Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline...

Autores
Barranco García, Rosa; García Peñas, Alberto; Blázquez Blázquez, Enrique; Ressia, Jorge Aníbal; Quinzani, Lidia Maria; Valles, Enrique Marcelo; Gómez Elvira, José M.; Pérez, Ernesto; Cerrada, María L.
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, nanocomposites based on polypropylene are synthesized by the in situ polymerization of propene in the presence of mesoporous SBA-15 silica, which acts as a carrier of the catalytic system (zirconocene as catalyst and methylaluminoxane as cocatalyst). The protocol for the immobilization and attainment of hybrid SBA-15 particles involves a pre-stage of contact between the catalyst with cocatalyst before their final functionalization. Two zirconocene catalysts are tested in order to attain materials with different microstructural characteristics, molar masses and regioregularities of chains. Some polypropylene chains are able to be accommodated within the silica mesostructure of these composites. Thus, an endothermic event of small intensity appears during heating calorimetric experiments at approximately 105 °C. The existence of these polypropylene crystals, confined within the nanometric channels of silica, is corroborated by SAXS measurements obtained via the change in the intensity and position of the first-order diffraction of SBA-15. The incorporation of silica also has a very significant effect on the rheological response of the resultant materials, leading to important variations in various magnitudes, such as the shear storage modulus, viscosity and δ angle, when a comparison is established with the corresponding neat iPP matrices. Rheological percolation is reached, thus demonstrating the role of SBA-15 particles as filler, in addition to the supporting role that they exert during the polymerizations.
Fil: Barranco García, Rosa. Instituto en Ciencia y Tecnología de Polímeros; España. Universidad Complutense de Madrid; España
Fil: García Peñas, Alberto. Universidad Carlos III de Madrid. Instituto de Salud; España
Fil: Blázquez Blázquez, Enrique. Instituto en Ciencia y Tecnología de Polímeros; España
Fil: Ressia, Jorge Aníbal. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Quinzani, Lidia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Gómez Elvira, José M.. Instituto en Ciencia y Tecnología de Polímeros; España
Fil: Pérez, Ernesto. Instituto en Ciencia y Tecnología de Polímeros; España
Fil: Cerrada, María L.. Instituto en Ciencia y Tecnología de Polímeros; España
Materia
CONFINEMENT
CRYSTALLITES
HYBRID PARTICLES
IN SITU POLYMERIZATION
METALLOCENE CATALYSTS
NANOCOMPOSITES
POLYPROPYLENE
RHEOLOGICAL PERCOLATION
SBA-15 SILICA
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/234232
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological BehaviorBarranco García, RosaGarcía Peñas, AlbertoBlázquez Blázquez, EnriqueRessia, Jorge AníbalQuinzani, Lidia MariaValles, Enrique MarceloGómez Elvira, José M.Pérez, ErnestoCerrada, María L.CONFINEMENTCRYSTALLITESHYBRID PARTICLESIN SITU POLYMERIZATIONMETALLOCENE CATALYSTSNANOCOMPOSITESPOLYPROPYLENERHEOLOGICAL PERCOLATIONSBA-15 SILICAhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this study, nanocomposites based on polypropylene are synthesized by the in situ polymerization of propene in the presence of mesoporous SBA-15 silica, which acts as a carrier of the catalytic system (zirconocene as catalyst and methylaluminoxane as cocatalyst). The protocol for the immobilization and attainment of hybrid SBA-15 particles involves a pre-stage of contact between the catalyst with cocatalyst before their final functionalization. Two zirconocene catalysts are tested in order to attain materials with different microstructural characteristics, molar masses and regioregularities of chains. Some polypropylene chains are able to be accommodated within the silica mesostructure of these composites. Thus, an endothermic event of small intensity appears during heating calorimetric experiments at approximately 105 °C. The existence of these polypropylene crystals, confined within the nanometric channels of silica, is corroborated by SAXS measurements obtained via the change in the intensity and position of the first-order diffraction of SBA-15. The incorporation of silica also has a very significant effect on the rheological response of the resultant materials, leading to important variations in various magnitudes, such as the shear storage modulus, viscosity and δ angle, when a comparison is established with the corresponding neat iPP matrices. Rheological percolation is reached, thus demonstrating the role of SBA-15 particles as filler, in addition to the supporting role that they exert during the polymerizations.Fil: Barranco García, Rosa. Instituto en Ciencia y Tecnología de Polímeros; España. Universidad Complutense de Madrid; EspañaFil: García Peñas, Alberto. Universidad Carlos III de Madrid. Instituto de Salud; EspañaFil: Blázquez Blázquez, Enrique. Instituto en Ciencia y Tecnología de Polímeros; EspañaFil: Ressia, Jorge Aníbal. