Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol

Autores
Del Árbol, Nerea Ruiz; Palacio, Irene; Sánchez Sánchez, Carlos; Otero Irurueta, Gonzalo; Martínez, José I.; Rodriguez, Luis Miguel; Serrate, David; Cossaro, Albano; Lacovig, Paolo; Lizzit, Silvano; Verdini, Alberto; Floreano, Luca; Martín Gago, José Ángel; López, María F.
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We present a comparative study of the room-temperature adsorption of p-aminophenol (p-AP) molecules on three metal surfaces, namely Cu(110), Cu(111), and Pt(111). We show that the chemical nature and the structural symmetry of the substrate control the activation of the terminal molecular groups, which result in different arrangements of the interfacial molecular layer. To this aim, we have used in situ STM images combined with synchrotron radiation high-resolution XPS and NEXAFS spectra, and the results were simulated by DFT calculations. On copper, the interaction between the molecules and the surface is weaker on the (111) surface crystal plane than on the (110) one, favoring molecular diffusion and leading to larger ordered domains. We demonstrate that the p-AP molecule undergoes spontaneous dehydrogenation of the alcohol group to form phenoxy species on all the studied surfaces; however, this process is not complete on the less reactive surface, Cu(111). The Pt(111) surface exhibits stronger molecule-surface interaction, inducing a short-range ordered molecular arrangement that increases over time. In addition, on the highly reactive Pt(111) surface other chemical processes are evidenced, such as the dehydrogenation of the amine group.
Fil: Del Árbol, Nerea Ruiz. Instituto de Ciencia de Materiales de Madrid; España
Fil: Palacio, Irene. Instituto de Ciencia de Materiales de Madrid; España
Fil: Sánchez Sánchez, Carlos. Instituto de Ciencia de Materiales de Madrid; España
Fil: Otero Irurueta, Gonzalo. Universidade de Aveiro; Portugal
Fil: Martínez, José I.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Rodriguez, Luis Miguel. Instituto de Ciencia de Materiales de Madrid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina
Fil: Serrate, David. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: Cossaro, Albano. Università degli Studi di Trieste; Italia. Laboratorio Nazionale Tasc; Italia
Fil: Lacovig, Paolo. Elettra - Synchrotron Ligght Laboratory; Italia
Fil: Lizzit, Silvano. Elettra - Synchrotron Ligght Laboratory; Italia
Fil: Verdini, Alberto. Laboratorio Nazionale Tasc; Italia
Fil: Floreano, Luca. No especifíca;
Fil: Martín Gago, José Ángel. Instituto de Ciencia de Materiales de Madrid; España
Fil: López, María F.. Instituto de Ciencia de Materiales de Madrid; España
Materia
aminophenol
surface science
STM
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/146773
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/146773
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-AminophenolDel Árbol, Nerea RuizPalacio, IreneSánchez Sánchez, CarlosOtero Irurueta, GonzaloMartínez, José I.Rodriguez, Luis MiguelSerrate, DavidCossaro, AlbanoLacovig, PaoloLizzit, SilvanoVerdini, AlbertoFloreano, LucaMartín Gago, José ÁngelLópez, María F.aminophenolsurface scienceSTMhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1We present a comparative study of the room-temperature adsorption of p-aminophenol (p-AP) molecules on three metal surfaces, namely Cu(110), Cu(111), and Pt(111). We show that the chemical nature and the structural symmetry of the substrate control the activation of the terminal molecular groups, which result in different arrangements of the interfacial molecular layer. To this aim, we have used in situ STM images combined with synchrotron radiation high-resolution XPS and NEXAFS spectra, and the results were simulated by DFT calculations. On copper, the interaction between the molecules and the surface is weaker on the (111) surface crystal plane than on the (110) one, favoring molecular diffusion and leading to larger ordered domains. We demonstrate that the p-AP molecule undergoes spontaneous dehydrogenation of the alcohol group to form phenoxy species on all the studied surfaces; however, this process is not complete on the less reactive surface, Cu(111). The Pt(111) surface exhibits stronger molecule-surface interaction, inducing a short-range ordered molecular arrangement that increases over time. In addition, on the highly reactive Pt(111) surface other chemical processes are evidenced, such as the dehydrogenation of the amine group.Fil: Del Árbol, Nerea Ruiz. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Palacio, Irene. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Sánchez Sánchez, Carlos. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Otero Irurueta, Gonzalo. Universidade de Aveiro; PortugalFil: Martínez, José I.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Rodriguez, Luis Miguel. Instituto de Ciencia de Materiales de Madrid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; ArgentinaFil: Serrate, David. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; EspañaFil: Cossaro, Albano. Università degli Studi di Trieste; Italia. Laboratorio Nazionale Tasc; ItaliaFil: Lacovig, Paolo. Elettra - Synchrotron Ligght Laboratory; ItaliaFil: Lizzit, Silvano. Elettra - Synchrotron Ligght Laboratory; ItaliaFil: Verdini, Alberto. Laboratorio Nazionale Tasc; ItaliaFil: Floreano, Luca. No especifíca;Fil: Martín Gago, José Ángel. Instituto de Ciencia de Materiales de Madrid; EspañaFil: López, María F.. Instituto de Ciencia de Materiales de Madrid; EspañaAmerican Chemical Society2020-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/146773Del Árbol, Nerea Ruiz; Palacio, Irene; Sánchez Sánchez, Carlos; Otero Irurueta, Gonzalo; Martínez, José I.; et al.; Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol; American Chemical Society; Journal of Physical Chemistry C; 124; 36; 9-2020; 19655-196651932-7447CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.0c06101info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.0c06101info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:18:07Zoai:ri.conicet.gov.ar:11336/146773instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:18:07.478CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
title Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
spellingShingle Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
Del Árbol, Nerea Ruiz
aminophenol
surface science
STM
title_short Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
title_full Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
title_fullStr Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
title_full_unstemmed Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
title_sort Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol
dc.creator.none.fl_str_mv Del Árbol, Nerea Ruiz
Palacio, Irene
Sánchez Sánchez, Carlos
Otero Irurueta, Gonzalo
Martínez, José I.
