Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts

Autores
Bocanegra, Sonia Alejandra; Castro, Alberto Antonio; Scelza, Osvaldo Antonio; de Miguel, Sergio Ruben
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper deals with the characterization and catalytic dehydrogenation behavior of trimetallic InPtSn catalysts with different Sn content (from 0.12 wt% up to 1.08 wt%) supported on MgAl2O4. The support was initially impregnated with In, followed by a co-impregnation with Pt and Sn. The Pt and In contents in all catalysts were 0.30 wt% and 0.28 wt%, respectively. Besides, two catalysts with a Sn content of 0.37 wt% were prepared by two different methods: (a) successive impregnation (first Pt, second Sn) and (b) impregnation with PtSn complex, [(CH3)4N]2[PtCl2(SnCl3)2]. Experiments of n-butane dehydrogenation reaction were carried out both in continuous flow equipment and in pulse equipment. The catalysts were characterized by TPR, XPS and test reactions of the metallic phase. Trimetallic catalysts display high activity and selectivity to butenes and low deactivation during the n-butane dehydrogenation reaction. In order to analyze the influence of the preparation method on the catalytic performance, the better trimetallic catalyst was selected. It was observed that the different impregnation methods of Pt and Sn lead to trimetallic catalysts with similar catalytic behaviors between them. The characterization studies indicate the existence of geometric effects of In and Sn on Pt sites that produce a dilution of the Pt surface, and also a strong interaction between the three metals, which could lead to alloy formation. These facts positively influence the catalytic performance, thus increasing the activity, the selectivity to butenes and the stability of the metallic phase.
Fil: Bocanegra, Sonia Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Castro, Alberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Catalyst Characterization
Mgal2o4 Support
N-Butane Dehydrogenation
Trimetallic Ptsnin Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66121
Acceder
id CONICETDig_e7be43e5528f609e7dd58b31ec4d2cbb
oai_identifier_str oai:ri.conicet.gov.ar:11336/66121
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalystsBocanegra, Sonia AlejandraCastro, Alberto AntonioScelza, Osvaldo Antoniode Miguel, Sergio RubenCatalyst CharacterizationMgal2o4 SupportN-Butane DehydrogenationTrimetallic Ptsnin Catalystshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This paper deals with the characterization and catalytic dehydrogenation behavior of trimetallic InPtSn catalysts with different Sn content (from 0.12 wt% up to 1.08 wt%) supported on MgAl2O4. The support was initially impregnated with In, followed by a co-impregnation with Pt and Sn. The Pt and In contents in all catalysts were 0.30 wt% and 0.28 wt%, respectively. Besides, two catalysts with a Sn content of 0.37 wt% were prepared by two different methods: (a) successive impregnation (first Pt, second Sn) and (b) impregnation with PtSn complex, [(CH3)4N]2[PtCl2(SnCl3)2]. Experiments of n-butane dehydrogenation reaction were carried out both in continuous flow equipment and in pulse equipment. The catalysts were characterized by TPR, XPS and test reactions of the metallic phase. Trimetallic catalysts display high activity and selectivity to butenes and low deactivation during the n-butane dehydrogenation reaction. In order to analyze the influence of the preparation method on the catalytic performance, the better trimetallic catalyst was selected. It was observed that the different impregnation methods of Pt and Sn lead to trimetallic catalysts with similar catalytic behaviors between them. The characterization studies indicate the existence of geometric effects of In and Sn on Pt sites that produce a dilution of the Pt surface, and also a strong interaction between the three metals, which could lead to alloy formation. These facts positively influence the catalytic performance, thus increasing the activity, the selectivity to butenes and the stability of the metallic phase.Fil: Bocanegra, Sonia Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Castro, Alberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2007-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66121Bocanegra, Sonia Alejandra; Castro, Alberto Antonio; Scelza, Osvaldo Antonio; de Miguel, Sergio Ruben; Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts; Elsevier Science; Applied Catalysis A: General; 333; 1; 12-2007; 49-560926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2007.09.002info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:17:28Zoai:ri.conicet.gov.ar:11336/66121instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:17:29.184CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
title Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
spellingShingle Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
Bocanegra, Sonia Alejandra
Catalyst Characterization
Mgal2o4 Support
N-Butane Dehydrogenation
Trimetallic Ptsnin Catalysts
title_short Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