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; ArgentinaFil: Quinzani, Lidia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Gómez Elvira, José M.. Instituto en Ciencia y Tecnología de Polímeros; EspañaFil: Pérez, Ernesto. Instituto en Ciencia y Tecnología de Polímeros; EspañaFil: Cerrada, María L.. Instituto en Ciencia y Tecnología de Polímeros; EspañaMolecular Diversity Preservation International2023-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfhttp://hdl.handle.net/11336/234232Barranco García, Rosa; García Peñas, Alberto; Blázquez Blázquez, Enrique; Ressia, Jorge Aníbal; Quinzani, Lidia Maria; et al.; Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior; Molecular Diversity Preservation International; Molecules; 28; 11; 6-2023; 1-261420-3049CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1420-3049/28/11/4261info:eu-repo/semantics/altIdentifier/doi/10.3390/molecules28114261info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:51:00Zoai:ri.conicet.gov.ar:11336/234232instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:51:01.17CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
title Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
spellingShingle Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
Barranco García, Rosa
CONFINEMENT
CRYSTALLITES
HYBRID PARTICLES
IN SITU POLYMERIZATION
METALLOCENE CATALYSTS
NANOCOMPOSITES
POLYPROPYLENE
RHEOLOGICAL PERCOLATION
SBA-15 SILICA
title_short Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
title_full Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
title_fullStr Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
title_full_unstemmed Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
title_sort Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior
dc.creator.none.fl_str_mv Barranco García, Rosa
García Peñas, Alberto
Blázquez Blázquez, Enrique
Ressia, Jorge Aníbal
Quinzani, Lidia Maria
Valles, Enrique Marcelo
Gómez Elvira, José M.
Pérez, Ernesto
Cerrada, María L.
author Barranco García, Rosa
author_facet Barranco García, Rosa
García Peñas, Alberto
Blázquez Blázquez, Enrique
Ressia, Jorge Aníbal
Quinzani, Lidia Maria
Valles, Enrique Marcelo
Gómez Elvira, José M.
Pérez, Ernesto
Cerrada, María L.
author_role author
author2 García Peñas, Alberto
Blázquez Blázquez, Enrique
Ressia, Jorge Aníbal
Quinzani, Lidia Maria
Valles, Enrique Marcelo
Gómez Elvira, José M.
Pérez, Ernesto
Cerrada, María L.
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv CONFINEMENT
CRYSTALLITES
HYBRID PARTICLES
IN SITU POLYMERIZATION
METALLOCENE CATALYSTS
NANOCOMPOSITES
POLYPROPYLENE
RHEOLOGICAL PERCOLATION
SBA-15 SILICA
topic CONFINEMENT
CRYSTALLITES
HYBRID PARTICLES
IN SITU POLYMERIZATION
METALLOCENE CATALYSTS
NANOCOMPOSITES
POLYPROPYLENE
RHEOLOGICAL PERCOLATION
SBA-15 SILICA
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this study, nanocomposites based on polypropylene are synthesized by the in situ polymerization of propene in the presence of mesoporous SBA-15 silica, which acts as a carrier of the catalytic system (zirconocene as catalyst and methylaluminoxane as cocatalyst). The protocol for the immobilization and attainment of hybrid SBA-15 particles involves a pre-stage of contact between the catalyst with cocatalyst before their final functionalization. Two zirconocene catalysts are tested in order to attain materials with different microstructural characteristics, molar masses and regioregularities of chains. Some polypropylene chains are able to be accommodated within the silica mesostructure of these composites. Thus, an endothermic event of small intensity appears during heating calorimetric experiments at approximately 105 °C. The existence of these polypropylene crystals, confined within the nanometric channels of silica, is corroborated by SAXS measurements obtained via the change in the intensity and position of the first-order diffraction of SBA-15. The incorporation of silica also has a very significant effect on the rheological response of the resultant materials, leading to important variations in various magnitudes, such as the shear storage modulus, viscosity and δ angle, when a comparison is established with the corresponding neat iPP matrices. Rheological percolation is reached, thus demonstrating the role of SBA-15 particles as filler, in addition to the supporting role that they exert during the polymerizations.
