Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides

Autores
Luggren, Pablo Jorge; Apesteguia, Carlos Rodolfo; Di Cosimo, Juana Isabel
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The reaction mechanism of 2-hexanol conversion to high molecular weight compounds to be used as liquid transportation fuels was studied on MgO, Cu/SiO2 and a bifunctional Cu-Mg-Al mixed oxide with 8 wt. % Cu (catalyst 8.0CuMgAl). Catalysts were characterized by several physical and spectroscopic techniques. The evolution of 2-hexanol conversion and yields in inert (N2) and reducing (H2) reaction atmospheres at different contact times (W/F0) was investigated, which allowed distinguishing between primary and secondary products. In H2, at W/F0 = 500 g h/mol, the bifunctional 8.0CuMgAl catalyst yielded more than 90 % of branched C9-C24 oxygenates and hydrocarbons that were obtained via sequential steps comprising dehydrogenation, C-C coupling, dehydration and hydrogenation reactions. The metal-base bifunctional nature of this reaction network on 8.0CuMgAl was elucidated: nano-sized Cu0 particles promote dehydrogenation and hydrogenation steps whereas Mg-O pairs participate mainly in C-C coupling reactions. The product distribution depended on the reaction atmosphere. In H2, the reaction pathways leading to formation of even carbon atom number products (C12, C18 and C24) were favored and hydrocarbons were the main products at high conversion levels. In N2, significant amounts of odd carbon atom number products (C9, C15 and C21) were formed with a higher contribution of oxygenates to the product pool.
Fil: Luggren, Pablo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
2-Hexanol
Aldol Condensation
Dehydrogenation
Hydrogenation
Copper
Mixed Oxides
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/36823
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/36823
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed OxidesLuggren, Pablo JorgeApesteguia, Carlos RodolfoDi Cosimo, Juana Isabel2-HexanolAldol CondensationDehydrogenationHydrogenationCopperMixed Oxideshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The reaction mechanism of 2-hexanol conversion to high molecular weight compounds to be used as liquid transportation fuels was studied on MgO, Cu/SiO2 and a bifunctional Cu-Mg-Al mixed oxide with 8 wt. % Cu (catalyst 8.0CuMgAl). Catalysts were characterized by several physical and spectroscopic techniques. The evolution of 2-hexanol conversion and yields in inert (N2) and reducing (H2) reaction atmospheres at different contact times (W/F0) was investigated, which allowed distinguishing between primary and secondary products. In H2, at W/F0 = 500 g h/mol, the bifunctional 8.0CuMgAl catalyst yielded more than 90 % of branched C9-C24 oxygenates and hydrocarbons that were obtained via sequential steps comprising dehydrogenation, C-C coupling, dehydration and hydrogenation reactions. The metal-base bifunctional nature of this reaction network on 8.0CuMgAl was elucidated: nano-sized Cu0 particles promote dehydrogenation and hydrogenation steps whereas Mg-O pairs participate mainly in C-C coupling reactions. The product distribution depended on the reaction atmosphere. In H2, the reaction pathways leading to formation of even carbon atom number products (C12, C18 and C24) were favored and hydrocarbons were the main products at high conversion levels. In N2, significant amounts of odd carbon atom number products (C9, C15 and C21) were formed with a higher contribution of oxygenates to the product pool.Fil: Luggren, Pablo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaSpringer/plenum Publishers2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/36823Luggren, Pablo Jorge; Apesteguia, Carlos Rodolfo; Di Cosimo, Juana Isabel; Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides; Springer/plenum Publishers; Topics In Catalysis; 59; 2-4; 7-2015; 196-2061022-5528CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs11244-015-0428-3info:eu-repo/semantics/altIdentifier/doi/10.1007/s11244-015-0428-3info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:22Zoai:ri.conicet.gov.ar:11336/36823instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:23.157CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
title Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
spellingShingle Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
Luggren, Pablo Jorge
2-Hexanol
Aldol Condensation
Dehydrogenation
Hydrogenation
Copper
Mixed Oxides
title_short Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
title_full Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
title_fullStr Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