title_full Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
title_fullStr Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
title_full_unstemmed Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
title_sort Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
dc.creator.none.fl_str_mv Bocanegra, Sonia Alejandra
Castro, Alberto Antonio
Scelza, Osvaldo Antonio
de Miguel, Sergio Ruben
author Bocanegra, Sonia Alejandra
author_facet Bocanegra, Sonia Alejandra
Castro, Alberto Antonio
Scelza, Osvaldo Antonio
de Miguel, Sergio Ruben
author_role author
author2 Castro, Alberto Antonio
Scelza, Osvaldo Antonio
de Miguel, Sergio Ruben
author2_role author
author
author
dc.subject.none.fl_str_mv Catalyst Characterization
Mgal2o4 Support
N-Butane Dehydrogenation
Trimetallic Ptsnin Catalysts
topic Catalyst Characterization
Mgal2o4 Support
N-Butane Dehydrogenation
Trimetallic Ptsnin Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This paper deals with the characterization and catalytic dehydrogenation behavior of trimetallic InPtSn catalysts with different Sn content (from 0.12 wt% up to 1.08 wt%) supported on MgAl2O4. The support was initially impregnated with In, followed by a co-impregnation with Pt and Sn. The Pt and In contents in all catalysts were 0.30 wt% and 0.28 wt%, respectively. Besides, two catalysts with a Sn content of 0.37 wt% were prepared by two different methods: (a) successive impregnation (first Pt, second Sn) and (b) impregnation with PtSn complex, [(CH3)4N]2[PtCl2(SnCl3)2]. Experiments of n-butane dehydrogenation reaction were carried out both in continuous flow equipment and in pulse equipment. The catalysts were characterized by TPR, XPS and test reactions of the metallic phase. Trimetallic catalysts display high activity and selectivity to butenes and low deactivation during the n-butane dehydrogenation reaction. In order to analyze the influence of the preparation method on the catalytic performance, the better trimetallic catalyst was selected. It was observed that the different impregnation methods of Pt and Sn lead to trimetallic catalysts with similar catalytic behaviors between them. The characterization studies indicate the existence of geometric effects of In and Sn on Pt sites that produce a dilution of the Pt surface, and also a strong interaction between the three metals, which could lead to alloy formation. These facts positively influence the catalytic performance, thus increasing the activity, the selectivity to butenes and the stability of the metallic phase.
Fil: Bocanegra, Sonia Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Castro, Alberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description This paper deals with the characterization and catalytic dehydrogenation behavior of trimetallic InPtSn catalysts with different Sn content (from 0.12 wt% up to 1.08 wt%) supported on MgAl2O4. The support was initially impregnated with In, followed by a co-impregnation with Pt and Sn. The Pt and In contents in all catalysts were 0.30 wt% and 0.28 wt%, respectively. Besides, two catalysts with a Sn content of 0.37 wt% were prepared by two different methods: (a) successive impregnation (first Pt, second Sn) and (b) impregnation with PtSn complex, [(CH3)4N]2[PtCl2(SnCl3)2]. Experiments of n-butane dehydrogenation reaction were carried out both in continuous flow equipment and in pulse equipment. The catalysts were characterized by TPR, XPS and test reactions of the metallic phase. Trimetallic catalysts display high activity and selectivity to butenes and low deactivation during the n-butane dehydrogenation reaction. In order to analyze the influence of the preparation method on the catalytic performance, the better trimetallic catalyst was selected. It was observed that the different impregnation methods of Pt and Sn lead to trimetallic catalysts with similar catalytic behaviors between them. The characterization studies indicate the existence of geometric effects of In and Sn on Pt sites that produce a dilution of the Pt surface, and also a strong interaction between the three metals, which could lead to alloy formation. These facts positively influence the catalytic performance, thus increasing the activity, the selectivity to butenes and the stability of the metallic phase.
publishDate 2007
dc.date.none.fl_str_mv 2007-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66121
Bocanegra, Sonia Alejandra; Castro, Alberto Antonio; Scelza, Osvaldo Antonio; de Miguel, Sergio Ruben; Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts; Elsevier Science; Applied Catalysis A: General; 333; 1; 12-2007; 49-56
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66121
identifier_str_mv Bocanegra, Sonia Alejandra; Castro, Alberto Antonio; Scelza, Osvaldo Antonio; de Miguel, Sergio Ruben; Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts; Elsevier Science; Applied Catalysis A: General; 333; 1; 12-2007; 49-56
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2007.09.002
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614128136617984
score 13.070432

Publicaciones similares