Fil: Barranco García, Rosa. Instituto en Ciencia y Tecnología de Polímeros; España. Universidad Complutense de Madrid; España
Fil: García Peñas, Alberto. Universidad Carlos III de Madrid. Instituto de Salud; España
Fil: Blázquez Blázquez, Enrique. Instituto en Ciencia y Tecnología de Polímeros; España
Fil: Ressia, Jorge Aníbal. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Quinzani, Lidia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Gómez Elvira, José M.. Instituto en Ciencia y Tecnología de Polímeros; España
Fil: Pérez, Ernesto. Instituto en Ciencia y Tecnología de Polímeros; España
Fil: Cerrada, María L.. Instituto en Ciencia y Tecnología de Polímeros; España
description In this study, nanocomposites based on polypropylene are synthesized by the in situ polymerization of propene in the presence of mesoporous SBA-15 silica, which acts as a carrier of the catalytic system (zirconocene as catalyst and methylaluminoxane as cocatalyst). The protocol for the immobilization and attainment of hybrid SBA-15 particles involves a pre-stage of contact between the catalyst with cocatalyst before their final functionalization. Two zirconocene catalysts are tested in order to attain materials with different microstructural characteristics, molar masses and regioregularities of chains. Some polypropylene chains are able to be accommodated within the silica mesostructure of these composites. Thus, an endothermic event of small intensity appears during heating calorimetric experiments at approximately 105 °C. The existence of these polypropylene crystals, confined within the nanometric channels of silica, is corroborated by SAXS measurements obtained via the change in the intensity and position of the first-order diffraction of SBA-15. The incorporation of silica also has a very significant effect on the rheological response of the resultant materials, leading to important variations in various magnitudes, such as the shear storage modulus, viscosity and δ angle, when a comparison is established with the corresponding neat iPP matrices. Rheological percolation is reached, thus demonstrating the role of SBA-15 particles as filler, in addition to the supporting role that they exert during the polymerizations.
publishDate 2023
dc.date.none.fl_str_mv 2023-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/234232
Barranco García, Rosa; García Peñas, Alberto; Blázquez Blázquez, Enrique; Ressia, Jorge Aníbal; Quinzani, Lidia Maria; et al.; Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior; Molecular Diversity Preservation International; Molecules; 28; 11; 6-2023; 1-26
1420-3049
CONICET Digital
CONICET
url http://hdl.handle.net/11336/234232
identifier_str_mv Barranco García, Rosa; García Peñas, Alberto; Blázquez Blázquez, Enrique; Ressia, Jorge Aníbal; Quinzani, Lidia Maria; et al.; Polypropylene Nanocomposites Attained by In Situ Polymerization Using SBA-15 Particles as Support for Metallocene Catalysts: Effect of Molecular Weight and Tacticity on Crystalline Details, Phase Transitions and Rheological Behavior; Molecular Diversity Preservation International; Molecules; 28; 11; 6-2023; 1-26
1420-3049
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1420-3049/28/11/4261
info:eu-repo/semantics/altIdentifier/doi/10.3390/molecules28114261
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
dc.publisher.none.fl_str_mv Molecular Diversity Preservation International
publisher.none.fl_str_mv Molecular Diversity Preservation International
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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