Supramolecular chemistry in solid state materials such as metal-organic frameworks
- Autores
- Fracaroli, Alejandro Matías; Hoyos, Maria Rita Micaela
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Supramolecular chemistry has enriched the scientific research for more than fifty years reaching one of its summits in 2016, when the Chemistry Nobel Prize was awarded for the design and synthesis of molecular machines, in which host-guest chemistry plays a fundamental role. Recently, the groups of Omar Yaghi and Fraser Stoddart, among others, have demonstrated that this chemistry can be extended to the pores of metal-organic frameworks (MOFs). This heterogenization of supramolecular chemistry can be achieved through the incorporation of macrocycles to the organic struts of these highly porous and crystalline materials. Throughout this short review we summarize interesting examples of selective recognition by naturally occurring and synthetic macrocycles in solution and solid state; and later we survey important milestones to achieve specific recognition sites and develop host-guest chemistry at the pores of MOFs.This summary contains examples of different synthetic strategies to incorporate macrocycles to solid state materials, and in particular, to prepare supramolecular MOFs with particular properties and related applications. Specifically, the revised research includes the incorporation of both naturally occurring and synthetic macrocycles to solid state materials such as polymers, metal nanoparticles, etc., as prelude of the solid phase recognition studied in MOFs. An important number of the contributions presented here feature porous solids with smooth access to the host´s cavity incorporated in the pores, allowing specific recognition of guest molecules. This smooth access to those active recognition sites in materials with extremely high surface area such as MOFs, open the possibility to develop the next generation of frontier materials with application in fields such as selective capture of water toxins and heterogeneous catalysis, among others.
Fil: Fracaroli, Alejandro Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
MACROCYCLES
METAL-ORGANIC FRAMEWORKS (MOFS)
SOLID PHASE RECOGNITION PROCESS
SUPRAMOLECULAR CHEMISTRY - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/85433
Ver los metadatos del registro completo
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Supramolecular chemistry in solid state materials such as metal-organic frameworksFracaroli, Alejandro MatíasHoyos, Maria Rita MicaelaMACROCYCLESMETAL-ORGANIC FRAMEWORKS (MOFS)SOLID PHASE RECOGNITION PROCESSSUPRAMOLECULAR CHEMISTRYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Supramolecular chemistry has enriched the scientific research for more than fifty years reaching one of its summits in 2016, when the Chemistry Nobel Prize was awarded for the design and synthesis of molecular machines, in which host-guest chemistry plays a fundamental role. Recently, the groups of Omar Yaghi and Fraser Stoddart, among others, have demonstrated that this chemistry can be extended to the pores of metal-organic frameworks (MOFs). This heterogenization of supramolecular chemistry can be achieved through the incorporation of macrocycles to the organic struts of these highly porous and crystalline materials. Throughout this short review we summarize interesting examples of selective recognition by naturally occurring and synthetic macrocycles in solution and solid state; and later we survey important milestones to achieve specific recognition sites and develop host-guest chemistry at the pores of MOFs.This summary contains examples of different synthetic strategies to incorporate macrocycles to solid state materials, and in particular, to prepare supramolecular MOFs with particular properties and related applications. Specifically, the revised research includes the incorporation of both naturally occurring and synthetic macrocycles to solid state materials such as polymers, metal nanoparticles, etc., as prelude of the solid phase recognition studied in MOFs. An important number of the contributions presented here feature porous solids with smooth access to the host´s cavity incorporated in the pores, allowing specific recognition of guest molecules. This smooth access to those active recognition sites in materials with extremely high surface area such as MOFs, open the possibility to develop the next generation of frontier materials with application in fields such as selective capture of water toxins and heterogeneous catalysis, among others.Fil: Fracaroli, Alejandro Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaScience From Israel-division Of Laser Pages Publ Ltd2018-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/85433Fracaroli, Alejandro Matías; Hoyos, Maria Rita Micaela; Supramolecular chemistry in solid state materials such as metal-organic frameworks; Science From Israel-division Of Laser Pages Publ Ltd; Israel Journal Of Chemistry; 58; 9; 10-2018; 1102-11110021-21481869-5868CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/ijch.201800114info:eu-repo/semantics/altIdentifier/doi/10.1002/ijch.201800114info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:05:45Zoai:ri.conicet.gov.ar:11336/85433instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:05:45.706CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
title |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
spellingShingle |
Supramolecular chemistry in solid state materials such as metal-organic frameworks Fracaroli, Alejandro Matías MACROCYCLES METAL-ORGANIC FRAMEWORKS (MOFS) SOLID PHASE RECOGNITION PROCESS SUPRAMOLECULAR CHEMISTRY |
title_short |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
