Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming

Autores
Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Vera, Carlos Roman; Yori, Juan Carlos; Grau, Javier Mario
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of the Ge content on the properties of the metal and acid functions of trimetallic naphtha reforming catalysts of platinum-rhenium-germanium supported on chloride alumina was studied. Pt, Re and Ge were loaded using the coimpregnation method. The elemental concentration of the catalysts used was: Pt = Re = 0.3%; Ge = 0.1%, 0.3%, 0.6% and 0.9% (weight basis). In order to make a comparison Pt/Al2O3 and Pt-Re/Al2O3 catalysts were prepared. The properties of the acid and metal functions were studied by physicochemical techniques and using test reactions. Reforming of n-heptane (450 °C, 0.1 MPa, H2/nC7 = 4, WHSV = 7.3) was used to evaluate the catalytic properties of the samples. It was found that the addition of small quantities of Ge (0.1%) decreased both the hydrogenolytic and dehydrogenation activities by breaking Pt-Re ensembles and modifying the electronic density of Pt. The latter was revealed by the decrease in the CO chemisorption capacity and the shift of the bands of linearly adsorbed CO. With respect to the acid function Ge addition produced a change in the acid strength distribution, increasing the amount of mild and weak acid sites and decreasing the amount of strong ones. This modification of the metal/acid balance had an effect over the distribution of products of n-heptane reforming. Both the isomerization activity and the stability of the catalyst were enhanced while the cracking and dehydrocyclization activities were decreased. The isoparaffins/aromatics ratio and the octane gain were improved and as a result the reformate product better adjusted to environmental regulations.
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Grau, Javier Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Ge Charge Effect on Pt-Re
N-Heptane Reforming
Pt-Re-Ge
Trimetallic Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/57021
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/57021
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reformingMazzieri, Vanina AlejandraPieck, Carlos LuisVera, Carlos RomanYori, Juan CarlosGrau, Javier MarioGe Charge Effect on Pt-ReN-Heptane ReformingPt-Re-GeTrimetallic Catalystshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The effect of the Ge content on the properties of the metal and acid functions of trimetallic naphtha reforming catalysts of platinum-rhenium-germanium supported on chloride alumina was studied. Pt, Re and Ge were loaded using the coimpregnation method. The elemental concentration of the catalysts used was: Pt = Re = 0.3%; Ge = 0.1%, 0.3%, 0.6% and 0.9% (weight basis). In order to make a comparison Pt/Al2O3 and Pt-Re/Al2O3 catalysts were prepared. The properties of the acid and metal functions were studied by physicochemical techniques and using test reactions. Reforming of n-heptane (450 °C, 0.1 MPa, H2/nC7 = 4, WHSV = 7.3) was used to evaluate the catalytic properties of the samples. It was found that the addition of small quantities of Ge (0.1%) decreased both the hydrogenolytic and dehydrogenation activities by breaking Pt-Re ensembles and modifying the electronic density of Pt. The latter was revealed by the decrease in the CO chemisorption capacity and the shift of the bands of linearly adsorbed CO. With respect to the acid function Ge addition produced a change in the acid strength distribution, increasing the amount of mild and weak acid sites and decreasing the amount of strong ones. This modification of the metal/acid balance had an effect over the distribution of products of n-heptane reforming. Both the isomerization activity and the stability of the catalyst were enhanced while the cracking and dehydrocyclization activities were decreased. The isoparaffins/aromatics ratio and the octane gain were improved and as a result the reformate product better adjusted to environmental regulations.Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Grau, Javier Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2009-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57021Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Vera, Carlos Roman; Yori, Juan Carlos; Grau, Javier Mario; Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming; Elsevier Science; Applied Catalysis A: General; 353; 1; 1-2009; 93-1000926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2008.10.024info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0926860X08006686info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:50Zoai:ri.conicet.gov.ar:11336/57021instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:50.726CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
title Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
spellingShingle Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
Mazzieri, Vanina Alejandra
Ge Charge Effect on Pt-Re
N-Heptane Reforming
Pt-Re-Ge
Trimetallic Catalysts
title_short Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
title_full Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
