Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions

Autores
Mancipe, Sonia; Coca, Valentina; Castillo, Juan Carlos; Rojas, Hugo; Brijaldo, María Helena; Castañeda, Claudia Gabriela; Martínez Zambrano, José Jobanny; Romanelli, Gustavo Pablo
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Hydroxymethylfurfural (HMF) derivatives that contain an acrylonitrile group result in inter-esting scaffold molecules that can be obtained from biomass. However, the synthesis of these typesof molecules has not been extensively studied. In this study, we investigated the catalytic activity ofMg(OH)2 and MgO materials. Specifically, we evaluated the Knoevenagel reaction between HMF andmalononitrile as a test reaction under solvent-free conditions. The fresh and used catalysts were eval-uated using various techniques. Our results indicate that the combination of synthesis methods in-fluences the crystalline, basic, and textural properties of the catalysts. We found that water plays anessential role in obtaining high yields. By using this simple and inexpensive method, we were able toachieve yields near 90% in short reaction times (<30 min).Keywords. HMF, Active methylene, Brucite, Solvent-free, Knoevenagel reaction.
Fil: Mancipe, Sonia. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Coca, Valentina. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Castillo, Juan Carlos. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Rojas, Hugo. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Brijaldo, María Helena. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Castañeda, Claudia Gabriela. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Martínez Zambrano, José Jobanny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
HMF
Brucite
Solvent-free
Knoevenagel reaction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/230136
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/230136
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditionsMancipe, SoniaCoca, ValentinaCastillo, Juan CarlosRojas, HugoBrijaldo, María HelenaCastañeda, Claudia GabrielaMartínez Zambrano, José JobannyRomanelli, Gustavo PabloHMFBruciteSolvent-freeKnoevenagel reactionhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Hydroxymethylfurfural (HMF) derivatives that contain an acrylonitrile group result in inter-esting scaffold molecules that can be obtained from biomass. However, the synthesis of these typesof molecules has not been extensively studied. In this study, we investigated the catalytic activity ofMg(OH)2 and MgO materials. Specifically, we evaluated the Knoevenagel reaction between HMF andmalononitrile as a test reaction under solvent-free conditions. The fresh and used catalysts were eval-uated using various techniques. Our results indicate that the combination of synthesis methods in-fluences the crystalline, basic, and textural properties of the catalysts. We found that water plays anessential role in obtaining high yields. By using this simple and inexpensive method, we were able toachieve yields near 90% in short reaction times (<30 min).Keywords. HMF, Active methylene, Brucite, Solvent-free, Knoevenagel reaction.Fil: Mancipe, Sonia. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Coca, Valentina. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Castillo, Juan Carlos. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Rojas, Hugo. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Brijaldo, María Helena. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Castañeda, Claudia Gabriela. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Martínez Zambrano, José Jobanny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaAcadémie des sciences2023-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230136Mancipe, Sonia; Coca, Valentina; Castillo, Juan Carlos; Rojas, Hugo; Brijaldo, María Helena; et al.; Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions; Académie des sciences; Comptes Rendus Chimie; 26; 8-2023; 77-871878-1543CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.239/info:eu-repo/semantics/altIdentifier/doi/10.5802/crchim.239info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:21:46Zoai:ri.conicet.gov.ar:11336/230136instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:21:46.758CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
title Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
spellingShingle Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
Mancipe, Sonia
HMF
Brucite
Solvent-free
Knoevenagel reaction
title_short Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
title_full Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
title_fullStr Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
title_full_unstemmed Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
title_sort Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions
dc.creator.none.fl_str_mv Mancipe, Sonia
Coca, Valentina
Castillo, Juan Carlos
Rojas, Hugo
Brijaldo, María Helena
Castañeda, Claudia Gabriela
Martínez Zambrano, José Jobanny
Romanelli, Gustavo Pablo
author Mancipe, Sonia
author_facet Mancipe, Sonia
Coca, Valentina
Castillo, Juan Carlos
Rojas, Hugo
Brijaldo, María Helena
Castañeda, Claudia Gabriela
Martínez Zambrano, José Jobanny
Romanelli, Gustavo Pablo
author_role author
author2 Coca, Valentina
Castillo, Juan Carlos
Rojas, Hugo
Brijaldo, María Helena
Castañeda, Claudia Gabriela
Martínez Zambrano, José Jobanny
Romanelli, Gustavo Pablo
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv HMF
Brucite
Solvent-free
Knoevenagel reaction
topic HMF
Brucite
Solvent-free
Knoevenagel reaction
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Hydroxymethylfurfural (HMF) derivatives that contain an acrylonitrile group result in inter-esting scaffold molecules that can be obtained from biomass. However, the synthesis of these typesof molecules has not been extensively studied. In this study, we investigated the catalytic activity ofMg(OH)2 and MgO materials. Specifically, we evaluated the Knoevenagel reaction between HMF andmalononitrile as a test reaction under solvent-free conditions. The fresh and used catalysts were eval-uated using various techniques. Our results indicate that the combination of synthesis methods in-fluences the crystalline, basic, and textural properties of the catalysts. We found that water plays anessential role in obtaining high yields. By using this simple and inexpensive method, we were able toachieve yields near 90% in short reaction times (<30 min).Keywords. HMF, Active methylene, Brucite, Solvent-free, Knoevenagel reaction.
Fil: Mancipe, Sonia. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Coca, Valentina. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Castillo, Juan Carlos. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Rojas, Hugo. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Brijaldo, María Helena. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Castañeda, Claudia Gabriela. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Martínez Zambrano, José Jobanny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Hydroxymethylfurfural (HMF) derivatives that contain an acrylonitrile group result in inter-esting scaffold molecules that can be obtained from biomass. However, the synthesis of these typesof molecules has not been extensively studied. In this study, we investigated the catalytic activity ofMg(OH)2 and MgO materials. Specifically, we evaluated the Knoevenagel reaction between HMF andmalononitrile as a test reaction under solvent-free conditions. The fresh and used catalysts were eval-uated using various techniques. Our results indicate that the combination of synthesis methods in-fluences the crystalline, basic, and textural properties of the catalysts. We found that water plays anessential role in obtaining high yields. By using this simple and inexpensive method, we were able toachieve yields near 90% in short reaction times (<30 min).Keywords. HMF, Active methylene, Brucite, Solvent-free, Knoevenagel reaction.
publishDate 2023
dc.date.none.fl_str_mv 2023-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/230136
Mancipe, Sonia; Coca, Valentina; Castillo, Juan Carlos; Rojas, Hugo; Brijaldo, María Helena; et al.; Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions; Académie des sciences; Comptes Rendus Chimie; 26; 8-2023; 77-87
1878-1543
CONICET Digital
CONICET
url http://hdl.handle.net/11336/230136
identifier_str_mv Mancipe, Sonia; Coca, Valentina; Castillo, Juan Carlos; Rojas, Hugo; Brijaldo, María Helena; et al.; Synthesis of acrylonitrile functionalized hydroxymethylfurfural derivatives with Mg(OH)2 under solvent-free conditions; Académie des sciences; Comptes Rendus Chimie; 26; 8-2023; 77-87
1878-1543
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.239/
info:eu-repo/semantics/altIdentifier/doi/10.5802/crchim.239
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Académie des sciences
publisher.none.fl_str_mv Académie des sciences
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614207507529728
score 13.070432

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