title_full |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
title_fullStr |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
title_full_unstemmed |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
title_sort |
Supramolecular chemistry in solid state materials such as metal-organic frameworks |
dc.creator.none.fl_str_mv |
Fracaroli, Alejandro Matías Hoyos, Maria Rita Micaela |
author |
Fracaroli, Alejandro Matías |
author_facet |
Fracaroli, Alejandro Matías Hoyos, Maria Rita Micaela |
author_role |
author |
author2 |
Hoyos, Maria Rita Micaela |
author2_role |
author |
dc.subject.none.fl_str_mv |
MACROCYCLES METAL-ORGANIC FRAMEWORKS (MOFS) SOLID PHASE RECOGNITION PROCESS SUPRAMOLECULAR CHEMISTRY |
topic |
MACROCYCLES METAL-ORGANIC FRAMEWORKS (MOFS) SOLID PHASE RECOGNITION PROCESS SUPRAMOLECULAR CHEMISTRY |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Supramolecular chemistry has enriched the scientific research for more than fifty years reaching one of its summits in 2016, when the Chemistry Nobel Prize was awarded for the design and synthesis of molecular machines, in which host-guest chemistry plays a fundamental role. Recently, the groups of Omar Yaghi and Fraser Stoddart, among others, have demonstrated that this chemistry can be extended to the pores of metal-organic frameworks (MOFs). This heterogenization of supramolecular chemistry can be achieved through the incorporation of macrocycles to the organic struts of these highly porous and crystalline materials. Throughout this short review we summarize interesting examples of selective recognition by naturally occurring and synthetic macrocycles in solution and solid state; and later we survey important milestones to achieve specific recognition sites and develop host-guest chemistry at the pores of MOFs.This summary contains examples of different synthetic strategies to incorporate macrocycles to solid state materials, and in particular, to prepare supramolecular MOFs with particular properties and related applications. Specifically, the revised research includes the incorporation of both naturally occurring and synthetic macrocycles to solid state materials such as polymers, metal nanoparticles, etc., as prelude of the solid phase recognition studied in MOFs. An important number of the contributions presented here feature porous solids with smooth access to the host´s cavity incorporated in the pores, allowing specific recognition of guest molecules. This smooth access to those active recognition sites in materials with extremely high surface area such as MOFs, open the possibility to develop the next generation of frontier materials with application in fields such as selective capture of water toxins and heterogeneous catalysis, among others. Fil: Fracaroli, Alejandro Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
Supramolecular chemistry has enriched the scientific research for more than fifty years reaching one of its summits in 2016, when the Chemistry Nobel Prize was awarded for the design and synthesis of molecular machines, in which host-guest chemistry plays a fundamental role. Recently, the groups of Omar Yaghi and Fraser Stoddart, among others, have demonstrated that this chemistry can be extended to the pores of metal-organic frameworks (MOFs). This heterogenization of supramolecular chemistry can be achieved through the incorporation of macrocycles to the organic struts of these highly porous and crystalline materials. Throughout this short review we summarize interesting examples of selective recognition by naturally occurring and synthetic macrocycles in solution and solid state; and later we survey important milestones to achieve specific recognition sites and develop host-guest chemistry at the pores of MOFs.This summary contains examples of different synthetic strategies to incorporate macrocycles to solid state materials, and in particular, to prepare supramolecular MOFs with particular properties and related applications. Specifically, the revised research includes the incorporation of both naturally occurring and synthetic macrocycles to solid state materials such as polymers, metal nanoparticles, etc., as prelude of the solid phase recognition studied in MOFs. An important number of the contributions presented here feature porous solids with smooth access to the host´s cavity incorporated in the pores, allowing specific recognition of guest molecules. This smooth access to those active recognition sites in materials with extremely high surface area such as MOFs, open the possibility to develop the next generation of frontier materials with application in fields such as selective capture of water toxins and heterogeneous catalysis, among others. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/85433 Fracaroli, Alejandro Matías; Hoyos, Maria Rita Micaela; Supramolecular chemistry in solid state materials such as metal-organic frameworks; Science From Israel-division Of Laser Pages Publ Ltd; Israel Journal Of Chemistry; 58; 9; 10-2018; 1102-1111 0021-2148 1869-5868 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/85433 |
identifier_str_mv |
Fracaroli, Alejandro Matías; Hoyos, Maria Rita Micaela; Supramolecular chemistry in solid state materials such as metal-organic frameworks; Science From Israel-division Of Laser Pages Publ Ltd; Israel Journal Of Chemistry; 58; 9; 10-2018; 1102-1111 0021-2148 1869-5868 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/ijch.201800114 info:eu-repo/semantics/altIdentifier/doi/10.1002/ijch.201800114 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Science From Israel-division Of Laser Pages Publ Ltd |
publisher.none.fl_str_mv |
Science From Israel-division Of Laser Pages Publ Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.13397 |