Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia

Autores
Coronel, Angelina del Carmen; Cerda García-Rojas, Carlos M.; Joseph Nathan, Pedro; Catalan, Cesar Atilio Nazareno
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Chemical investigations on the essential oil of Lippia integrifolia performed by column chromatography, HPLC, GC-MS, 1H- and 13C-NMR spectroscopy led to the identification of 78 components. A new sesquiterpene alcohol, trans-africanan-1α-ol (4), was characterized as a significant component of the oil. Additionally, six samples obtained at monthly intervals through the annual cycle of the shrub (November-April) were studied. The oil was characterized by large amounts of oxygenated sesquiterpenes (53.3-69.4%) and sesquiterpene hydrocarbons (14.3-27.9%), along with small amounts of monoterpenoids (1.4-2.9%). Lippifoli-1(6)-en-5-one (2), african-5-en-1α-ol (3), β-caryophyllene oxide, 4,5-seco-africanan-4,5-dione (10), trans-africanan-1α-ol (4), humulene epoxide II, integrifolian-1,5-dione (1) and lippifoli-1(6)-en4β-ol-5-one (7) were the main oxygenated constituents. Although the qualitative composition appeared to be constant, there were large quantitative variations in the content of most components through the studied period. Copyright © 2006 John Wiley & Sons, Ltd.
Fil: Coronel, Angelina del Carmen. Universidad Nacional de Tucumán; Argentina
Fil: Cerda García-Rojas, Carlos M.. CENTRO DE INVESTIGACIÓN Y DE ESTUDIOS AVANZADOS ; INSTITUTO POLITÉCNICO NACIONAL;
Fil: Joseph Nathan, Pedro. CENTRO DE INVESTIGACIÓN Y DE ESTUDIOS AVANZADOS ; INSTITUTO POLITÉCNICO NACIONAL;
Fil: Catalan, Cesar Atilio Nazareno. Universidad Nacional de Tucumán; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Materia
ESSENTIAL OIL COMPOSITION
LIPPIA INTEGRIFOLIA
NEW SESQUITERPENE ALCOHOL
SEASONAL VARIATION
TRANS-AFRICANAN-1Α-O1
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/99571
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/99571
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifoliaCoronel, Angelina del CarmenCerda García-Rojas, Carlos M.Joseph Nathan, PedroCatalan, Cesar Atilio NazarenoESSENTIAL OIL COMPOSITIONLIPPIA INTEGRIFOLIANEW SESQUITERPENE ALCOHOLSEASONAL VARIATIONTRANS-AFRICANAN-1Α-O1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Chemical investigations on the essential oil of Lippia integrifolia performed by column chromatography, HPLC, GC-MS, 1H- and 13C-NMR spectroscopy led to the identification of 78 components. A new sesquiterpene alcohol, trans-africanan-1α-ol (4), was characterized as a significant component of the oil. Additionally, six samples obtained at monthly intervals through the annual cycle of the shrub (November-April) were studied. The oil was characterized by large amounts of oxygenated sesquiterpenes (53.3-69.4%) and sesquiterpene hydrocarbons (14.3-27.9%), along with small amounts of monoterpenoids (1.4-2.9%). Lippifoli-1(6)-en-5-one (2), african-5-en-1α-ol (3), β-caryophyllene oxide, 4,5-seco-africanan-4,5-dione (10), trans-africanan-1α-ol (4), humulene epoxide II, integrifolian-1,5-dione (1) and lippifoli-1(6)-en4β-ol-5-one (7) were the main oxygenated constituents. Although the qualitative composition appeared to be constant, there were large quantitative variations in the content of most components through the studied period. Copyright © 2006 John Wiley & Sons, Ltd.Fil: Coronel, Angelina del Carmen. Universidad Nacional de Tucumán; ArgentinaFil: Cerda García-Rojas, Carlos M.. CENTRO DE INVESTIGACIÓN Y DE ESTUDIOS AVANZADOS ; INSTITUTO POLITÉCNICO NACIONAL; Fil: Joseph Nathan, Pedro. CENTRO DE INVESTIGACIÓN Y DE ESTUDIOS AVANZADOS ; INSTITUTO POLITÉCNICO NACIONAL; Fil: Catalan, Cesar Atilio Nazareno. Universidad Nacional de Tucumán; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaJohn Wiley & Sons Ltd2006-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/99571Coronel, Angelina del Carmen; Cerda García-Rojas, Carlos M.; Joseph Nathan, Pedro; Catalan, Cesar Atilio Nazareno; Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia; John Wiley & Sons Ltd; Flavour And Fragrance Journal; 21; 5; 9-2006; 839-8470882-5734CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/ffj.1736info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ffj.1736info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:02Zoai:ri.conicet.gov.ar:11336/99571instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:02.77CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
title Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
spellingShingle Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
Coronel, Angelina del Carmen
ESSENTIAL OIL COMPOSITION
LIPPIA INTEGRIFOLIA
NEW SESQUITERPENE ALCOHOL
SEASONAL VARIATION
TRANS-AFRICANAN-1Α-O1
title_short Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
title_full Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
title_fullStr Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
title_full_unstemmed Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
title_sort Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia
dc.creator.none.fl_str_mv Coronel, Angelina del Carmen
Cerda García-Rojas, Carlos M.
