Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine

Autores
Barbosa, Silvia Elena; Castillo, Luciana Andrea
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A detailed petrographical, mineralogical, morphological, geochemical and physicochemical characterization of talc from an Argentinean ore is presented. This deposit is located in the San Juan province at the foothills of the Andes. Characterization was performed on rock and milled talc using different techniques including polarized light microscopy, transmission electron and scanning microscopy with energy dispersive spectroscopy (SEM/EDX), chemical analyses, X-ray diffraction (XRD), X-ray fluorescence, Fourier transform infrared spectroscopy (FTIR), particle size determination by laser diffraction, thermogravimetry analysis, and colorimetry. A mineral sample contains approximately 80 wt% talc. Associated minerals such as carbonates as veins and chlorite interlaminated with talc were detected. Carbonates are calcite, dolomite and magnesite, as was corroborated by FTIR. Morphology and crystallinity were assessed by XRD data, obtaining a morphological index of 0.79 which indicates the macrocrystalline character. Crystalline habits of associated minerals were recognized by SEM, detecting their constitutive elements by EDX. Talc color parameters are L* = 82.76, a* = −1.50, and b* = 5.38. The slight yellowing could be attributed to chlorite or traces of Fe oxides. Although the whiteness index (62.12) impedes its commercialization as a high-priced mineral, this kind of talc can be used as an additive for polymers, since it would offer a high reinforcing effect (improvement of mechanical properties).
Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Castillo, Luciana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Talc
Macrocrystalline morphology
Argentinean ore
Carbonates
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/223823
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Morphological and Physicochemical Properties of Macrocrystalline Talc from ArgentineBarbosa, Silvia ElenaCastillo, Luciana AndreaTalcMacrocrystalline morphologyArgentinean oreCarbonateshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A detailed petrographical, mineralogical, morphological, geochemical and physicochemical characterization of talc from an Argentinean ore is presented. This deposit is located in the San Juan province at the foothills of the Andes. Characterization was performed on rock and milled talc using different techniques including polarized light microscopy, transmission electron and scanning microscopy with energy dispersive spectroscopy (SEM/EDX), chemical analyses, X-ray diffraction (XRD), X-ray fluorescence, Fourier transform infrared spectroscopy (FTIR), particle size determination by laser diffraction, thermogravimetry analysis, and colorimetry. A mineral sample contains approximately 80 wt% talc. Associated minerals such as carbonates as veins and chlorite interlaminated with talc were detected. Carbonates are calcite, dolomite and magnesite, as was corroborated by FTIR. Morphology and crystallinity were assessed by XRD data, obtaining a morphological index of 0.79 which indicates the macrocrystalline character. Crystalline habits of associated minerals were recognized by SEM, detecting their constitutive elements by EDX. Talc color parameters are L* = 82.76, a* = −1.50, and b* = 5.38. The slight yellowing could be attributed to chlorite or traces of Fe oxides. Although the whiteness index (62.12) impedes its commercialization as a high-priced mineral, this kind of talc can be used as an additive for polymers, since it would offer a high reinforcing effect (improvement of mechanical properties).Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Castillo, Luciana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaMultidisciplinary Digital Publishing Institute2023-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/223823Barbosa, Silvia Elena; Castillo, Luciana Andrea; Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine; Multidisciplinary Digital Publishing Institute; Minerals; 13; 5; 5-2023; 683-7022075-163XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2075-163X/13/5/683info:eu-repo/semantics/altIdentifier/doi/10.3390/min13050683info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:03Zoai:ri.conicet.gov.ar:11336/223823instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:03.605CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
title Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
spellingShingle Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
Barbosa, Silvia Elena
Talc
Macrocrystalline morphology
Argentinean ore
Carbonates
title_short Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
title_full Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
title_fullStr Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
title_full_unstemmed Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
title_sort Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine
dc.creator.none.fl_str_mv Barbosa, Silvia Elena
Castillo, Luciana Andrea
author Barbosa, Silvia Elena
author_facet Barbosa, Silvia Elena
Castillo, Luciana Andrea
author_role author
author2 Castillo, Luciana Andrea
author2_role author
dc.subject.none.fl_str_mv Talc
Macrocrystalline morphology
Argentinean ore
Carbonates
topic Talc
Macrocrystalline morphology
Argentinean ore
Carbonates
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A detailed petrographical, mineralogical, morphological, geochemical and physicochemical characterization of talc from an Argentinean ore is presented. This deposit is located in the San Juan province at the foothills of the Andes. Characterization was performed on rock and milled talc using different techniques including polarized light microscopy, transmission electron and scanning microscopy with energy dispersive spectroscopy (SEM/EDX), chemical analyses, X-ray diffraction (XRD), X-ray fluorescence, Fourier transform infrared spectroscopy (FTIR), particle size determination by laser diffraction, thermogravimetry analysis, and colorimetry. A mineral sample contains approximately 80 wt% talc. Associated minerals such as carbonates as veins and chlorite interlaminated with talc were detected. Carbonates are calcite, dolomite and magnesite, as was corroborated by FTIR. Morphology and crystallinity were assessed by XRD data, obtaining a morphological index of 0.79 which indicates the macrocrystalline character. Crystalline habits of associated minerals were recognized by SEM, detecting their constitutive elements by EDX. Talc color parameters are L* = 82.76, a* = −1.50, and b* = 5.38. The slight yellowing could be attributed to chlorite or traces of Fe oxides. Although the whiteness index (62.12) impedes its commercialization as a high-priced mineral, this kind of talc can be used as an additive for polymers, since it would offer a high reinforcing effect (improvement of mechanical properties).
Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Castillo, Luciana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description A detailed petrographical, mineralogical, morphological, geochemical and physicochemical characterization of talc from an Argentinean ore is presented. This deposit is located in the San Juan province at the foothills of the Andes. Characterization was performed on rock and milled talc using different techniques including polarized light microscopy, transmission electron and scanning microscopy with energy dispersive spectroscopy (SEM/EDX), chemical analyses, X-ray diffraction (XRD), X-ray fluorescence, Fourier transform infrared spectroscopy (FTIR), particle size determination by laser diffraction, thermogravimetry analysis, and colorimetry. A mineral sample contains approximately 80 wt% talc. Associated minerals such as carbonates as veins and chlorite interlaminated with talc were detected. Carbonates are calcite, dolomite and magnesite, as was corroborated by FTIR. Morphology and crystallinity were assessed by XRD data, obtaining a morphological index of 0.79 which indicates the macrocrystalline character. Crystalline habits of associated minerals were recognized by SEM, detecting their constitutive elements by EDX. Talc color parameters are L* = 82.76, a* = −1.50, and b* = 5.38. The slight yellowing could be attributed to chlorite or traces of Fe oxides. Although the whiteness index (62.12) impedes its commercialization as a high-priced mineral, this kind of talc can be used as an additive for polymers, since it would offer a high reinforcing effect (improvement of mechanical properties).
publishDate 2023
dc.date.none.fl_str_mv 2023-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/223823
Barbosa, Silvia Elena; Castillo, Luciana Andrea; Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine; Multidisciplinary Digital Publishing Institute; Minerals; 13; 5; 5-2023; 683-702
2075-163X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/223823
identifier_str_mv Barbosa, Silvia Elena; Castillo, Luciana Andrea; Morphological and Physicochemical Properties of Macrocrystalline Talc from Argentine; Multidisciplinary Digital Publishing Institute; Minerals; 13; 5; 5-2023; 683-702
2075-163X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2075-163X/13/5/683
info:eu-repo/semantics/altIdentifier/doi/10.3390/min13050683
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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