Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions

Autores
Serial, María Raquel; Velasco, Manuel Isaac; Silletta, Emilia Victoria; Zanotto, Franco Martín; Dassie, Sergio Alberto; Acosta, Rodolfo Héctor
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The fluid dynamics of a liquid|liquid system inside a four-electrode electrochemical cell were studied by velocimetry magnetic resonance imaging (MRI) and flow propagator measurements. To characterize this system fully, three different cell configurations operating at two rotational frequencies were analyzed. Quantitative information about the stability of the liquid|liquid interface and the dynamics of the organic phase were determined. The NMR spectroscopy results were in agreement with the electrochemical measurements performed by using the same experimental setup.
Fil: Serial, María Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Velasco, Manuel Isaac. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Silletta, Emilia Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Zanotto, Franco Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Acosta, Rodolfo Héctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Materia
CHARGE TRANSFER
ELECTROCHEMISTRY
FLOW PROPAGATORS
FORCED HYDRODYNAMIC CONDITIONS
INTERFACES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64722
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/64722
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditionsSerial, María RaquelVelasco, Manuel IsaacSilletta, Emilia VictoriaZanotto, Franco MartínDassie, Sergio AlbertoAcosta, Rodolfo HéctorCHARGE TRANSFERELECTROCHEMISTRYFLOW PROPAGATORSFORCED HYDRODYNAMIC CONDITIONSINTERFACEShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The fluid dynamics of a liquid|liquid system inside a four-electrode electrochemical cell were studied by velocimetry magnetic resonance imaging (MRI) and flow propagator measurements. To characterize this system fully, three different cell configurations operating at two rotational frequencies were analyzed. Quantitative information about the stability of the liquid|liquid interface and the dynamics of the organic phase were determined. The NMR spectroscopy results were in agreement with the electrochemical measurements performed by using the same experimental setup.Fil: Serial, María Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Velasco, Manuel Isaac. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Silletta, Emilia Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Zanotto, Franco Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Acosta, Rodolfo Héctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaWiley VCH Verlag2017-12-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64722Serial, María Raquel; Velasco, Manuel Isaac; Silletta, Emilia Victoria; Zanotto, Franco Martín; Dassie, Sergio Alberto; et al.; Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions; Wiley VCH Verlag; Chemphyschem; 18; 23; 27-12-2017; 3469-34771439-42351439-7641CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201700775info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pubmed/28960697info:eu-repo/semantics/altIdentifier/doi/10.1002/cphc.201700775info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:21:02Zoai:ri.conicet.gov.ar:11336/64722instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:21:02.768CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
title Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
spellingShingle Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
Serial, María Raquel
CHARGE TRANSFER
ELECTROCHEMISTRY
FLOW PROPAGATORS
FORCED HYDRODYNAMIC CONDITIONS
INTERFACES
title_short Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
title_full Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
title_fullStr Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
title_full_unstemmed Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
title_sort Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions
dc.creator.none.fl_str_mv Serial, María Raquel
Velasco, Manuel Isaac
Silletta, Emilia Victoria
Zanotto, Franco Martín
Dassie, Sergio Alberto
Acosta, Rodolfo Héctor
author Serial, María Raquel
author_facet Serial, María Raquel
Velasco, Manuel Isaac
Silletta, Emilia Victoria
Zanotto, Franco Martín
Dassie, Sergio Alberto
Acosta, Rodolfo Héctor
author_role author
author2 Velasco, Manuel Isaac
Silletta, Emilia Victoria
Zanotto, Franco Martín
Dassie, Sergio Alberto
Acosta, Rodolfo Héctor
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv CHARGE TRANSFER
ELECTROCHEMISTRY
FLOW PROPAGATORS
FORCED HYDRODYNAMIC CONDITIONS
INTERFACES
topic CHARGE TRANSFER
ELECTROCHEMISTRY
FLOW PROPAGATORS
FORCED HYDRODYNAMIC CONDITIONS
INTERFACES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The fluid dynamics of a liquid|liquid system inside a four-electrode electrochemical cell were studied by velocimetry magnetic resonance imaging (MRI) and flow propagator measurements. To characterize this system fully, three different cell configurations operating at two rotational frequencies were analyzed. Quantitative information about the stability of the liquid|liquid interface and the dynamics of the organic phase were determined. The NMR spectroscopy results were in agreement with the electrochemical measurements performed by using the same experimental setup.
Fil: Serial, María Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Velasco, Manuel Isaac. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Silletta, Emilia Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Zanotto, Franco Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Acosta, Rodolfo Héctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
description The fluid dynamics of a liquid|liquid system inside a four-electrode electrochemical cell were studied by velocimetry magnetic resonance imaging (MRI) and flow propagator measurements. To characterize this system fully, three different cell configurations operating at two rotational frequencies were analyzed. Quantitative information about the stability of the liquid|liquid interface and the dynamics of the organic phase were determined. The NMR spectroscopy results were in agreement with the electrochemical measurements performed by using the same experimental setup.
publishDate 2017
dc.date.none.fl_str_mv 2017-12-27
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64722
Serial, María Raquel; Velasco, Manuel Isaac; Silletta, Emilia Victoria; Zanotto, Franco Martín; Dassie, Sergio Alberto; et al.; Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions; Wiley VCH Verlag; Chemphyschem; 18; 23; 27-12-2017; 3469-3477
1439-4235
1439-7641
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64722
identifier_str_mv Serial, María Raquel; Velasco, Manuel Isaac; Silletta, Emilia Victoria; Zanotto, Franco Martín; Dassie, Sergio Alberto; et al.; Flow-Pattern characterization of biphasic electrochemical cells by magnetic resonance imaging under forced hydrodynamic conditions; Wiley VCH Verlag; Chemphyschem; 18; 23; 27-12-2017; 3469-3477
1439-4235
1439-7641
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201700775
info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pubmed/28960697
info:eu-repo/semantics/altIdentifier/doi/10.1002/cphc.201700775
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781708334006272
score 13.229304

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