Joseph Nathan, Pedro
Catalan, Cesar Atilio Nazareno
author Coronel, Angelina del Carmen
author_facet Coronel, Angelina del Carmen
Cerda García-Rojas, Carlos M.
Joseph Nathan, Pedro
Catalan, Cesar Atilio Nazareno
author_role author
author2 Cerda García-Rojas, Carlos M.
Joseph Nathan, Pedro
Catalan, Cesar Atilio Nazareno
author2_role author
author
author
dc.subject.none.fl_str_mv ESSENTIAL OIL COMPOSITION
LIPPIA INTEGRIFOLIA
NEW SESQUITERPENE ALCOHOL
SEASONAL VARIATION
TRANS-AFRICANAN-1Α-O1
topic ESSENTIAL OIL COMPOSITION
LIPPIA INTEGRIFOLIA
NEW SESQUITERPENE ALCOHOL
SEASONAL VARIATION
TRANS-AFRICANAN-1Α-O1
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Chemical investigations on the essential oil of Lippia integrifolia performed by column chromatography, HPLC, GC-MS, 1H- and 13C-NMR spectroscopy led to the identification of 78 components. A new sesquiterpene alcohol, trans-africanan-1α-ol (4), was characterized as a significant component of the oil. Additionally, six samples obtained at monthly intervals through the annual cycle of the shrub (November-April) were studied. The oil was characterized by large amounts of oxygenated sesquiterpenes (53.3-69.4%) and sesquiterpene hydrocarbons (14.3-27.9%), along with small amounts of monoterpenoids (1.4-2.9%). Lippifoli-1(6)-en-5-one (2), african-5-en-1α-ol (3), β-caryophyllene oxide, 4,5-seco-africanan-4,5-dione (10), trans-africanan-1α-ol (4), humulene epoxide II, integrifolian-1,5-dione (1) and lippifoli-1(6)-en4β-ol-5-one (7) were the main oxygenated constituents. Although the qualitative composition appeared to be constant, there were large quantitative variations in the content of most components through the studied period. Copyright © 2006 John Wiley & Sons, Ltd.
Fil: Coronel, Angelina del Carmen. Universidad Nacional de Tucumán; Argentina
Fil: Cerda García-Rojas, Carlos M.. CENTRO DE INVESTIGACIÓN Y DE ESTUDIOS AVANZADOS ; INSTITUTO POLITÉCNICO NACIONAL;
Fil: Joseph Nathan, Pedro. CENTRO DE INVESTIGACIÓN Y DE ESTUDIOS AVANZADOS ; INSTITUTO POLITÉCNICO NACIONAL;
Fil: Catalan, Cesar Atilio Nazareno. Universidad Nacional de Tucumán; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
description Chemical investigations on the essential oil of Lippia integrifolia performed by column chromatography, HPLC, GC-MS, 1H- and 13C-NMR spectroscopy led to the identification of 78 components. A new sesquiterpene alcohol, trans-africanan-1α-ol (4), was characterized as a significant component of the oil. Additionally, six samples obtained at monthly intervals through the annual cycle of the shrub (November-April) were studied. The oil was characterized by large amounts of oxygenated sesquiterpenes (53.3-69.4%) and sesquiterpene hydrocarbons (14.3-27.9%), along with small amounts of monoterpenoids (1.4-2.9%). Lippifoli-1(6)-en-5-one (2), african-5-en-1α-ol (3), β-caryophyllene oxide, 4,5-seco-africanan-4,5-dione (10), trans-africanan-1α-ol (4), humulene epoxide II, integrifolian-1,5-dione (1) and lippifoli-1(6)-en4β-ol-5-one (7) were the main oxygenated constituents. Although the qualitative composition appeared to be constant, there were large quantitative variations in the content of most components through the studied period. Copyright © 2006 John Wiley & Sons, Ltd.
publishDate 2006
dc.date.none.fl_str_mv 2006-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/99571
Coronel, Angelina del Carmen; Cerda García-Rojas, Carlos M.; Joseph Nathan, Pedro; Catalan, Cesar Atilio Nazareno; Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia; John Wiley & Sons Ltd; Flavour And Fragrance Journal; 21; 5; 9-2006; 839-847
0882-5734
CONICET Digital
CONICET
url http://hdl.handle.net/11336/99571
identifier_str_mv Coronel, Angelina del Carmen; Cerda García-Rojas, Carlos M.; Joseph Nathan, Pedro; Catalan, Cesar Atilio Nazareno; Chemical composition, seasonal variation and a new sesquiterpene alcohol from the essential oil of Lippia integrifolia; John Wiley & Sons Ltd; Flavour And Fragrance Journal; 21; 5; 9-2006; 839-847
0882-5734
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/ffj.1736
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ffj.1736
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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