Using photosensitive dye to improve multi walled carbon nanotubes dispersion

Autores
Díaz Costanzo, Guadalupe; Goyanes, Silvia Nair; Ledesma, Silvia Adriana
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
As already well-known, the outstanding mechanical and electrical properties of carbon nanotubes (CNT) are partially lost when CNT aggregate. The fact that CNT tend to aggregate makes difficult to put them into a host matrix, for example. Until now, achieving stable dispersions of CNT is still a challenge. In the present work, we show that the addition of an azobenzene derivative, Disperse Orange 3 (DO3) to dispersions of multi walled carbon nanotubes (MWCNT) in the organic solvent tetrahydrofuran (THF) efficiently helps debundling MWCNT and makes dispersions stable for days. We report UV-Vis optical absorption experiments that suggest an interaction between MWCNT and DO3 molecules following the behavior qualitatively observed. Dispersions with MWCNT and DO3 in THF were observed qualitatively over time. Successful suspensions (for the higher DO3 concentrations studied) were stable for several days. Also, we prepared polymeric films doped with MWCNT non-covalent functionalized with DO3 in one of the proper DO3/MWCNT weight relation where stable supensions were obtained. In this study we show preliminary results where the optical response of these samples was also measured.
Fil: Díaz Costanzo, Guadalupe. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Goyanes, Silvia Nair. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Ledesma, Silvia Adriana. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Materia
Azo Dye
Carbon Nanotubes
Dispersion
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/56746

id CONICETDig_e6e40b9398c41721bd5688a7029630e0
oai_identifier_str oai:ri.conicet.gov.ar:11336/56746
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Using photosensitive dye to improve multi walled carbon nanotubes dispersionDíaz Costanzo, GuadalupeGoyanes, Silvia NairLedesma, Silvia AdrianaAzo DyeCarbon NanotubesDispersionhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2As already well-known, the outstanding mechanical and electrical properties of carbon nanotubes (CNT) are partially lost when CNT aggregate. The fact that CNT tend to aggregate makes difficult to put them into a host matrix, for example. Until now, achieving stable dispersions of CNT is still a challenge. In the present work, we show that the addition of an azobenzene derivative, Disperse Orange 3 (DO3) to dispersions of multi walled carbon nanotubes (MWCNT) in the organic solvent tetrahydrofuran (THF) efficiently helps debundling MWCNT and makes dispersions stable for days. We report UV-Vis optical absorption experiments that suggest an interaction between MWCNT and DO3 molecules following the behavior qualitatively observed. Dispersions with MWCNT and DO3 in THF were observed qualitatively over time. Successful suspensions (for the higher DO3 concentrations studied) were stable for several days. Also, we prepared polymeric films doped with MWCNT non-covalent functionalized with DO3 in one of the proper DO3/MWCNT weight relation where stable supensions were obtained. In this study we show preliminary results where the optical response of these samples was also measured.Fil: Díaz Costanzo, Guadalupe. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Goyanes, Silvia Nair. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Ledesma, Silvia Adriana. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaInstitute of Physics Publishing2011-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/56746Díaz Costanzo, Guadalupe; Goyanes, Silvia Nair; Ledesma, Silvia Adriana; Using photosensitive dye to improve multi walled carbon nanotubes dispersion; Institute of Physics Publishing; Journal of Physics: Conference Series; 274; 1; 11-2011; 1-71742-6596CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1088/1742-6596/274/1/012117info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:48:32Zoai:ri.conicet.gov.ar:11336/56746instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:48:32.851CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Using photosensitive dye to improve multi walled carbon nanotubes dispersion
title Using photosensitive dye to improve multi walled carbon nanotubes dispersion
spellingShingle Using photosensitive dye to improve multi walled carbon nanotubes dispersion
Díaz Costanzo, Guadalupe
Azo Dye
Carbon Nanotubes
Dispersion
