Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell

Autores
García, Juan Rafael; Sedran, Ulises Anselmo; Zaini, Muhammad Abbas Ahmad; Zakaria, Zainul Akmar
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Palm oil mill wastes (palm kernel shell (PKS)) were used to prepare activated carbons, which were tested in the removal of colorants from water. The adsorbents were prepared by 1-h impregnation of PKS with ZnCl2 as the activating agent (PKS:ZnCl2 mass ratios of 1:1 and 2:1), followed by carbonization in autogenous atmosphere at 500 and 550 °C during 1 h. The characterization of the activated carbons included textural properties (porosity), surface chemistry (functional groups), and surface morphology. The dye removal performance of the different activated carbons was investigated by means of the uptake of methylene blue (MB) in solutions with various initial concentrations (25–400 mg/L of MB) at 30 °C, using a 0.05-g carbon/50-mL solution relationship. The sample prepared with 1:1 PKS:ZnCl2 and carbonized at 550 °C showed the highest MB adsorption capacity (maximum uptake at the equilibrium, qmax = 225.3 mg MB / g adsorbent), resulting from its elevated specific surface area (BET, 1058 m2/g) and microporosity (micropore surface area, 721 m2/g). The kinetic experiments showed that removals over 90% of the equilibrium adsorptions were achieved after 4-h contact time in all the cases. The study showed that palm oil mill waste biomass could be used in the preparation of adsorbents efficient in the removal of colorants in wastewaters.
Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Zaini, Muhammad Abbas Ahmad. Universiti Teknologi Malaysia; Malasia
Fil: Zakaria, Zainul Akmar. Universiti Teknologi Malaysia; Malasia
Materia
ACTIVATED CARBON
ADSORPTION
DYE REMOVAL
PALM KERNEL SHELL
WASTE BIOMASS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/87385
Acceder
id CONICETDig_e2737008353f4dc20ef205c3a6351584
oai_identifier_str oai:ri.conicet.gov.ar:11336/87385
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shellGarcía, Juan RafaelSedran, Ulises AnselmoZaini, Muhammad Abbas AhmadZakaria, Zainul AkmarACTIVATED CARBONADSORPTIONDYE REMOVALPALM KERNEL SHELLWASTE BIOMASShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Palm oil mill wastes (palm kernel shell (PKS)) were used to prepare activated carbons, which were tested in the removal of colorants from water. The adsorbents were prepared by 1-h impregnation of PKS with ZnCl2 as the activating agent (PKS:ZnCl2 mass ratios of 1:1 and 2:1), followed by carbonization in autogenous atmosphere at 500 and 550 °C during 1 h. The characterization of the activated carbons included textural properties (porosity), surface chemistry (functional groups), and surface morphology. The dye removal performance of the different activated carbons was investigated by means of the uptake of methylene blue (MB) in solutions with various initial concentrations (25–400 mg/L of MB) at 30 °C, using a 0.05-g carbon/50-mL solution relationship. The sample prepared with 1:1 PKS:ZnCl2 and carbonized at 550 °C showed the highest MB adsorption capacity (maximum uptake at the equilibrium, qmax = 225.3 mg MB / g adsorbent), resulting from its elevated specific surface area (BET, 1058 m2/g) and microporosity (micropore surface area, 721 m2/g). The kinetic experiments showed that removals over 90% of the equilibrium adsorptions were achieved after 4-h contact time in all the cases. The study showed that palm oil mill waste biomass could be used in the preparation of adsorbents efficient in the removal of colorants in wastewaters.Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Zaini, Muhammad Abbas Ahmad. Universiti Teknologi Malaysia; MalasiaFil: Zakaria, Zainul Akmar. Universiti Teknologi Malaysia; MalasiaSpringer Heidelberg2018-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87385García, Juan Rafael; Sedran, Ulises Anselmo; Zaini, Muhammad Abbas Ahmad; Zakaria, Zainul Akmar; Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell; Springer Heidelberg; Environmental Science and Pollution Research; 25; 6; 2-2018; 5076-50850944-1344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11356-017-8975-8info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11356-017-8975-8info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:16Zoai:ri.conicet.gov.ar:11336/87385instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:17.287CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
title Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
spellingShingle Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
García, Juan Rafael
ACTIVATED CARBON
ADSORPTION
DYE REMOVAL
PALM KERNEL SHELL
WASTE BIOMASS
title_short Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