title_full_unstemmed Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
title_sort Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides
dc.creator.none.fl_str_mv Luggren, Pablo Jorge
Apesteguia, Carlos Rodolfo
Di Cosimo, Juana Isabel
author Luggren, Pablo Jorge
author_facet Luggren, Pablo Jorge
Apesteguia, Carlos Rodolfo
Di Cosimo, Juana Isabel
author_role author
author2 Apesteguia, Carlos Rodolfo
Di Cosimo, Juana Isabel
author2_role author
author
dc.subject.none.fl_str_mv 2-Hexanol
Aldol Condensation
Dehydrogenation
Hydrogenation
Copper
Mixed Oxides
topic 2-Hexanol
Aldol Condensation
Dehydrogenation
Hydrogenation
Copper
Mixed Oxides
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The reaction mechanism of 2-hexanol conversion to high molecular weight compounds to be used as liquid transportation fuels was studied on MgO, Cu/SiO2 and a bifunctional Cu-Mg-Al mixed oxide with 8 wt. % Cu (catalyst 8.0CuMgAl). Catalysts were characterized by several physical and spectroscopic techniques. The evolution of 2-hexanol conversion and yields in inert (N2) and reducing (H2) reaction atmospheres at different contact times (W/F0) was investigated, which allowed distinguishing between primary and secondary products. In H2, at W/F0 = 500 g h/mol, the bifunctional 8.0CuMgAl catalyst yielded more than 90 % of branched C9-C24 oxygenates and hydrocarbons that were obtained via sequential steps comprising dehydrogenation, C-C coupling, dehydration and hydrogenation reactions. The metal-base bifunctional nature of this reaction network on 8.0CuMgAl was elucidated: nano-sized Cu0 particles promote dehydrogenation and hydrogenation steps whereas Mg-O pairs participate mainly in C-C coupling reactions. The product distribution depended on the reaction atmosphere. In H2, the reaction pathways leading to formation of even carbon atom number products (C12, C18 and C24) were favored and hydrocarbons were the main products at high conversion levels. In N2, significant amounts of odd carbon atom number products (C9, C15 and C21) were formed with a higher contribution of oxygenates to the product pool.
Fil: Luggren, Pablo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The reaction mechanism of 2-hexanol conversion to high molecular weight compounds to be used as liquid transportation fuels was studied on MgO, Cu/SiO2 and a bifunctional Cu-Mg-Al mixed oxide with 8 wt. % Cu (catalyst 8.0CuMgAl). Catalysts were characterized by several physical and spectroscopic techniques. The evolution of 2-hexanol conversion and yields in inert (N2) and reducing (H2) reaction atmospheres at different contact times (W/F0) was investigated, which allowed distinguishing between primary and secondary products. In H2, at W/F0 = 500 g h/mol, the bifunctional 8.0CuMgAl catalyst yielded more than 90 % of branched C9-C24 oxygenates and hydrocarbons that were obtained via sequential steps comprising dehydrogenation, C-C coupling, dehydration and hydrogenation reactions. The metal-base bifunctional nature of this reaction network on 8.0CuMgAl was elucidated: nano-sized Cu0 particles promote dehydrogenation and hydrogenation steps whereas Mg-O pairs participate mainly in C-C coupling reactions. The product distribution depended on the reaction atmosphere. In H2, the reaction pathways leading to formation of even carbon atom number products (C12, C18 and C24) were favored and hydrocarbons were the main products at high conversion levels. In N2, significant amounts of odd carbon atom number products (C9, C15 and C21) were formed with a higher contribution of oxygenates to the product pool.
publishDate 2015
dc.date.none.fl_str_mv 2015-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/36823
Luggren, Pablo Jorge; Apesteguia, Carlos Rodolfo; Di Cosimo, Juana Isabel; Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides; Springer/plenum Publishers; Topics In Catalysis; 59; 2-4; 7-2015; 196-206
1022-5528
CONICET Digital
CONICET
url http://hdl.handle.net/11336/36823
identifier_str_mv Luggren, Pablo Jorge; Apesteguia, Carlos Rodolfo; Di Cosimo, Juana Isabel; Conversion of Biomass-Derived 2-Hexanol to Liquid Transportation Fuels: Study of the Reaction Mechanism on Cu–Mg–Al Mixed Oxides; Springer/plenum Publishers; Topics In Catalysis; 59; 2-4; 7-2015; 196-206
1022-5528
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs11244-015-0428-3
info:eu-repo/semantics/altIdentifier/doi/10.1007/s11244-015-0428-3
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer/plenum Publishers
publisher.none.fl_str_mv Springer/plenum Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613397108228096
score 13.070432

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