Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity

Autores
Baldessari, Alicia; Mangone, Constanza P.
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alkyl carboxylates showed a remarkable regioselective behavior; only monoacyl derivatives were obtained. The surfactant activity, composition and clean enzymatic methodology applied in the preparation of these products make them useful as ingredients in cosmetic and pharmaceutical formulations or food additives.
Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Mangone, Constanza P.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Materia
ENZYME-CATALYZED
FATTY ACIDS
PYRIDOXINE
SURFACTANTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/84704
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activityBaldessari, AliciaMangone, Constanza P.ENZYME-CATALYZEDFATTY ACIDSPYRIDOXINESURFACTANTShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alkyl carboxylates showed a remarkable regioselective behavior; only monoacyl derivatives were obtained. The surfactant activity, composition and clean enzymatic methodology applied in the preparation of these products make them useful as ingredients in cosmetic and pharmaceutical formulations or food additives.Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaFil: Mangone, Constanza P.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaTaylor & Francis Ltd2002-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/84704Baldessari, Alicia; Mangone, Constanza P.; Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity; Taylor & Francis Ltd; Biocatalysis and Biotransformation; 20; 4; 12-2002; 275-2791024-2422CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/10242420290004910info:eu-repo/semantics/altIdentifier/doi/10.1080/10242420290004910info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:18Zoai:ri.conicet.gov.ar:11336/84704instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:18.591CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
title Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
spellingShingle Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
Baldessari, Alicia
ENZYME-CATALYZED
FATTY ACIDS
PYRIDOXINE
SURFACTANTS
title_short Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
title_full Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
title_fullStr Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
title_full_unstemmed Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
title_sort Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
dc.creator.none.fl_str_mv Baldessari, Alicia
Mangone, Constanza P.
author Baldessari, Alicia
author_facet Baldessari, Alicia
Mangone, Constanza P.
author_role author
author2 Mangone, Constanza P.
author2_role author
dc.subject.none.fl_str_mv ENZYME-CATALYZED
FATTY ACIDS
PYRIDOXINE
SURFACTANTS
topic ENZYME-CATALYZED
FATTY ACIDS
PYRIDOXINE
SURFACTANTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alkyl carboxylates showed a remarkable regioselective behavior; only monoacyl derivatives were obtained. The surfactant activity, composition and clean enzymatic methodology applied in the preparation of these products make them useful as ingredients in cosmetic and pharmaceutical formulations or food additives.
Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Mangone, Constanza P.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
description A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alkyl carboxylates showed a remarkable regioselective behavior; only monoacyl derivatives were obtained. The surfactant activity, composition and clean enzymatic methodology applied in the preparation of these products make them useful as ingredients in cosmetic and pharmaceutical formulations or food additives.
publishDate 2002
dc.date.none.fl_str_mv 2002-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/84704
Baldessari, Alicia; Mangone, Constanza P.; Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity; Taylor & Francis Ltd; Biocatalysis and Biotransformation; 20; 4; 12-2002; 275-279
1024-2422
CONICET Digital
CONICET
url http://hdl.handle.net/11336/84704
identifier_str_mv Baldessari, Alicia; Mangone, Constanza P.; Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity; Taylor & Francis Ltd; Biocatalysis and Biotransformation; 20; 4; 12-2002; 275-279
1024-2422
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/10242420290004910
info:eu-repo/semantics/altIdentifier/doi/10.1080/10242420290004910
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613446661832704
score 13.070432

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