Rodriguez, Luis Miguel
Serrate, David
Cossaro, Albano
Lacovig, Paolo
Lizzit, Silvano
Verdini, Alberto
Floreano, Luca
Martín Gago, José Ángel
López, María F.
author Del Árbol, Nerea Ruiz
author_facet Del Árbol, Nerea Ruiz
Palacio, Irene
Sánchez Sánchez, Carlos
Otero Irurueta, Gonzalo
Martínez, José I.
Rodriguez, Luis Miguel
Serrate, David
Cossaro, Albano
Lacovig, Paolo
Lizzit, Silvano
Verdini, Alberto
Floreano, Luca
Martín Gago, José Ángel
López, María F.
author_role author
author2 Palacio, Irene
Sánchez Sánchez, Carlos
Otero Irurueta, Gonzalo
Martínez, José I.
Rodriguez, Luis Miguel
Serrate, David
Cossaro, Albano
Lacovig, Paolo
Lizzit, Silvano
Verdini, Alberto
Floreano, Luca
Martín Gago, José Ángel
López, María F.
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv aminophenol
surface science
STM
topic aminophenol
surface science
STM
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We present a comparative study of the room-temperature adsorption of p-aminophenol (p-AP) molecules on three metal surfaces, namely Cu(110), Cu(111), and Pt(111). We show that the chemical nature and the structural symmetry of the substrate control the activation of the terminal molecular groups, which result in different arrangements of the interfacial molecular layer. To this aim, we have used in situ STM images combined with synchrotron radiation high-resolution XPS and NEXAFS spectra, and the results were simulated by DFT calculations. On copper, the interaction between the molecules and the surface is weaker on the (111) surface crystal plane than on the (110) one, favoring molecular diffusion and leading to larger ordered domains. We demonstrate that the p-AP molecule undergoes spontaneous dehydrogenation of the alcohol group to form phenoxy species on all the studied surfaces; however, this process is not complete on the less reactive surface, Cu(111). The Pt(111) surface exhibits stronger molecule-surface interaction, inducing a short-range ordered molecular arrangement that increases over time. In addition, on the highly reactive Pt(111) surface other chemical processes are evidenced, such as the dehydrogenation of the amine group.
Fil: Del Árbol, Nerea Ruiz. Instituto de Ciencia de Materiales de Madrid; España
Fil: Palacio, Irene. Instituto de Ciencia de Materiales de Madrid; España
Fil: Sánchez Sánchez, Carlos. Instituto de Ciencia de Materiales de Madrid; España
Fil: Otero Irurueta, Gonzalo. Universidade de Aveiro; Portugal
Fil: Martínez, José I.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Rodriguez, Luis Miguel. Instituto de Ciencia de Materiales de Madrid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina
Fil: Serrate, David. Universidad de Zaragoza. Instituto de Ciencias de Materiales de Aragon; España
Fil: Cossaro, Albano. Università degli Studi di Trieste; Italia. Laboratorio Nazionale Tasc; Italia
Fil: Lacovig, Paolo. Elettra - Synchrotron Ligght Laboratory; Italia
Fil: Lizzit, Silvano. Elettra - Synchrotron Ligght Laboratory; Italia
Fil: Verdini, Alberto. Laboratorio Nazionale Tasc; Italia
Fil: Floreano, Luca. No especifíca;
Fil: Martín Gago, José Ángel. Instituto de Ciencia de Materiales de Madrid; España
Fil: López, María F.. Instituto de Ciencia de Materiales de Madrid; España
description We present a comparative study of the room-temperature adsorption of p-aminophenol (p-AP) molecules on three metal surfaces, namely Cu(110), Cu(111), and Pt(111). We show that the chemical nature and the structural symmetry of the substrate control the activation of the terminal molecular groups, which result in different arrangements of the interfacial molecular layer. To this aim, we have used in situ STM images combined with synchrotron radiation high-resolution XPS and NEXAFS spectra, and the results were simulated by DFT calculations. On copper, the interaction between the molecules and the surface is weaker on the (111) surface crystal plane than on the (110) one, favoring molecular diffusion and leading to larger ordered domains. We demonstrate that the p-AP molecule undergoes spontaneous dehydrogenation of the alcohol group to form phenoxy species on all the studied surfaces; however, this process is not complete on the less reactive surface, Cu(111). The Pt(111) surface exhibits stronger molecule-surface interaction, inducing a short-range ordered molecular arrangement that increases over time. In addition, on the highly reactive Pt(111) surface other chemical processes are evidenced, such as the dehydrogenation of the amine group.
publishDate 2020
dc.date.none.fl_str_mv 2020-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/146773
Del Árbol, Nerea Ruiz; Palacio, Irene; Sánchez Sánchez, Carlos; Otero Irurueta, Gonzalo; Martínez, José I.; et al.; Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol; American Chemical Society; Journal of Physical Chemistry C; 124; 36; 9-2020; 19655-19665
1932-7447
CONICET Digital
CONICET
url http://hdl.handle.net/11336/146773
identifier_str_mv Del Árbol, Nerea Ruiz; Palacio, Irene; Sánchez Sánchez, Carlos; Otero Irurueta, Gonzalo; Martínez, José I.; et al.; Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol; American Chemical Society; Journal of Physical Chemistry C; 124; 36; 9-2020; 19655-19665
1932-7447
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.0c06101
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.0c06101
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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