Essential work of fracture of photo-oxidized LDPE/EVA films

Autores
Fasce, Laura Alejandra; Chiaverano, G.; Lach, R.; Frontini, Patricia Maria
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The Essential Work of Fracture approach (EWF) was used to determine how UV-C irradiation alters the fracture behaviour of LDPE/EVA films. Complementary characterization was performed by FTIR, DSC, TOM, and uniaxial tensile testing. The crosslinking reactions that govern photo-oxidation process at initial stage of exposure stiffened the amorphous phase of the polymer, leading to films with enhanced elastic modulus, yield stress and ultimate strength, but impaired strain at break. In the fracture experiments carried out on films irradiated within o and 5 days, EWF methodology requirements were met and the corresponding fracture toughness parameters (we and βwp) turned out to be sensitive to UV-C irradiation. Longer irradiation time triggered the development of microcracks, which not allowed further stable crack growth and invalidated the application of EWF approach. Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Chiaverano, G.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Lach, R.. University Halle; Alemania
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Essential Work of Fracture
Fracture Toughness
Irradiation
Plastic Films
Polyethylene
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70744
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Essential work of fracture of photo-oxidized LDPE/EVA filmsFasce, Laura AlejandraChiaverano, G.Lach, R.Frontini, Patricia MariaEssential Work of FractureFracture ToughnessIrradiationPlastic FilmsPolyethylenehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The Essential Work of Fracture approach (EWF) was used to determine how UV-C irradiation alters the fracture behaviour of LDPE/EVA films. Complementary characterization was performed by FTIR, DSC, TOM, and uniaxial tensile testing. The crosslinking reactions that govern photo-oxidation process at initial stage of exposure stiffened the amorphous phase of the polymer, leading to films with enhanced elastic modulus, yield stress and ultimate strength, but impaired strain at break. In the fracture experiments carried out on films irradiated within o and 5 days, EWF methodology requirements were met and the corresponding fracture toughness parameters (we and βwp) turned out to be sensitive to UV-C irradiation. Longer irradiation time triggered the development of microcracks, which not allowed further stable crack growth and invalidated the application of EWF approach. Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Chiaverano, G.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Lach, R.. University Halle; AlemaniaFil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaWiley2007-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70744Fasce, Laura Alejandra; Chiaverano, G.; Lach, R.; Frontini, Patricia Maria; Essential work of fracture of photo-oxidized LDPE/EVA films; Wiley; Macromolecular Symposia; 247; 12-2007; 271-2811022-1360CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/masy.200750131info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:36Zoai:ri.conicet.gov.ar:11336/70744instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:36.362CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Essential work of fracture of photo-oxidized LDPE/EVA films
title Essential work of fracture of photo-oxidized LDPE/EVA films
spellingShingle Essential work of fracture of photo-oxidized LDPE/EVA films
Fasce, Laura Alejandra
Essential Work of Fracture
Fracture Toughness
Irradiation
Plastic Films
Polyethylene
title_short Essential work of fracture of photo-oxidized LDPE/EVA films
title_full Essential work of fracture of photo-oxidized LDPE/EVA films
title_fullStr Essential work of fracture of photo-oxidized LDPE/EVA films
title_full_unstemmed Essential work of fracture of photo-oxidized LDPE/EVA films
title_sort Essential work of fracture of photo-oxidized LDPE/EVA films
dc.creator.none.fl_str_mv Fasce, Laura Alejandra
Chiaverano, G.
Lach, R.
Frontini, Patricia Maria
author Fasce, Laura Alejandra
author_facet Fasce, Laura Alejandra
Chiaverano, G.
Lach, R.
Frontini, Patricia Maria
author_role author
author2 Chiaverano, G.
Lach, R.
Frontini, Patricia Maria
author2_role author
author
author
dc.subject.none.fl_str_mv Essential Work of Fracture
Fracture Toughness
Irradiation
Plastic Films
Polyethylene
topic Essential Work of Fracture
Fracture Toughness
Irradiation
Plastic Films
Polyethylene
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The Essential Work of Fracture approach (EWF) was used to determine how UV-C irradiation alters the fracture behaviour of LDPE/EVA films. Complementary characterization was performed by FTIR, DSC, TOM, and uniaxial tensile testing. The crosslinking reactions that govern photo-oxidation process at initial stage of exposure stiffened the amorphous phase of the polymer, leading to films with enhanced elastic modulus, yield stress and ultimate strength, but impaired strain at break. In the fracture experiments carried out on films irradiated within o and 5 days, EWF methodology requirements were met and the corresponding fracture toughness parameters (we and βwp) turned out to be sensitive to UV-C irradiation. Longer irradiation time triggered the development of microcracks, which not allowed further stable crack growth and invalidated the application of EWF approach. Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Chiaverano, G.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Lach, R.. University Halle; Alemania
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The Essential Work of Fracture approach (EWF) was used to determine how UV-C irradiation alters the fracture behaviour of LDPE/EVA films. Complementary characterization was performed by FTIR, DSC, TOM, and uniaxial tensile testing. The crosslinking reactions that govern photo-oxidation process at initial stage of exposure stiffened the amorphous phase of the polymer, leading to films with enhanced elastic modulus, yield stress and ultimate strength, but impaired strain at break. In the fracture experiments carried out on films irradiated within o and 5 days, EWF methodology requirements were met and the corresponding fracture toughness parameters (we and βwp) turned out to be sensitive to UV-C irradiation. Longer irradiation time triggered the development of microcracks, which not allowed further stable crack growth and invalidated the application of EWF approach. Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.
publishDate 2007
dc.date.none.fl_str_mv 2007-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70744
Fasce, Laura Alejandra; Chiaverano, G.; Lach, R.; Frontini, Patricia Maria; Essential work of fracture of photo-oxidized LDPE/EVA films; Wiley; Macromolecular Symposia; 247; 12-2007; 271-281
1022-1360
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70744
identifier_str_mv Fasce, Laura Alejandra; Chiaverano, G.; Lach, R.; Frontini, Patricia Maria; Essential work of fracture of photo-oxidized LDPE/EVA films; Wiley; Macromolecular Symposia; 247; 12-2007; 271-281
1022-1360
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/masy.200750131
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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