Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane

Autores
Rovetto, Laura Jorgelina; Bottini, Susana Beatriz; Peters, Cornelis J.
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The hydrogenolysis of fatty acid methyl esters (FAME) to obtain fatty alcohols, is a catalytic, multiphase reaction. Reaction rates can be greatly increased by using a supercritical solvent to bring the reactive mixture into a single homogeneous phase. Knowledge of the corresponding phase equilibria is a prerequisite in order to find the homogeneous region and to determine the most favorable conditions for the hydrogenation process. This paper reports experimental phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane. A temperature region between 360 and 450 K, and pressures up to 15 MPa were covered.
Fil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Peters, Cornelis J.. Delft University of Technology; Países Bajos
Materia
HYDROGEN
METHYL PALMITATE
PHASE EQUILIBRIA
PROPANE
SUPERCRITICAL HYDROGENOLYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/97828
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propaneRovetto, Laura JorgelinaBottini, Susana BeatrizPeters, Cornelis J.HYDROGENMETHYL PALMITATEPHASE EQUILIBRIAPROPANESUPERCRITICAL HYDROGENOLYSIShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The hydrogenolysis of fatty acid methyl esters (FAME) to obtain fatty alcohols, is a catalytic, multiphase reaction. Reaction rates can be greatly increased by using a supercritical solvent to bring the reactive mixture into a single homogeneous phase. Knowledge of the corresponding phase equilibria is a prerequisite in order to find the homogeneous region and to determine the most favorable conditions for the hydrogenation process. This paper reports experimental phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane. A temperature region between 360 and 450 K, and pressures up to 15 MPa were covered.Fil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Peters, Cornelis J.. Delft University of Technology; Países BajosElsevier Science2004-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/97828Rovetto, Laura Jorgelina; Bottini, Susana Beatriz; Peters, Cornelis J.; Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane; Elsevier Science; Journal of Supercritical Fluids; 31; 2; 10-2004; 111-1210896-8446CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2003.10.003info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0896844603002596info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:54Zoai:ri.conicet.gov.ar:11336/97828instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:55.022CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
title Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
spellingShingle Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
Rovetto, Laura Jorgelina
HYDROGEN
METHYL PALMITATE
PHASE EQUILIBRIA
PROPANE
SUPERCRITICAL HYDROGENOLYSIS
title_short Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
title_full Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
title_fullStr Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
title_full_unstemmed Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
title_sort Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane
dc.creator.none.fl_str_mv Rovetto, Laura Jorgelina
Bottini, Susana Beatriz
Peters, Cornelis J.
author Rovetto, Laura Jorgelina
author_facet Rovetto, Laura Jorgelina
Bottini, Susana Beatriz
Peters, Cornelis J.
author_role author
author2 Bottini, Susana Beatriz
Peters, Cornelis J.
author2_role author
author
dc.subject.none.fl_str_mv HYDROGEN
METHYL PALMITATE
PHASE EQUILIBRIA
PROPANE
SUPERCRITICAL HYDROGENOLYSIS
topic HYDROGEN
METHYL PALMITATE
PHASE EQUILIBRIA
PROPANE
SUPERCRITICAL HYDROGENOLYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The hydrogenolysis of fatty acid methyl esters (FAME) to obtain fatty alcohols, is a catalytic, multiphase reaction. Reaction rates can be greatly increased by using a supercritical solvent to bring the reactive mixture into a single homogeneous phase. Knowledge of the corresponding phase equilibria is a prerequisite in order to find the homogeneous region and to determine the most favorable conditions for the hydrogenation process. This paper reports experimental phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane. A temperature region between 360 and 450 K, and pressures up to 15 MPa were covered.
Fil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Peters, Cornelis J.. Delft University of Technology; Países Bajos
description The hydrogenolysis of fatty acid methyl esters (FAME) to obtain fatty alcohols, is a catalytic, multiphase reaction. Reaction rates can be greatly increased by using a supercritical solvent to bring the reactive mixture into a single homogeneous phase. Knowledge of the corresponding phase equilibria is a prerequisite in order to find the homogeneous region and to determine the most favorable conditions for the hydrogenation process. This paper reports experimental phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane. A temperature region between 360 and 450 K, and pressures up to 15 MPa were covered.
publishDate 2004
dc.date.none.fl_str_mv 2004-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/97828
Rovetto, Laura Jorgelina; Bottini, Susana Beatriz; Peters, Cornelis J.; Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane; Elsevier Science; Journal of Supercritical Fluids; 31; 2; 10-2004; 111-121
0896-8446
CONICET Digital
CONICET
url http://hdl.handle.net/11336/97828
identifier_str_mv Rovetto, Laura Jorgelina; Bottini, Susana Beatriz; Peters, Cornelis J.; Phase equilibrium data on binary and ternary mixtures of methyl palmitate, hydrogen and propane; Elsevier Science; Journal of Supercritical Fluids; 31; 2; 10-2004; 111-121
0896-8446
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2003.10.003
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0896844603002596
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614282106372096
score 13.260194

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