title_full Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
title_fullStr Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
title_full_unstemmed Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
title_sort Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell
dc.creator.none.fl_str_mv García, Juan Rafael
Sedran, Ulises Anselmo
Zaini, Muhammad Abbas Ahmad
Zakaria, Zainul Akmar
author García, Juan Rafael
author_facet García, Juan Rafael
Sedran, Ulises Anselmo
Zaini, Muhammad Abbas Ahmad
Zakaria, Zainul Akmar
author_role author
author2 Sedran, Ulises Anselmo
Zaini, Muhammad Abbas Ahmad
Zakaria, Zainul Akmar
author2_role author
author
author
dc.subject.none.fl_str_mv ACTIVATED CARBON
ADSORPTION
DYE REMOVAL
PALM KERNEL SHELL
WASTE BIOMASS
topic ACTIVATED CARBON
ADSORPTION
DYE REMOVAL
PALM KERNEL SHELL
WASTE BIOMASS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Palm oil mill wastes (palm kernel shell (PKS)) were used to prepare activated carbons, which were tested in the removal of colorants from water. The adsorbents were prepared by 1-h impregnation of PKS with ZnCl2 as the activating agent (PKS:ZnCl2 mass ratios of 1:1 and 2:1), followed by carbonization in autogenous atmosphere at 500 and 550 °C during 1 h. The characterization of the activated carbons included textural properties (porosity), surface chemistry (functional groups), and surface morphology. The dye removal performance of the different activated carbons was investigated by means of the uptake of methylene blue (MB) in solutions with various initial concentrations (25–400 mg/L of MB) at 30 °C, using a 0.05-g carbon/50-mL solution relationship. The sample prepared with 1:1 PKS:ZnCl2 and carbonized at 550 °C showed the highest MB adsorption capacity (maximum uptake at the equilibrium, qmax = 225.3 mg MB / g adsorbent), resulting from its elevated specific surface area (BET, 1058 m2/g) and microporosity (micropore surface area, 721 m2/g). The kinetic experiments showed that removals over 90% of the equilibrium adsorptions were achieved after 4-h contact time in all the cases. The study showed that palm oil mill waste biomass could be used in the preparation of adsorbents efficient in the removal of colorants in wastewaters.
Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Zaini, Muhammad Abbas Ahmad. Universiti Teknologi Malaysia; Malasia
Fil: Zakaria, Zainul Akmar. Universiti Teknologi Malaysia; Malasia
description Palm oil mill wastes (palm kernel shell (PKS)) were used to prepare activated carbons, which were tested in the removal of colorants from water. The adsorbents were prepared by 1-h impregnation of PKS with ZnCl2 as the activating agent (PKS:ZnCl2 mass ratios of 1:1 and 2:1), followed by carbonization in autogenous atmosphere at 500 and 550 °C during 1 h. The characterization of the activated carbons included textural properties (porosity), surface chemistry (functional groups), and surface morphology. The dye removal performance of the different activated carbons was investigated by means of the uptake of methylene blue (MB) in solutions with various initial concentrations (25–400 mg/L of MB) at 30 °C, using a 0.05-g carbon/50-mL solution relationship. The sample prepared with 1:1 PKS:ZnCl2 and carbonized at 550 °C showed the highest MB adsorption capacity (maximum uptake at the equilibrium, qmax = 225.3 mg MB / g adsorbent), resulting from its elevated specific surface area (BET, 1058 m2/g) and microporosity (micropore surface area, 721 m2/g). The kinetic experiments showed that removals over 90% of the equilibrium adsorptions were achieved after 4-h contact time in all the cases. The study showed that palm oil mill waste biomass could be used in the preparation of adsorbents efficient in the removal of colorants in wastewaters.
publishDate 2018
dc.date.none.fl_str_mv 2018-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/87385
García, Juan Rafael; Sedran, Ulises Anselmo; Zaini, Muhammad Abbas Ahmad; Zakaria, Zainul Akmar; Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell; Springer Heidelberg; Environmental Science and Pollution Research; 25; 6; 2-2018; 5076-5085
0944-1344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/87385
identifier_str_mv García, Juan Rafael; Sedran, Ulises Anselmo; Zaini, Muhammad Abbas Ahmad; Zakaria, Zainul Akmar; Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell; Springer Heidelberg; Environmental Science and Pollution Research; 25; 6; 2-2018; 5076-5085
0944-1344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s11356-017-8975-8
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11356-017-8975-8
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer Heidelberg
publisher.none.fl_str_mv Springer Heidelberg
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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