A possible use of a polymeric surfactant as petroleum pollution collector

Autores
Rodríguez, J. L.; Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Schulz, Pablo Carlos
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A polymeric amphiphile was synthesised by addition of phosphonate groups to asymmetric terminal double bonds of polybutadiene giving α, β-unsaturated phosphonic acids. The polymer was characterized by NMR and FT-IR. The synthesis produces a complex cream-like O/W emulsion containing simultaneously water and toluene. The oil droplets are interconnected by polymer chains avoiding the dispersion of the emulsion in water. When this emulsion is spread on a crude petroleum overflow on water, the oil stain shrink and is absorbed by the cream-like emulsion. The resulting product can be manipulated more easily than the original oil to extract it from the water surface.
Fil: Rodríguez, J. L.. Instituto Universitario Naval. Escuela de Oficiales de la Armada; Argentina
Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pieroni, Olga Inés. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Vuano, Bruno Mario. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Schulz, Pablo Carlos. Instituto Universitario Naval. Escuela de Oficiales de la Armada; Argentina
Materia
Poly(Butadiene)
Amphiphilic Polymer
Petroleum Collector
Characterization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/39413
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A possible use of a polymeric surfactant as petroleum pollution collectorRodríguez, J. L.Ciolino, Andrés EduardoPieroni, Olga InésVuano, Bruno MarioSchulz, Pablo CarlosPoly(Butadiene)Amphiphilic PolymerPetroleum CollectorCharacterizationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A polymeric amphiphile was synthesised by addition of phosphonate groups to asymmetric terminal double bonds of polybutadiene giving α, β-unsaturated phosphonic acids. The polymer was characterized by NMR and FT-IR. The synthesis produces a complex cream-like O/W emulsion containing simultaneously water and toluene. The oil droplets are interconnected by polymer chains avoiding the dispersion of the emulsion in water. When this emulsion is spread on a crude petroleum overflow on water, the oil stain shrink and is absorbed by the cream-like emulsion. The resulting product can be manipulated more easily than the original oil to extract it from the water surface.Fil: Rodríguez, J. L.. Instituto Universitario Naval. Escuela de Oficiales de la Armada; ArgentinaFil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pieroni, Olga Inés. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Vuano, Bruno Mario. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Schulz, Pablo Carlos. Instituto Universitario Naval. Escuela de Oficiales de la Armada; ArgentinaIndian Society for Surface Science and Technology2007-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/39413Rodríguez, J. L.; Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Schulz, Pablo Carlos; A possible use of a polymeric surfactant as petroleum pollution collector; Indian Society for Surface Science and Technology; Journal of Surface Science and Technology; 23; 3-4; 12-2007; 111-1300970-1893CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.informaticsjournals.com/index.php/jsst/article/view/1927info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:48:47Zoai:ri.conicet.gov.ar:11336/39413instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:48:47.726CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A possible use of a polymeric surfactant as petroleum pollution collector
title A possible use of a polymeric surfactant as petroleum pollution collector
spellingShingle A possible use of a polymeric surfactant as petroleum pollution collector
Rodríguez, J. L.
Poly(Butadiene)
Amphiphilic Polymer
Petroleum Collector
Characterization
title_short A possible use of a polymeric surfactant as petroleum pollution collector
title_full A possible use of a polymeric surfactant as petroleum pollution collector
title_fullStr A possible use of a polymeric surfactant as petroleum pollution collector
title_full_unstemmed A possible use of a polymeric surfactant as petroleum pollution collector
title_sort A possible use of a polymeric surfactant as petroleum pollution collector
dc.creator.none.fl_str_mv Rodríguez, J. L.
Ciolino, Andrés Eduardo
Pieroni, Olga Inés
Vuano, Bruno Mario
Schulz, Pablo Carlos
author Rodríguez, J. L.
author_facet Rodríguez, J. L.
Ciolino, Andrés Eduardo
Pieroni, Olga Inés
Vuano, Bruno Mario
Schulz, Pablo Carlos
author_role author
author2 Ciolino, Andrés Eduardo
Pieroni, Olga Inés
Vuano, Bruno Mario
Schulz, Pablo Carlos
author2_role author
author
author
author
dc.subject.none.fl_str_mv Poly(Butadiene)
Amphiphilic Polymer
Petroleum Collector
Characterization
topic Poly(Butadiene)
Amphiphilic Polymer
Petroleum Collector
Characterization
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A polymeric amphiphile was synthesised by addition of phosphonate groups to asymmetric terminal double bonds of polybutadiene giving α, β-unsaturated phosphonic acids. The polymer was characterized by NMR and FT-IR. The synthesis produces a complex cream-like O/W emulsion containing simultaneously water and toluene. The oil droplets are interconnected by polymer chains avoiding the dispersion of the emulsion in water. When this emulsion is spread on a crude petroleum overflow on water, the oil stain shrink and is absorbed by the cream-like emulsion. The resulting product can be manipulated more easily than the original oil to extract it from the water surface.
Fil: Rodríguez, J. L.. Instituto Universitario Naval. Escuela de Oficiales de la Armada; Argentina
Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pieroni, Olga Inés. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Vuano, Bruno Mario. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Schulz, Pablo Carlos. Instituto Universitario Naval. Escuela de Oficiales de la Armada; Argentina
description A polymeric amphiphile was synthesised by addition of phosphonate groups to asymmetric terminal double bonds of polybutadiene giving α, β-unsaturated phosphonic acids. The polymer was characterized by NMR and FT-IR. The synthesis produces a complex cream-like O/W emulsion containing simultaneously water and toluene. The oil droplets are interconnected by polymer chains avoiding the dispersion of the emulsion in water. When this emulsion is spread on a crude petroleum overflow on water, the oil stain shrink and is absorbed by the cream-like emulsion. The resulting product can be manipulated more easily than the original oil to extract it from the water surface.
publishDate 2007
dc.date.none.fl_str_mv 2007-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/39413
Rodríguez, J. L.; Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Schulz, Pablo Carlos; A possible use of a polymeric surfactant as petroleum pollution collector; Indian Society for Surface Science and Technology; Journal of Surface Science and Technology; 23; 3-4; 12-2007; 111-130
0970-1893
CONICET Digital
CONICET
url http://hdl.handle.net/11336/39413
identifier_str_mv Rodríguez, J. L.; Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Schulz, Pablo Carlos; A possible use of a polymeric surfactant as petroleum pollution collector; Indian Society for Surface Science and Technology; Journal of Surface Science and Technology; 23; 3-4; 12-2007; 111-130
0970-1893
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.informaticsjournals.com/index.php/jsst/article/view/1927
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Indian Society for Surface Science and Technology
publisher.none.fl_str_mv Indian Society for Surface Science and Technology
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083009303805952
score 13.22299

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