Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)

Autores
D'amico, David Alberto; Fasce, Laura Alejandra; Hoppe, Cristina Elena; López Quintela, M. Arturo; Cyras, Viviana Paola
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Superparamagnetic nanocomposites were obtained by dispersion of oleic acidcoated magnetic ultrafine iron oxide nanoparticles (NPs) in poly(hydroxybutyrate) (PHB), a semicrystalline, biodegradable and biocompatible polymer. Film nanocomposites displayed an optically homogeneous structure formed by sub-micrometric clusters created by a strong NPs segregation that occurred during solvent evaporation and polymer crystallization. Number and size of clusters increased with the concentration of NPs producing a controlled shift in the blocking temperature but hardly affecting PHB crystallinity and melting temperature. The presence of NPs decreased the elastic modulus of PHB and slightly reduced its hardness, leading to materials with improved resistance to permanent damage. This softening effect was attributed to the oleic acid shell covering the iron oxide core of the NPs. The present results shed some light on the mechanisms controlling morphology of semicrystalline-based nanocomposites modified with ultrafine NPs, opening interesting possibilities for the design of materials with controlled functional properties.
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: López Quintela, M. Arturo. Universidad de Santiago de Compostela. Facultad de Quimica; España
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
BIODEGRADABLE POLYMERS
POLY(3-HYDROXYBUTYRATE)
NANOCOMPOSITES
SUPERPARAMAGNETIC MATERIALS
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5017
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5017
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)D'amico, David AlbertoFasce, Laura AlejandraHoppe, Cristina ElenaLópez Quintela, M. ArturoCyras, Viviana PaolaBIODEGRADABLE POLYMERSPOLY(3-HYDROXYBUTYRATE)NANOCOMPOSITESSUPERPARAMAGNETIC MATERIALShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Superparamagnetic nanocomposites were obtained by dispersion of oleic acidcoated magnetic ultrafine iron oxide nanoparticles (NPs) in poly(hydroxybutyrate) (PHB), a semicrystalline, biodegradable and biocompatible polymer. Film nanocomposites displayed an optically homogeneous structure formed by sub-micrometric clusters created by a strong NPs segregation that occurred during solvent evaporation and polymer crystallization. Number and size of clusters increased with the concentration of NPs producing a controlled shift in the blocking temperature but hardly affecting PHB crystallinity and melting temperature. The presence of NPs decreased the elastic modulus of PHB and slightly reduced its hardness, leading to materials with improved resistance to permanent damage. This softening effect was attributed to the oleic acid shell covering the iron oxide core of the NPs. The present results shed some light on the mechanisms controlling morphology of semicrystalline-based nanocomposites modified with ultrafine NPs, opening interesting possibilities for the design of materials with controlled functional properties.Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: López Quintela, M. Arturo. Universidad de Santiago de Compostela. Facultad de Quimica; EspañaFil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2014-04-04info:eu-repo/date/embargoEnd/2016-05-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5017D'amico, David Alberto; Fasce, Laura Alejandra; Hoppe, Cristina Elena; López Quintela, M. Arturo; Cyras, Viviana Paola; Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate); Elsevier; European Polymer Journal; 55; 4-4-2014; 160-1690014-3057enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/issn/0014-3057info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2014.03.033info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S001430571400113Xinfo:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:59:07Zoai:ri.conicet.gov.ar:11336/5017instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:59:07.554CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
title Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
spellingShingle Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
D'amico, David Alberto
BIODEGRADABLE POLYMERS
POLY(3-HYDROXYBUTYRATE)
NANOCOMPOSITES
SUPERPARAMAGNETIC MATERIALS
title_short Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
title_full Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
title_fullStr Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
title_full_unstemmed Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
title_sort Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate)
dc.creator.none.fl_str_mv D'amico, David Alberto
Fasce, Laura Alejandra
Hoppe, Cristina Elena
López Quintela, M. Arturo
Cyras, Viviana Paola
author D'amico, David Alberto
author_facet D'amico, David Alberto
Fasce, Laura Alejandra
Hoppe, Cristina Elena
López Quintela, M. Arturo
Cyras, Viviana Paola
author_role author
author2 Fasce, Laura Alejandra
Hoppe, Cristina Elena
López Quintela, M. Arturo
Cyras, Viviana Paola
author2_role author
author
author
author
dc.subject.none.fl_str_mv BIODEGRADABLE POLYMERS
POLY(3-HYDROXYBUTYRATE)
NANOCOMPOSITES
SUPERPARAMAGNETIC MATERIALS
topic BIODEGRADABLE POLYMERS
POLY(3-HYDROXYBUTYRATE)
NANOCOMPOSITES
SUPERPARAMAGNETIC MATERIALS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Superparamagnetic nanocomposites were obtained by dispersion of oleic acidcoated magnetic ultrafine iron oxide nanoparticles (NPs) in poly(hydroxybutyrate) (PHB), a semicrystalline, biodegradable and biocompatible polymer. Film nanocomposites displayed an optically homogeneous structure formed by sub-micrometric clusters created by a strong NPs segregation that occurred during solvent evaporation and polymer crystallization. Number and size of clusters increased with the concentration of NPs producing a controlled shift in the blocking temperature but hardly affecting PHB crystallinity and melting temperature. The presence of NPs decreased the elastic modulus of PHB and slightly reduced its hardness, leading to materials with improved resistance to permanent damage. This softening effect was attributed to the oleic acid shell covering the iron oxide core of the NPs. The present results shed some light on the mechanisms controlling morphology of semicrystalline-based nanocomposites modified with ultrafine NPs, opening interesting possibilities for the design of materials with controlled functional properties.
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: López Quintela, M. Arturo. Universidad de Santiago de Compostela. Facultad de Quimica; España
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description Superparamagnetic nanocomposites were obtained by dispersion of oleic acidcoated magnetic ultrafine iron oxide nanoparticles (NPs) in poly(hydroxybutyrate) (PHB), a semicrystalline, biodegradable and biocompatible polymer. Film nanocomposites displayed an optically homogeneous structure formed by sub-micrometric clusters created by a strong NPs segregation that occurred during solvent evaporation and polymer crystallization. Number and size of clusters increased with the concentration of NPs producing a controlled shift in the blocking temperature but hardly affecting PHB crystallinity and melting temperature. The presence of NPs decreased the elastic modulus of PHB and slightly reduced its hardness, leading to materials with improved resistance to permanent damage. This softening effect was attributed to the oleic acid shell covering the iron oxide core of the NPs. The present results shed some light on the mechanisms controlling morphology of semicrystalline-based nanocomposites modified with ultrafine NPs, opening interesting possibilities for the design of materials with controlled functional properties.
publishDate 2014
dc.date.none.fl_str_mv 2014-04-04
info:eu-repo/date/embargoEnd/2016-05-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5017
D'amico, David Alberto; Fasce, Laura Alejandra; Hoppe, Cristina Elena; López Quintela, M. Arturo; Cyras, Viviana Paola; Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate); Elsevier; European Polymer Journal; 55; 4-4-2014; 160-169
0014-3057
url http://hdl.handle.net/11336/5017
identifier_str_mv D'amico, David Alberto; Fasce, Laura Alejandra; Hoppe, Cristina Elena; López Quintela, M. Arturo; Cyras, Viviana Paola; Superparamagnetic nanocomposites obtained by dispersion of ultrafine magnetic iron oxide nanoparticles in poly(3-hydroxybutyrate); Elsevier; European Polymer Journal; 55; 4-4-2014; 160-169
0014-3057
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/issn/0014-3057
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2014.03.033
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S001430571400113X
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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