiltonian in a well defined model.
Fil: Ruderman, Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Dente, Axel Damián. Invap S. E.; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Santos, Elizabeth del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Pastawski, Horacio Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Materia
ATOMS
MOLECULES
TRANSITION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/186038
Acceder
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spelling Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized statesRuderman, AndresDente, Axel DamiánSantos, Elizabeth del CarmenPastawski, Horacio MiguelATOMSMOLECULESTRANSITIONhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Weaddress a molecular dissociation mechanism that is known to occur when aH2 molecule approaches a catalyst with its molecular axis parallel to the surface. It is found that molecular dissociation is a form of quantum dynamical phase transition associated to an analytic discontinuity of quite unusual nature: the molecule is destabilized by the transition from non-physical virtual states into actual localized states. Current description complements our recent results for a molecule approaching the catalyst with its molecular axis perpendicular to the surface (Ruderman et al 2015 J. Phys.: Condens. Matter 27 315501). Also, such a description can be seen as a further successful implementation of a non-Hermitian Hamiltonian in a well defined model.Fil: Ruderman, Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Dente, Axel Damián. Invap S. E.; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Santos, Elizabeth del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Pastawski, Horacio Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaIOP Publishing2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/186038Ruderman, Andres; Dente, Axel Damián; Santos, Elizabeth del Carmen; Pastawski, Horacio Miguel; Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states; IOP Publishing; Materials Research Express; 3; 8; 8-2016; 1-102053-1591CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1088/2053-1591/3/8/085017info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-26T08:37:45Zoai:ri.conicet.gov.ar:11336/186038instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-26 08:37:46.237CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
title Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
spellingShingle Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
Ruderman, Andres
ATOMS
MOLECULES
TRANSITION
title_short Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
title_full Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
title_fullStr Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
title_full_unstemmed Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
title_sort Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states
dc.creator.none.fl_str_mv Ruderman, Andres
Dente, Axel Damián
Santos, Elizabeth del Carmen
Pastawski, Horacio Miguel
author Ruderman, Andres
author_facet Ruderman, Andres
Dente, Axel Damián
Santos, Elizabeth del Carmen
Pastawski, Horacio Miguel
author_role author
author2 Dente, Axel Damián
Santos, Elizabeth del Carmen
Pastawski, Horacio Miguel
author2_role author
author
author
dc.subject.none.fl_str_mv ATOMS
MOLECULES
TRANSITION
topic ATOMS
MOLECULES
TRANSITION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Weaddress a molecular dissociation mechanism that is known to occur when aH2 molecule approaches a catalyst with its molecular axis parallel to the surface. It is found that molecular dissociation is a form of quantum dynamical phase transition associated to an analytic discontinuity of quite unusual nature: the molecule is destabilized by the transition from non-physical virtual states into actual localized states. Current description complements our recent results for a molecule approaching the catalyst with its molecular axis perpendicular to the surface (Ruderman et al 2015 J. Phys.: Condens. Matter 27 315501). Also, such a description can be seen as a further successful implementation of a non-Hermitian Hamiltonian in a well defined model.
Fil: Ruderman, Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Dente, Axel Damián. Invap S. E.; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Santos, Elizabeth del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Pastawski, Horacio Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
description Weaddress a molecular dissociation mechanism that is known to occur when aH2 molecule approaches a catalyst with its molecular axis parallel to the surface. It is found that molecular dissociation is a form of quantum dynamical phase transition associated to an analytic discontinuity of quite unusual nature: the molecule is destabilized by the transition from non-physical virtual states into actual localized states. Current description complements our recent results for a molecule approaching the catalyst with its molecular axis perpendicular to the surface (Ruderman et al 2015 J. Phys.: Condens. Matter 27 315501). Also, such a description can be seen as a further successful implementation of a non-Hermitian Hamiltonian in a well defined model.
publishDate 2016
dc.date.none.fl_str_mv 2016-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/186038
Ruderman, Andres; Dente, Axel Damián; Santos, Elizabeth del Carmen; Pastawski, Horacio Miguel; Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states; IOP Publishing; Materials Research Express; 3; 8; 8-2016; 1-10
2053-1591
CONICET Digital
CONICET
url http://hdl.handle.net/11336/186038
identifier_str_mv Ruderman, Andres; Dente, Axel Damián; Santos, Elizabeth del Carmen; Pastawski, Horacio Miguel; Molecular dissociation in presence of a catalyst: II. The bond breaking role of the transition from virtual to localized states; IOP Publishing; Materials Research Express; 3; 8; 8-2016; 1-10
2053-1591
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1088/2053-1591/3/8/085017
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv IOP Publishing
publisher.none.fl_str_mv IOP Publishing
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.011256

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