title_short Using photosensitive dye to improve multi walled carbon nanotubes dispersion
title_full Using photosensitive dye to improve multi walled carbon nanotubes dispersion
title_fullStr Using photosensitive dye to improve multi walled carbon nanotubes dispersion
title_full_unstemmed Using photosensitive dye to improve multi walled carbon nanotubes dispersion
title_sort Using photosensitive dye to improve multi walled carbon nanotubes dispersion
dc.creator.none.fl_str_mv Díaz Costanzo, Guadalupe
Goyanes, Silvia Nair
Ledesma, Silvia Adriana
author Díaz Costanzo, Guadalupe
author_facet Díaz Costanzo, Guadalupe
Goyanes, Silvia Nair
Ledesma, Silvia Adriana
author_role author
author2 Goyanes, Silvia Nair
Ledesma, Silvia Adriana
author2_role author
author
dc.subject.none.fl_str_mv Azo Dye
Carbon Nanotubes
Dispersion
topic Azo Dye
Carbon Nanotubes
Dispersion
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv As already well-known, the outstanding mechanical and electrical properties of carbon nanotubes (CNT) are partially lost when CNT aggregate. The fact that CNT tend to aggregate makes difficult to put them into a host matrix, for example. Until now, achieving stable dispersions of CNT is still a challenge. In the present work, we show that the addition of an azobenzene derivative, Disperse Orange 3 (DO3) to dispersions of multi walled carbon nanotubes (MWCNT) in the organic solvent tetrahydrofuran (THF) efficiently helps debundling MWCNT and makes dispersions stable for days. We report UV-Vis optical absorption experiments that suggest an interaction between MWCNT and DO3 molecules following the behavior qualitatively observed. Dispersions with MWCNT and DO3 in THF were observed qualitatively over time. Successful suspensions (for the higher DO3 concentrations studied) were stable for several days. Also, we prepared polymeric films doped with MWCNT non-covalent functionalized with DO3 in one of the proper DO3/MWCNT weight relation where stable supensions were obtained. In this study we show preliminary results where the optical response of these samples was also measured.
Fil: Díaz Costanzo, Guadalupe. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Goyanes, Silvia Nair. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Ledesma, Silvia Adriana. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
description As already well-known, the outstanding mechanical and electrical properties of carbon nanotubes (CNT) are partially lost when CNT aggregate. The fact that CNT tend to aggregate makes difficult to put them into a host matrix, for example. Until now, achieving stable dispersions of CNT is still a challenge. In the present work, we show that the addition of an azobenzene derivative, Disperse Orange 3 (DO3) to dispersions of multi walled carbon nanotubes (MWCNT) in the organic solvent tetrahydrofuran (THF) efficiently helps debundling MWCNT and makes dispersions stable for days. We report UV-Vis optical absorption experiments that suggest an interaction between MWCNT and DO3 molecules following the behavior qualitatively observed. Dispersions with MWCNT and DO3 in THF were observed qualitatively over time. Successful suspensions (for the higher DO3 concentrations studied) were stable for several days. Also, we prepared polymeric films doped with MWCNT non-covalent functionalized with DO3 in one of the proper DO3/MWCNT weight relation where stable supensions were obtained. In this study we show preliminary results where the optical response of these samples was also measured.
publishDate 2011
dc.date.none.fl_str_mv 2011-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/56746
Díaz Costanzo, Guadalupe; Goyanes, Silvia Nair; Ledesma, Silvia Adriana; Using photosensitive dye to improve multi walled carbon nanotubes dispersion; Institute of Physics Publishing; Journal of Physics: Conference Series; 274; 1; 11-2011; 1-7
1742-6596
CONICET Digital
CONICET
url http://hdl.handle.net/11336/56746
identifier_str_mv Díaz Costanzo, Guadalupe; Goyanes, Silvia Nair; Ledesma, Silvia Adriana; Using photosensitive dye to improve multi walled carbon nanotubes dispersion; Institute of Physics Publishing; Journal of Physics: Conference Series; 274; 1; 11-2011; 1-7
1742-6596
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1088/1742-6596/274/1/012117
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Institute of Physics Publishing
publisher.none.fl_str_mv Institute of Physics Publishing
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268929075970048
score 13.13397