title_fullStr Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
title_full_unstemmed Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
title_sort Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming
dc.creator.none.fl_str_mv Mazzieri, Vanina Alejandra
Pieck, Carlos Luis
Vera, Carlos Roman
Yori, Juan Carlos
Grau, Javier Mario
author Mazzieri, Vanina Alejandra
author_facet Mazzieri, Vanina Alejandra
Pieck, Carlos Luis
Vera, Carlos Roman
Yori, Juan Carlos
Grau, Javier Mario
author_role author
author2 Pieck, Carlos Luis
Vera, Carlos Roman
Yori, Juan Carlos
Grau, Javier Mario
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ge Charge Effect on Pt-Re
N-Heptane Reforming
Pt-Re-Ge
Trimetallic Catalysts
topic Ge Charge Effect on Pt-Re
N-Heptane Reforming
Pt-Re-Ge
Trimetallic Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The effect of the Ge content on the properties of the metal and acid functions of trimetallic naphtha reforming catalysts of platinum-rhenium-germanium supported on chloride alumina was studied. Pt, Re and Ge were loaded using the coimpregnation method. The elemental concentration of the catalysts used was: Pt = Re = 0.3%; Ge = 0.1%, 0.3%, 0.6% and 0.9% (weight basis). In order to make a comparison Pt/Al2O3 and Pt-Re/Al2O3 catalysts were prepared. The properties of the acid and metal functions were studied by physicochemical techniques and using test reactions. Reforming of n-heptane (450 °C, 0.1 MPa, H2/nC7 = 4, WHSV = 7.3) was used to evaluate the catalytic properties of the samples. It was found that the addition of small quantities of Ge (0.1%) decreased both the hydrogenolytic and dehydrogenation activities by breaking Pt-Re ensembles and modifying the electronic density of Pt. The latter was revealed by the decrease in the CO chemisorption capacity and the shift of the bands of linearly adsorbed CO. With respect to the acid function Ge addition produced a change in the acid strength distribution, increasing the amount of mild and weak acid sites and decreasing the amount of strong ones. This modification of the metal/acid balance had an effect over the distribution of products of n-heptane reforming. Both the isomerization activity and the stability of the catalyst were enhanced while the cracking and dehydrocyclization activities were decreased. The isoparaffins/aromatics ratio and the octane gain were improved and as a result the reformate product better adjusted to environmental regulations.
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Grau, Javier Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The effect of the Ge content on the properties of the metal and acid functions of trimetallic naphtha reforming catalysts of platinum-rhenium-germanium supported on chloride alumina was studied. Pt, Re and Ge were loaded using the coimpregnation method. The elemental concentration of the catalysts used was: Pt = Re = 0.3%; Ge = 0.1%, 0.3%, 0.6% and 0.9% (weight basis). In order to make a comparison Pt/Al2O3 and Pt-Re/Al2O3 catalysts were prepared. The properties of the acid and metal functions were studied by physicochemical techniques and using test reactions. Reforming of n-heptane (450 °C, 0.1 MPa, H2/nC7 = 4, WHSV = 7.3) was used to evaluate the catalytic properties of the samples. It was found that the addition of small quantities of Ge (0.1%) decreased both the hydrogenolytic and dehydrogenation activities by breaking Pt-Re ensembles and modifying the electronic density of Pt. The latter was revealed by the decrease in the CO chemisorption capacity and the shift of the bands of linearly adsorbed CO. With respect to the acid function Ge addition produced a change in the acid strength distribution, increasing the amount of mild and weak acid sites and decreasing the amount of strong ones. This modification of the metal/acid balance had an effect over the distribution of products of n-heptane reforming. Both the isomerization activity and the stability of the catalyst were enhanced while the cracking and dehydrocyclization activities were decreased. The isoparaffins/aromatics ratio and the octane gain were improved and as a result the reformate product better adjusted to environmental regulations.
publishDate 2009
dc.date.none.fl_str_mv 2009-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/57021
Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Vera, Carlos Roman; Yori, Juan Carlos; Grau, Javier Mario; Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming; Elsevier Science; Applied Catalysis A: General; 353; 1; 1-2009; 93-100
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/57021
identifier_str_mv Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Vera, Carlos Roman; Yori, Juan Carlos; Grau, Javier Mario; Effect of Ge content on the metal and acid properties of Pt-Re-Ge/Al2O3-Cl catalysts for naphtha reforming; Elsevier Science; Applied Catalysis A: General; 353; 1; 1-2009; 93-100
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2008.10.024
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0926860X08006686
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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